Impact of intensive fish farming on methane emission in a tropical hydropower reservoir

Fisheries and aquaculture are important sources of food for hundreds of millions of people around the world. World fish production is projected to increase by 15% in the next 10 years, reaching around 200 million tonnes per year. The main driver of this increase will be based on fish farming management in developing countries. In Brazil, fish farming is increasing due to the climate conditions and large supply of water resources, with the production system based on Nile tilapia (Oreochromis niloticus) farming in reservoirs. Inland waters like reservoirs are a natural source of methane (CH₄) to the atmosphere. However, knowledge of the impact from intensive fish production in net cages on CH₄ fluxes is not well known. This paper presents in situ measurements of CH₄ fluxes and dissolved CH₄ (DM) in the Furnas Hydroelectric Reservoir in order to evaluate the impact of fish farming on methane emissions. Measurements were taken in a control area without fish production and three areas with fish farming. The overall mean of diffusive methane flux (DMF) (5.9?±?4.5 mg CH₄ m^?2 day^?1) was significantly lower when compared to the overall mean of bubble methane flux (BMF) (552.9?±?1003.9 mg CH₄ m^?2 day^?1). The DMF and DM were significantly higher in the two areas with fish farming, whereas the BMF was not significantly different. The DMF and DM were correlated to depth and chlorophyll-a. However, the low production of BMF did not allow the comparison with the limnological parameters measured. This case study shows that CH₄ emissions are influenced more by reservoir characteristics than fish production. Further investigation is necessary to assess the impact of fish farming on the greenhouse gas emissions.     

A new early Holocene shoreline displacement record for Blekinge,southern Sweden,and implications for underwater archaeology

We present evidence of a submerged early Holocene landscape off the Blekinge coastline in the Baltic Sea, dating to the Yoldia Sea and Initial Littorina Sea Stages when the water level was lower than at present. ¹⁴C dated wood remains obtained by surveillance diving and new archaeological findings in combination with bathymetric analyses and interpolations between other sites across the Baltic Sea were used for refinement of the shoreline displacement history of the region. The new results reveal a Yoldia Sea lowstand level at 20 m b.s.l., a subsequent Ancylus Lake highstand at 3 m a.s.l., and then a period of relatively stable water level at about 4 m b.s.l. during the Initial Littorina Sea Stage, several metres lower than previously concluded. The refined shoreline displacement record was used for palaeo‐reconstructions of the study area during four key periods, the Yoldia Sea lowstand phase, the Ancylus Lake transgression phase, the Ancylus Lake highstand phase and the Initial Littorina Sea lowstand phase, using elevation data and map algebra functions. A flow accumulation algorithm was used for reconstruction of the now submerged prehistoric river network in order to identify areas of high archaeological potential. Our revised shoreline displacement record, and especially its lowstand period during the Initial Littorina Sea Stage around 9500–8500 cal. a BP, raises future demands not only for specific archaeological shallow‐water surveys down to 4 m b.s.l. in the area, but also for a renewed cultural heritage management strategy. The results of this study fill an important gap in the early Holocene part of the shoreline displacement history of Blekinge, contributing to its completion since the deglaciation, which is unique for the Baltic Sea.     

Late orogenic collapse and thermal doming in the northern Gondwana margin incorporated in the Variscan Chain: A case study from the Ozieri Metamorphic Complex, northern Sardinia, Italy

A branch of the South European Variscan chain is noticeably exposed in Sardinia. The early stage of collision between the Northern Gondwana margin and the Armorica Terrane Assemblage (ATA) generated syn-metamorphic folding and thrusting. The evidences of such deformation are well preserved in the nappe zone, a structural domain characterized by stacking of different tectonic units under metamorphism of Barrovian greenschist facies. A late, post-nappe, shortening, under retrograde metamorphic conditions, gave rise to wide, upright, N120–N160 trending antiforms that control the trend of the chain. The structural analysis of the Ozieri Metamorphic Complex (OMC) shows evidence of an important phase of late-Variscan extensional tectonics. Deformation results in, the formation of oppositely dipping, normal shear zones, which developed at upper and middle structural level along the limbs of major regional antiforms causing fabric reactivation, crustal thinning, and exhumation of the OMC core. Within the OMC, the activity of the shear zones was coeval with HT-LP metamorphism as suggests the occurrence of syn-kinematic cordierite + andalusite ± sillimanite + biotite. Whereas syntectonic dykes and a tonalite body in the deeper part of the OMC indicate that early emplacement of melt along shear zones and/or in the antiform hinges possibly supplied the heat for the anomalous thermal gradient and triggered the exhumation of a core complex-like structure.     

