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81.
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Laboratory investigations were conducted on the formation of NaF° ion-pairs at the ionic strength of seawater using specific ion electrodes. Sodium and fluoride ion electrodes produced results which are consistent with the ion-pairing model for these ionic interactions. The stoichiometric association constant for NaF°, K1NaF, was determined at 15, 25, and 35°C. It was assumed that K1NaF was a function of temperature, pressure, and ionic strength but not of solution composition. The value for K1NaF at 25°C and I = 0.7 m is 0.045 ± 0.006. K1NaF increased with decreasing temperature. This result was used to recompute values of K1MgF and K1CaF accounting for the presence of NaF° ion-pairs. The value for K1NaF indicates that 1.1% of the fluoride in seawater is ion-paired with sodium at 25°C and 35‰ salinity. This fraction increases to approximately 2% at the lower temperatures found in the deep ocean. The percentage of free fluoride in natural seawater was measured at 15, 25, and 35°C to verify the speciation calculated from equilibrium constants.  相似文献   
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 The oxidation and reduction that occur during early diagenesis of sediments has been studied in the interstitial waters of a rapidly accumulating sedimentary sequence from the Mediterranean margin of Spain. A series of reactions that are mediated by progressively lower free energy derived from oxidation of organic matter is evident in the sedimentary sequence. Iron and manganese are rapidly reduced. Phosphate and alkalinity maxima at a subbottom depth of 15 m indicate maximal organic matter degradation. Methane first appears at ∼20 m subbottom after sulfate is depleted, and its concentrations quickly climb. Received: 27 October 1997 / Revision received: 4 March 1998  相似文献   
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This paper revisits the derivation of the parametric surf zone model proposed by Baldock et al. [Baldock, T. E., Holmes, P., Bunker, S. & Van Weert, P. 1998 Cross-shore hydrodynamics within an unsaturated surf zone. Coast. Eng. 34, 173–196.]. We show that a consistent use of the proposed Rayleigh distribution for surf zone wave heights results in modification of the expressions for the bulk dissipation rate and enhanced dissipation levels on steep beaches and over-saturated surf zone conditions. As a consequence, the modification proposed herein renders the model robust even on steep beaches where it could otherwise develop a shoreline singularity.  相似文献   
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A technique, referred to as SARTopo, has been developed for obtaining surface height estimates with 10 km horizontal resolution and 75 m vertical resolution of the surface of Titan along each Cassini Synthetic Aperture Radar (SAR) swath. We describe the technique and present maps of the co-located data sets. A global map and regional maps of Xanadu and the northern hemisphere hydrocarbon lakes district are included in the results. A strength of the technique is that it provides topographic information co-located with SAR imagery. Having a topographic context vastly improves the interpretability of the SAR imagery and is essential for understanding Titan.SARTopo is capable of estimating surface heights for most of the SAR-imaged surface of Titan. Currently nearly 30% of the surface is within 100 km of a SARTopo height profile. Other competing techniques provide orders of magnitude less coverage.We validate the SARTopo technique through comparison with known geomorphological features such as mountain ranges and craters, and by comparison with co-located nadir altimetry, including a 3000 km strip that had been observed by SAR a month earlier. In this area, the SARTopo and nadir altimetry data sets are co-located tightly (within 5-10 km for one 500 km section), have similar resolution, and as expected agree closely in surface height. Furthermore the region contains prominent high spatial resolution topography, so it provides an excellent test of the resolution and precision of both techniques.  相似文献   
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We present the Millennium-II Simulation (MS-II), a very large N -body simulation of dark matter evolution in the concordance Λ cold dark matter (ΛCDM) cosmology. The MS-II assumes the same cosmological parameters and uses the same particle number and output data structure as the original Millennium Simulation (MS), but was carried out in a periodic cube one-fifth the size  (100  h −1 Mpc)  with five times better spatial resolution (a Plummer equivalent softening of  1.0  h −1 kpc  ) and with 125 times better mass resolution (a particle mass of  6.9 × 106  h −1 M  ). By comparing results at MS and MS-II resolution, we demonstrate excellent convergence in dark matter statistics such as the halo mass function, the subhalo abundance distribution, the mass dependence of halo formation times, the linear and non-linear autocorrelations and power spectra, and halo assembly bias. Together, the two simulations provide precise results for such statistics over an unprecedented range of scales, from haloes similar to those hosting Local Group dwarf spheroidal galaxies to haloes corresponding to the richest galaxy clusters. The 'Milky Way' haloes of the Aquarius Project were selected from a lower resolution version of the MS-II and were then resimulated at much higher resolution. As a result, they are present in the MS-II along with thousands of other similar mass haloes. A comparison of their assembly histories in the MS-II and in resimulations of 1000 times better resolution shows detailed agreement over a factor of 100 in mass growth. We publicly release halo catalogues and assembly trees for the MS-II in the same format within the same archive as those already released for the MS.  相似文献   
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