A Mössbauer spectroscopic study of the iron redox transition in eastern Mediterranean sediments

Fe cycling at two sites in the Mediterranean Sea (southwest of Rhodes and in the North Aegean) has been studied, combining the pore water determination of nutrients, manganese, and iron, citrate-bicarbonate-dithionite (CDB) and total sediment extractions, X-ray diffraction, and ⁵⁷Fe Mössbauer spectroscopy (MBS). At the Rhodes site, double peaks in the CDB-extractable Mn and Fe profiles indicate non-steady-state diagenesis. The crystalline iron oxide hematite, identified at both sites by room temperature (RT) MBS, appears to contribute little to the overall Fe reduction. MBS at liquid helium temperature (LHT) revealed that the reactive sedimentary Fe oxide phase was nanophase goethite, not ferrihydrite as is usually assumed. The pore water data at both sites indicates that upon reductive dissolution of nanophase goethite, the upward diffusing dissolved Fe²⁺ is oxidized by Mn oxides, rather than by nitrate or oxygen. The observed oxidation of Fe²⁺ by Mn oxides may be more common than previously thought but not obvious in sediments where the nitrate penetration depth coincides with the Mn oxide peak. At the Rhodes site, the solid-phase Fe(II) increase occurred at a shallower depth than the accumulation of dissolved Fe²⁺ in the pore water. The deeper relict Mn oxide peak acts as an oxidation barrier for the upward diffusing dissolved Fe²⁺, thereby keeping the pore water Fe²⁺ at depth. At the North Aegean site, the solid-phase Fe(II) increase occurs at approximately the same depth as the increase in dissolved Fe²⁺ in the pore water. Overall, the use of RT and cryogenic MBS provided insight into the solid-phase Fe(II) gradient and allowed identification of the sedimentary Fe oxides: hematite, maghemite, and nanophase goethite.     

Earthquake activity related to seismic cycles in a model for a heterogeneous strike-slip fault

We investigate the evolution of seismicity within large earthquake cycles in a model of a discrete strike-slip fault in elastic solid. The model dynamics is governed by realistic boundary conditions consisting of constant velocity motion of regions around the fault, static/kinetic friction and dislocation creep along the fault, and 3D elastic stress transfer. The fault consists of brittle parts which fail during earthquakes and undergo small creep deformation between events, and aseismic creep cells which are characterized by high ongoing creep motion. This mixture of brittle and creep cells is found to generate realistic aftershock sequences which follow the modified Omori law and scale with the mainshock size. Furthermore, we find that the distribution of interevent times of the simulated earthquakes is in good agreement with observations. The temporal occurrence, however, is magnitude-dependent; in particular, the small events are clustered in time, whereas the largest earthquakes occur quasiperiodically. Averaging the seismicity before several large earthquakes, we observe an increase of activity and a broadening scaling range of magnitudes when the time of the next mainshock is approached. These results are characteristics of a critical point behavior. The presence of critical point dynamics is further supported by the evolution of the stress field in the model, which is compatible with the observation of accelerating moment release in natural fault systems.     

Pasture enclosures increase soil carbon dioxide flux rate in Semiarid Rangeland,Kenya

Background

Pasture enclosures play an important role in rehabilitating the degraded soils and vegetation, and may also influence the emission of key greenhouse gasses (GHGs) from the soil. However, no study in East Africa and in Kenya has conducted direct measurements of GHG fluxes following the restoration of degraded communal grazing lands through the establishment of pasture enclosures. A field experiment was conducted in northwestern Kenya to measure the emission of CO₂, CH₄ and N₂O from soil under two pasture restoration systems; grazing dominated enclosure (GDE) and contractual grazing enclosure (CGE), and in the adjacent open grazing rangeland (OGR) as control. Herbaceous vegetation cover, biomass production, and surface (0–10 cm) soil organic carbon (SOC) were also assessed to determine their relationship with the GHG flux rate.

Results

Vegetation cover was higher enclosure systems and ranged from 20.7% in OGR to 40.2% in GDE while aboveground biomass increased from 72.0 kg DM ha^?1 in OGR to 483.1 and 560.4 kg DM ha^?1 in CGE and GDE respectively. The SOC concentration in GDE and CGE increased by an average of 27% relative to OGR and ranged between 4.4 g kg^?1 and 6.6 g kg^?1. The mean emission rates across the grazing systems were 18.6 μg N m^?2 h^?1, 50.1 μg C m^?2 h^?1 and 199.7 mg C m^?2 h^?1 for N₂O, CH₄, and CO₂, respectively. Soil CO₂ emission was considerably higher in GDE and CGE systems than in OGR (P?<?0.001). However, non-significantly higher CH₄ and N₂O emissions were observed in GDE and CGE compared to OGR (P?=?0.33 and 0.53 for CH₄ and N₂O, respectively). Soil moisture exhibited a significant positive relationship with CO₂, CH₄, and N₂O, implying that it is the key factor influencing the flux rate of GHGs in the area.

Conclusions

The results demonstrated that the establishment of enclosures in tropical rangelands is a valuable intervention for improving pasture production and restoration of surface soil properties. However, a long-term study is required to evaluate the patterns in annual CO₂, N₂O, CH₄ fluxes from soils and determine the ecosystem carbon balance across the pastoral landscape.