Pressure–temperature evolution of the late Hercynian Calabria continental crust: compatibility with post‐collisional extensional tectonics

The late Hercynian tectonic evolution of the Calabria crust is characterized by peak metamorphic conditions up to 800 °C and 1000 MPa, and coeval mid‐crustal granitoid emplacement at 304–300 Ma. To check if a post‐collisional extensional framework, similar to that of other Hercynian massifs, can explain petrologic data, we model the pressure–temperature evolution of the crust during extension following granitoid emplacement. Model parameters are constrained by petrologic, geochemical and structural data. Computed P–T paths are characterized by nearly isothermal decompression followed by isobaric cooling, which show a good fit to petrologic P–T paths for duration of extension between 5 and 10 Ma. The model results, therefore, support an interpretation of the magmatic and metamorphic evolution of the Calabria crust in terms of the late Hercynian extension. In this framework, slab break‐off is a reasonable explanation for the common evolution of the southern European Hercynian massifs.     

Seafloor change detection using multibeam echosounder backscatter: case study on the Belgian part of the North Sea

To characterize seafloor substrate type, seabed mapping and particularly multibeam echosounding are increasingly used. Yet, the utilisation of repetitive MBES-borne backscatter surveys to monitor the environmental status of the seafloor remains limited. Often methodological frameworks are missing, and should comprise of a suite of change detection procedures, similarly to those developed in the terrestrial sciences. In this study, pre-, ensemble and post-classification approaches were tested on an eight km² study site within a Habitat Directive Area in the Belgian part of the North Sea. In this area, gravel beds with epifaunal assemblages were observed. Flourishing of the fauna is constrained by overtopping with sand or increased turbidity levels, which could result from anthropogenic activities. Monitoring of the gravel to sand ratio was hence put forward as an indicator of good environmental status. Seven acoustic surveys were undertaken from 2004 to 2015. The methods allowed quantifying temporal trends and patterns of change of the main substrate classes identified in the study area; namely fine to medium homogenous sand, medium sand with bioclastic detritus and medium to coarse sand with gravel. Results indicated that by considering the entire study area and the entire time series, the gravel to sand ratio fluctuated, but was overall stable. Nonetheless, when only the biodiversity hotspots were considered, net losses and a gradual trend, indicative of potential smothering, was captured by ensemble and post-classification approaches respectively. Additionally, a two-dimensional morphological analysis, based on the bathymetric data, suggested a loss of profile complexity from 2004 to 2015. Causal relationships with natural and anthropogenic stressors are yet to be established. The methodologies presented and discussed are repeatable and can be applied to broad-scale geographical extents given that broad-scale time series datasets become available.     

Huygens probe entry trajectory and attitude estimated simultaneously with Titan atmospheric structure by Kalman filtering

Space probes entering planetary atmospheres are used for in situ study of their physical structures. During the entry phase aerodynamic forces exerted on the probe depend on atmospheric density. As a consequence accelerations measured by on-board sensors can be used to derive probe trajectory as well as atmospheric density, pressure and temperature profiles. In this work acceleration data acquired by the Huygens Atmospheric Structure Instrument (HASI) have been used to reconstruct the probe trajectory and the Titan's atmospheric structure from down to of altitude. An accurate six degree of freedom model of Huygens during the entry phase has been developed and a new reconstruction technique based on Kalman filtering is presented. This technique estimates simultaneously the probe trajectory, the attitude profile consistent with measured data and the atmospheric density, pressure and temperature.     

Geological,geochemical and mineralogical features of some bauxite deposits from Nurra (Western Sardinia,Italy): insights on conditions of formation and parental affinity

Bauxite deposits are widespread in NW Sardinia. They formed during the middle Cretaceous, in consequence of a period of emergence of the Mesozoic carbonate shelf. In the Nurra area the geometries derived by the Middle Cretaceous tectonic phases controlled the ore typologies. Two bauxite profiles, laying on different bedrocks, were sampled. The bauxitization proceeded from the surface downward, with the accumulation of Al₂O₃ and residual ‘immobile’ elements (Al, Ti, HFSE), and corresponding mobility and loss of SiO₂ and Fe₂O₃. Epigenetic kaolinite formed close to faults and joints, probably as a result of silicification, introduced by low temperature hydrothermal solutions. Rare earth elements, especially LREE, are concentrated in Fe-rich bauxite horizons, probably due to scavenging by goethite. REE-enrichment is not observed in the boehmite-rich horizons. Very high REE contents are observed in a Fe-depleted horizon due to the occurrence of REE accessory minerals, probably of the bastnäsite group. Conservative indices, including TiO₂/Al₂O₃ and Ti/Cr ratios, and Eu anomalies (Eu/Eu*), suggest that the deposits formed by weathering of sediments derived from mafic rocks of the Hercynian basement. This, in turn, implies that the basement was exposed during middle Cretaceous.     

