Electrical conductivity of the earth's crust and upper mantle

This review summarizes recent results of electrical resistivity studies of the earth's crust and upper mantle. Where available, the data are discussed in the context of further regional geophysical information. Electrical resistivity is very sensitive to a wide range of petrological and physical parameters, e.g., to carbon, fluids, volatiles and enhanced temperatures, making electrical resistivity methods a powerful tool in crust and upper mantle investigations. Yet, the general increase in resistivity data of the crust and mantle has not ended the battle of explanations for anomalous crustal conductivities.     

Fluid variability in 2 GPa eclogites as an indicator of fluid behavior during subduction

Fluid activity ratios calculated between millimeter- to centimeter-scale layers in banded mafic eclogites from the Tauern Window, Austria, indicate that variations in a _{H 2 O} existed between layers during equilibration at P approximately equal to 2GPa and T approximately equal to 625°C, whereas a _{CO 2} was nearly constant between the same layers. Model calculations in the system H₂O–CO₂–NaCl show that these results are consistent with the existence of different saturated saline brines, carbonic fluids, or immiscible pairs of both in different layers. The data cannot be explained by the exisience of water-rich fluids in all layers. The model fluid compositions agree with fluid inclusion compositions from eclogite-stage veins and segregations that contain (1) saline brines (up to 39 equivalent wt. % NaCl) with up to six silicate, oxide, and carbonate daughter phases, and (2) carbonic fluids. The formation of crystalline segregations from fluid-filled pockets or hydrofractures indicates high fluid pressures at 2 GPa; the record of fluid variability in the banded eclogite host rocks, however, implies that fluid transport was limited to local flow along individual layers and that there was no large-scale mixing of fluids during devolatilization at depths of 60–70 km. The lack of evidence for fluid mixing may, in part, reflect variations in wetting behavior of fluids of different composition; nonwetting fluids (water-rich or carbonic) would be confined to intergranular pore spaces and would be essentially immobile, whereas wetting fluids (saline brines) could migrate more easily along an interconnected fluid network. The heterogeneous distribution of chemically distinct fluids may influence chemical transport processes during subduction by affecting mineral-fluid element partitioning and by altering the migration properties of the fluid phase(s) in the downgoing slab.     

Arctic radiation deficit and climate variability

One of the generally accepted climatic effects of stratospheric aerosol injection is the reduction of the global radiation in high latitudes by an order of 5% during El Chichon type eruptions. To test the effect of a high-latitude radiation deficit on global climate, a GCM experiment was performed with the ECMWF T21 atmosphere general circulation model (AGCM). The results provide physically-consistent evidence that this radiation deficit is a possible external forcing factor for severe climatic anomalies not only in the area directly affected by the reduced radiation, but also in the tropics. The most important factor is the creation of enhanced snow cover in regions of Asia that are distant from the location of the introduced radiation anomaly. The simulated results show certain features that are well known from observations in weak monsoon years, i.e. the weakened easterly jet in the upper troposphere over northern India, prolonged winter monsoon conditions, and prevailing anticyclonic vorticity anomalies over the entire Indian summer monsoon region. Over the western Pacific at the end of boreal winter (May), increased convective activity leads to a negative Walker circulation anomaly with westerly wind anomalies near the surface and easterly anomalies in the upper troposphere. This is known as one of the most important anomalies at the beginning of an El Niño/Southern Oscillation (ENSO) event.This paper was presented at the International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 11–15 September 1989 under the auspices of the Meteorological Institute of the University of Hamburg and the Max Planck Institute for Meteorology. Guest Editor for these papers is Dr. L. Dümenil     

Low-temperature opal-CT precipitation in Antarctic deep-sea sediments: evidence from oxygen isotopes

Porcellanite has been found in Antarctic deep-sea sediments of shallow burial depth at four different sites in host sediments younger than 4 Ma. Oxygen isotope analysis shows that the opal-CT samples are extremely rich in¹⁸O (δ¹⁸O= 41.2to44.7‰ rel. SMOW). According to the quartz/water fractionation the calculated isotopic opal-CT formation temperature is in the range of 0 to 4°C. This agrees well with sediment temperature measurements. The low opal-CT precipitation temperature contrasts with current ideas about later diagenetic formation of opal-CT at higher temperatures of 18 to 56°C.     

Der Eiswinter 1989/90 im deutschen Küstengebiet zwischen Ems und Trave

Ohne Zusammenfassung     

Reconstruction of the ice winter severity since 1701 in the Western Baltic

This reconstruction of the ice winter severity in the Western Baltic is based for the period 1878-1993 on the accumulated areal ice volume along the German Baltic coast with observations from 13 coastal stations; for the period 1701-1877 it is based on the accumulated areal ice volume divided into 7 classes (ice winter severity types). The various types of data consulted in the latter case provided ice data of good spatial and temporal resolution.Speerschneider's compilation of data relating to ice conditions in Danish Baltic waters was found to be a valuable source of information. Using a classification table for the periods 1907-1943 and 1947-1992, five of the seven ice winter types have been derived with certainty as they are characterized by typical stages of maximum ice cover throughout the Western Baltic.The Gaussian lowpass-filtered time series of the ice winter index numerals with a 20 year cutoff period shows four periods of varying ice winter severity over a secular range: 1701-1720: slightly increased ice winter severity with regard to the mean of the 1701-1993 time series; this period can be assigned to the end of a cooling phase during Little Ice Age which in central Europe peaked in the second half of the 17th c. 1721-1760: ice winter severity is clearly reduced in this period. 1761-1860: ice winter severity is clearly increased (maximum occurs around 1800) towards the end of the Little Ice Age, associated with increased variability of ice production. 1861-1993: the present-day ice winter regime when three short intervals with increased ice winter severity (the 1890s, 1940s and 1980s) and a period of greatly reduced ice winter severity (between 1900 and the mid-1920s) stand out.     

Experimental Na-K distribution between amphiboles and aqueous chloride solutions, and a mixing model along the richterite – K-richterite join

The cation exchange equilibrium has been investigated by hydrothermal experiments at 700 and 800°C at 200 MPa. To avoid equilibration problems of conventional exchange experiments, we synthesized amphiboles with an excess fluid allowing exchange between solid and fluid during the experiment. The exchangeable cations Na and K were provided as excess 1 to 2n chloridic solution. These exchange syntheses can be described by the reaction equation with ^(aq) for hydroxides and chlorides in aqueous solutions and _{( s )} and _{( p )}?=?start and product fluid. The amphiboles grew in presence of the exchange fluid and adjusted their stoichiometry in equilibrium with the fluid phase. The solid products consist of more than 99% amphibole (Na,K-richterite_ss) with traces of diopside and quartz. The amphiboles are up to 1?mm long and often ≈ 40 μm thick. Detailed EMP- and HRTEM-observations show that they are chemically homogeneous and structurally wellordered. The experimental results give consistent phase relations in the reciprocal ternary system Na-richterite–K-richterite–NaCl–KCl. We analysed the product fluid with AAS- and ICP-methods. The Na-K distribution coefficients between fluid and amphiboles of the richterite–K-richterite join are close to unity at 700°C and 800°C at 200 MPa. Small systematic deviations are explained by a symmetric solution model for the A-position of the amphiboles. Using ideal mixing for H₂O-NaCl-KCl fluids, a mixing model for the system richterite–K-richterite is presented. We suggest that the composition of richterite solid solutions can be used as a sensor for NaCl/KCl-ratios in metamorphic fluids.