     

Reassembly of the Dharwar and Bastar cratons at ca. 1 Ga: Evidence from multiple tectonothermal events along the Karimnagar granulite belt and Khammam schist belt,southern India

The northern part of the Nellore–Khammam schist belt and the Karimnagar granulite belt, which are juxtaposed at high angle to each other have unique U–Pb zircon age records suggesting distinctive tectonothermal histories. Plate accretion and rifting in the eastern part of the Dharwar craton and between the Dharwar and Bastar craton indicate multiple and complex events from 2600 to 500 Ma. The Khammam schist belt, the Dharwar and the Bastar craton were joined together by the end of the Archaean. The Khammam schist belt had experienced additional tectonic events at \(\sim \)1900 and \(\sim \)1600 Ma. The Dharwar and Bastar cratons separated during development of the Pranhita–Godavari (P–G) valley basin at \(\sim \)1600 Ma, potentially linked to the breakup of the Columbia supercontinent and were reassembled during the Mesoproterozoic at about 1000 Ma. This amalgamation process in southern India could be associated with the formation of the Rodinia supercontinent. The Khammam schist belt and the Eastern Ghats mobile belt also show evidence for accretionary processes at around 500 Ma, which is interpreted as a record of Pan-African collisions during the Gondwana assembly. From then on, southern India, as is known today, formed an integral part of the Indian continent.     

Delineation of spatial-temporal patterns of groundwater/surface-water interaction along a river reach (Aa River,Belgium) with transient thermal modeling

Among the advances made in analytical and numerical analysis methods to quantify groundwater/surface-water interaction, one methodology that stands out is the use of heat as an environmental tracer. A large data set of river and riverbed temperature profiles from the Aa River in Belgium has been used to examine the spatial-temporal variations of groundwater/surface-water interaction. Exchange fluxes were calculated with the numerical heat-transport code STRIVE. The code was applied in transient mode to overcome previous limitations of steady-state analysis, and allowed for the calculation of model quality. In autumn and winter the mean exchange fluxes reached ?90 mm d^?1, while in spring and early summer fluxes were ?42 mm d^?1. Predominantly gaining conditions occurred along the river reach; however, in a few areas the direction of flow changed in time. The river banks showed elevated fluxes up to a factor of 3 compared to the center of the river. Higher fluxes were detected in the upstream section of the reach. Due to the influence of exchange fluxes along the river banks, larger temporal variations were found in the downstream section. The exchange fluxes at the river banks seemed more driven by variable local exchange flows, while the center of the river was dominated by deep and steady regional groundwater flows. These spatial and temporal differences in groundwater/surface-water exchange show the importance of long-term investigations on the driving forces of hyporheic processes across different scales.     

Astro-WISE interfaces

From a simple text interface to a graphical user interfaces—Astro-WISE provides the user with a wide range of possibilities to interact with the information system according to the user’s tasks and use cases. We describe a general approach to the interfacing of a scientific information system. We use this approach to create a number of services, which allows the user to browse the data stored in the system, to process the data and to exchange the newly created images and catalogs with the users within the system and wider astronomical community. Reusability of interfaces and services is another important feature of our approach. It reduces the time and resources spent to interface other information systems created from Astro-WISE.     

The life cycle of crevasse splays as a key mechanism in the aggradation of alluvial ridges and river avulsion

Accommodation space in the unconfined distal part of low‐gradient fluvial fans facilitates abundant floodplain deposition. Here, the development of crevasse splays plays a key role in the aggradation of alluvial ridges and subsequent river avulsion. This study presents an analysis of different stages in the evolution of crevasse splays based on observations made in the modern‐day Río Colorado dryland fluvial fan fringing the endorheic Altiplano Basin in Bolivia. A generic life cycle is proposed in which crevasse‐splay channels adjust towards a graded equilibrium profile with their lower‐lying distal termini acting as a local base level. Initial development is dominantly controlled by the outflow of floodwater, promoting erosion near the crevasse apex and deposition towards the splay fringes. When proximal incision advances to below the maximum level of floodplain inundation, return flow occurs during the waning stage of flooding. This floodwater reflux leads to a temporary repositioning of the local base level to the deeper trunk‐channel thalweg at the apex of the crevasse‐splay channels. The resultant decrease in the floodplainward gradient of these channels ultimately leads to backfilling and abandonment of the crevasse splay, leaving a subtle local elevation of the floodplain. Consecutive splays form an alluvial ridge through lateral amalgamation and subsequent vertical stacking, which is mirrored by the aggradation of their parent channel floor. As this alluvial ridge becomes increasingly perched above the surrounding floodplain, splay equilibration may cause incision of the levee crevasse down to or below its trunk channel thalweg, leading to an avulsion. The mechanisms proposed in this study are relevant to fluvial settings promoting progradational avulsions. The relatively rapid accumulation rate and high preservation potential of crevasse splays in this setting makes them an important constituent of the resultant fluvial stratigraphy, amongst which are hydrocarbon‐bearing successions. Copyright © 2018 John Wiley & Sons, Ltd.     

Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.