Occurrence of palygorskite and sepiolite in upper Paleocene–middle Eocene marine deep sediments of the Lagonegro Basin (Southern Apennines—Italy): Paleoenvironmental and provenance inferences

A mineralogical and geochemical study of clay lithologies and a biostratigraphic analysis of the carbonates from the deep-sea Lagonegro Basin (Southern Apennines—Italy) have been carried out to deduce in general the provenance of clay sediments and their paleoenvironmental conditions and particular to recognize the signature of the Paleocene–Eocene climatic global warming. The analysed succession comprising a wide stratigraphic interval of the Sannio Unit, spanning between Albian to the upper Oligocene–lower Miocene, is exposed near Accettura and Stigliano villages. Eighteen clay samples were analysed by XRD, XRF, SEM, TG-DTA. Their age was framed by biostratigraphic analyses carried out on carbonate sediments. Mineral assemblage of the clay sediments includes quartz, carbonates (calcite and dolomite), feldspars (plagioclase and k-feldspars), hematite, randomly illite/smectite mixed layers with a low illite percentage, kaolinite, discrete illite–muscovite, chlorite, palygorskite and sepiolite. The low illite percentage in randomly illite/smectite mixed layers indicates low diagenetic conditions for the studied successions. These features are unique for the Cretaceous–Tertiary successions of the Lagonegro domain and are particularly significant for the preservation of the native mineralogical assemblage useful to determine the provenance and paleoenvironmental conditions of the clayey sediments. Palygorskite and sepiolite are concentrated in the upper Paleocene–middle Eocene stratigraphic interval and particularly in the upper part of the early Eocene—lower part of the middle Eocene (biozone of Blow P 9–12). Clay sediments rich in palygorskite and sepiolite show a higher P₂O₅ amount and a lower kaolinite percentage, compatible with warm and arid climatic conditions typical of the global warming event well recorded in the southern tethyan margin. Likely palygorskite and sepiolite formed in lagoonal environment in nearby carbonate platform margins and then they were transported into the Lagonegro Basin as indicated by the well developed habitus of palygorskite. During the Paleogene the Lagonegro Basin and the nearby carbonate platforms represented a key sector the southern paleodomains of the Tethys. The discovery of these minerals gives a contribution to the reconstruction paleoenvironmental conditions of the Tethian paleo-margin during the early–middle Eocene.     

Precipitable water evaluations from infrared sun‐photometric measurements analyzed using the atmospheric hygrometry technique

Measurements of direct solar irradiance were taken employing 4 different sun‐photometers at near infrared wavelengths, suitable for use in atmospheric hygrometry. This technique utilising a set of spectral ratios, in and out of selected water vapour absorption bands, was applied to the measurements to obtain accurate evaluations of precipitable water. For all the hygrometric ratios given by the 4 sun‐photometers used at the 3 stations of Sagres, Monchique and Mt. Foia, during the CLEARCOLUMN experiment, we determined the calibration curves by correcting them for the Rayleigh scattering effects and, then, plotting the natural logarithms of such corrected ratios versus the square root of the water vapour mass present along the atmospheric slant path. The regression lines drawn for the various scatter diagrams were estimated to give evaluations of precipitable water with an uncertainty of less than 5%, 3% and 10% at the 3 stations, respectively. The calibration curves of the sun‐photometer located at the Sagres station were determined using the precipitable water evaluations obtained from the local radiosounding measurements taken on 5 clear‐sky days. Those of the sun‐photometers used at the Monchique and Mt. Foia stations were instead determined through intercomparison between subsets of measurements simultaneously taken with various instruments at Sagres and Mt. Foia. Using these calibration curves, we examined all the field measurements determining the time‐patterns of precipitable water at the 3 stations. During the period from 16 June to 25 July 1997, precipitable water was found to vary between 1.1 and 3.7 g cm⁻² at the Sagres station (with an accuracy within ±13%), between 1.0 and 2.8 g cm⁻² at Monchique (±11%) and between 0.8 and 3.0 g cm⁻² at the top of Mt. Foia (±26%).