Study of the soil–atmosphere moisture exchanges through convective drying tests in non‐isothermal conditions

This paper deals with the moisture exchanges occurring between soils and the surrounding atmosphere. Convective drying tests are performed on Awans silts at different drying temperatures and air relative humidities in order to reproduce the natural drying conditions. The experiments improve the understanding of the vapour transfers kinetics between the soil samples and the atmosphere. The experimental results are analysed assuming that the transfers take place in a boundary layer existing at the surface of the porous medium. The influence of the thermal conditions on the evaporation is also taken into account. In our model, coupled vapour and energy exchanges are controlled by mass and heat transfer coefficients characterizing the boundary layer. These coefficients are determined from the drying experiments. The modelling of the drying tests in non‐isothermal conditions is performed in order to validate the formulation of the vapour and heat exchanges. The numerical results present a good agreement with the kinetic of the materials desaturation determined during the tests. The analysis of the moisture transport mechanisms into the sample and at the boundary shows that at the beginning of the test, the drying is first achieved by the transport of moisture in its liquid form and its evaporation at the sample outer boundary in contact with the atmosphere. In a second step, vapour diffusion becomes predominant into the sample and it corresponds to the most important decrease of relative humidity. Copyright © 2009 John Wiley & Sons, Ltd.     

Pattern‐process relationships in surface hydrology: hydrological connectivity expressed in landscape metrics

The degree of hydrological connectivity is mainly determined by the spatial organisation of heterogeneity. A meaningful and aggregate abstraction of spatial patterns is one of the promising means to gain fundamental insights into this complex interaction and can, moreover, be used as a tool to acquire a profound understanding of the major controls of catchment hydrology. In order to disclose such controls, pattern‐process relationships and the explanatory power of landscape metrics were tested by simulating the runoff of differently patterned virtual basins, generated by neutral landscape models and fractal networks and solved by a surface hydrological model composed of kinematic wave routing and Green‐Ampt infiltration. A total of 23 landscape metrics quantified the spatial patterns and were subsequently related to the functional connectivity, assessed as the proportion of internal runoff generation constituting the hydrological response at the outlet. Landscape metrics allowed the identification of dominant features of heterogeneity that explained the observed connectivity, and to disclose changes in control with class abundance. Therefore, landscape metrics are a useful tool for basin comparison and classification in terms of the dominant processes and the corresponding model structure requirements. Copyright © 2011 John Wiley & Sons, Ltd.     

Early diagenesis in rapidly accumulating sediments on the Alboran slope, ODP site 976

The oxidation and reduction that occur during early diagenesis of sediments has been studied in the interstitial waters of a rapidly accumulating sedimentary sequence from the Mediterranean margin of Spain. A series of reactions that are mediated by progressively lower free energy derived from oxidation of organic matter is evident in the sedimentary sequence. Iron and manganese are rapidly reduced. Phosphate and alkalinity maxima at a subbottom depth of 15?m indicate maximal organic matter degradation. Methane first appears at ～20?m subbottom after sulfate is depleted, and its concentrations quickly climb.     

Amorphous silicates as a record of solar nebular and parent body processes—A transmission electron microscope study of fine‐grained rims and matrix in three Antarctic CR chondrites

Renazzo‐type (CR) carbonaceous chondrites belong to one of the most pristine meteorite groups containing various early solar system components such as matrix and fine‐grained rims (FGRs), whose formation mechanisms are still debated. Here, we have investigated FGRs of three Antarctic CR chondrites (GRA 95229, MIL 07525, and EET 92161) by electron microscopy techniques. We specifically focused on the abundances and chemical compositions of the amorphous silicates within the rims and matrix by analytical transmission electron microscopy. Comparison of the amorphous silicate composition to a matrix area of GRA 95229 clearly shows a compositional relationship between the matrix and the fine‐grained rim, such as similar Mg/Si and Fe/Si ratios. This relationship and the abundance of the amorphous silicates in the rims strengthen a solar nebular origin and rule out a primary formation mechanism by parent body processes such as chondrule erosion. Moreover, our chemical analyses of the amorphous silicates and their abundance indicate that the CR rims experienced progressive alteration stages. According to our analyses, the GRA 95229 sample is the least altered one based on its high modal abundance of amorphous silicates (31%) and close‐to‐chondritic Fe/Si ratios, followed by MIL 07525 and finally EET 92161 with lesser amounts of amorphous silicates (12% and 5%, respectively) and higher Fe/Si ratios. Abundances and chemical compositions of amorphous silicates within matrix and rims are therefore suitable recorders to track different alteration stages on a submicron scale within variably altered CR chondrites.     

