Analysis of Extreme Events in Geoelectrical Time Series Measured in a Seismic Area of Southern Appenine Chain (Italy)

In the present paper we analyse the series of extreme events in geoelectrical signals recorded at the monitoring station Tito located in a seismic area of southern Italy. Applying an objective criterion to estimate the probability of occurrence of extreme events in the time series (Cuomo et al., 1996; Cuomo et al., 1997), we found a correlation between the geoelectrical anomalies and earthquakes in the area monitored during the period of recording.     

Progressive assembly of a massive layer of ignimbrite with a normal-to-reverse compositional zoning: the Zaragoza ignimbrite of central Mexico

The Zaragoza ignimbrite and two enclosing rhyodacite pumice fall layers were emplaced during the 15 km³ (DRE), ∼0.1 Ma Zaragoza eruption from Los Humeros volcanic centre, 180 km east of Mexico City. The ignimbrite comprises several massive flow-units, the largest of which locally exceeds 20 m in thickness and is regionally traceable. It comprises massive lapilli-ash with vertical elutriation pipes, and has a fine-grained inverse-graded base and a pumice concentration zone at the top. It also exhibits an unusual gradational ‘double’ vertical compositional zonation that is widely traceable. A basal rhyodacitic (67.6–69 wt% SiO₂) zone grades up via a mixed zone into a central andesitic (58–62 wt% SiO₂) zone, which, in turn, grades up into an upper rhyodacitic (67.6–69 wt% SiO₂) zone. Zoning is also defined by vertical variations in lithic clast populations. We infer that pyroclastic fountaining fed initially rhyodacite pumice clasts to a sustained granular fluid-based pyroclastic density current. The composition of the pumice clasts supplied to the current then gradually changed, first to andesite and then back to rhyodacite. Inverse grading at the base of the massive layer may reflect initial waxing flow competence. The pumice concentration at the top of the massive layer is entirely rhyodacitic and was probably deposited during waning stages of the current, when the supply of andesitic pumice clasts had ceased. The return to rhyodacitic composition may have been the result of eruption-conduit modification during collapse of Los Potreros caldera, marked in the ignimbrite by a widespread influx of hydrothermally altered lithic blocks, and/or a decrease in draw-up depth from a compositionally stratified magma chamber as the eruptive mass flux waned. The massive layer of ignimbrite thins locally to less than 2 m, yet it still shows the double zonation. Correlation of the zoning suggests that the thin massive layer is stratigraphically condensed, and aggraded relatively slowly during the same time interval as did the much thicker (≤50 m) massive layer.Editorial responsibility: J McPhie     

Spatial moments for colloid-enhanced radionuclide transport in heterogeneous aquifers

We consider colloid facilitated radionuclide transport by steady groundwater flow in a heterogeneous porous formation. Radionuclide binding on colloids and soil-matrix is assumed to be kinetically/equilibrium controlled. All reactive parameters are regarded as uniform, whereas the hydraulic log-conductivity is modelled as a stationary random space function (RSF). Colloid-enhanced radionuclide transport is studied by means of spatial moments pertaining to both the dissolved and colloid-bounded concentration. The general expressions of spatial moments for a colloid-bounded plume are presented for the first time, and are discussed in order to show the combined impact of sorption processes as well as aquifer heterogeneity upon the plume migration. For the general case, spatial moments are defined by the aid of two characteristic reaction functions which cannot be expressed analytically. By adopting the approximation for the longitudinal fluid trajectory covariance valid for a flow parallel to the formation bedding suggested by Dagan and Cvetkovic [Dagan G, Cvetkovic V. Spatial Moments of Kinetically Sorbing Plume in a Heterogeneous Aquifers. Water Resour Res 1993;29:4053], we obtain closed form solutions.