Seismic time‐lapse imaging using interferometric least‐squares migration: Case study

Seismic time‐lapse surveys are susceptible to repeatability errors due to varying environmental conditions. To mitigate this problem, we propose the use of interferometric least‐squares migration to estimate the migration images for the baseline and monitor surveys. Here, a known reflector is used as the reference reflector for interferometric least‐squares migration, and the data are approximately redatumed to this reference reflector before imaging. This virtual redatuming mitigates the repeatability errors in the time‐lapse migration image. Results with synthetic and field data show that interferometric least‐squares migration can sometimes reduce or eliminate artifacts caused by non‐repeatability in time‐lapse surveys and provide a high‐resolution estimate of the time‐lapse change in the reservoir.     

Full‐waveform inversion with multisource frequency selection of marine streamer data

The theory and practice of multisource full‐waveform inversion of marine supergathers are described with a frequency‐selection strategy. The key enabling property of frequency selection is that it eliminates the crosstalk among sources, thus overcoming the aperture mismatch of marine multisource inversion. Tests on multisource full‐waveform inversion of synthetic marine data and also the Gulf of Mexico data show speedups of 4 × and 8 × , respectively, compared with conventional full‐waveform inversion.     

Probabilistic models for structures with bilinear demand-intensity relationships

An extension to the existing SAC/FEMA expressions to estimate mean annual frequency of exceedance (MAFE) for a given limit state is described. In specific, this study pertains to structural systems whose demand versus seismic intensity relationship cannot be reasonably represented by a linear fit in logspace, but rather a bilinear fit over the entire range of structural response. Using a predefined limiting intensity, the median demand is separated into two distinct zones of response. These expressions are derived using a second-order polynomial hazard model fit and can be considered a further extension of the closed-form expressions available in the literature. The steps in the derivation are described along with an example application of the proposed expressions. Comparing different models shows that the MAFE can be significantly misrepresented when using a linear demand-intensity model for systems whose behaviour deviates from this assumption in logspace. Similarly, a logarithmic function demand-intensity fit is examined and seen not to be suitable in the specific situations focused on here. Furthermore, significant underestimation or overestimation is observed when using local fits in the vicinity of the behaviour transition point, which highlights the need for such a bilinear model when assessing the structural performance at the transition point's vicinity. Adopting a bilinear model is shown to better represent structural systems with complex response characteristics, also allowing the use of a single demand model for the entire range of response. This is at the same time still compatible with the existing framework for performance-based seismic design and assessment.     

A Spatial Analysis System for Integrating Data,Methods and Models on Environmental Risks and Health Outcomes

Integrating data on health outcomes with methods of disease mapping and spatially explicit models of environmental contaminants are important aspects of environmental health surveillance. In this article, we describe a modular, web‐based spatial analysis system that uses GIS, spatial analysis methods and software services delivered over computer networks to achieve this end. The Environmental Health Surveillance System (EHSS) is a prototype system that is designed to serve three purposes: a secure environment for producing maps of disease outcomes from individual‐level data while preserving privacy; an automated process of linking environmental data, environmental models, and GIS tasks like geocoding for the purposes of estimating individual exposures to environmental contaminants; and mechanisms to visualize the spatial patterns of disease outcomes via Web‐based mapping interfaces and interactive tools like Google Earth.     

Evolution of the Galactic Halo and Disk

Correlations between stellar kinematics and chemical abundances are fossil evidence for evolutionary connections between Galactic structural components. Extensive stellar surveys show that the only tolerably clear distinction between galactic components appears in the distributions of specific angular momentum. Here the stellar metal-poor halo and the metal-rich bulge are indistinguishable from each other, as are the thick disk and the old disk. Each pair is very distinct from the other. This leads to an evolutionary model in which the metal-poor stellar halo evolves into the inner bulge, while the thick disk is a precursor to the thin disk. These evolutionary sequences are distinct. The galaxy is made of two discrete 'populations', one of low and one of high angular momentum. Some (minor?) complexity is added to this picture by the debris of late and continuing mergers, which will be especially important in the outer stellar halo.