Chemical ionisation mass spectrometer for measurements of OH and Peroxy radical concentrations in moderately polluted atmospheres

A new version of an atmospheric pressure chemical ionisation mass spectrometer has been developed for ground based in situ atmospheric measurements of OH and total peroxy (HO₂ + organic peroxy) radicals. Based on the previously developed principle of chemical conversion of OH radicals to H₂SO₄ in reaction with SO₂ and detection of H₂SO₄ using an ion molecule reaction with NO₃^─, the new instrument is equipped with a turbulent chemical conversion reactor allowing for measurements in moderately polluted atmosphere at NO concentrations up to several ppb. Unlike other similar devices, where the primary NO₃^─ ions are produced using radioactive ion sources, the new instrument is equipped with a specially developed corona discharge ion source. According to laboratory measurements, the overall accuracy and detection limits are estimated to be, respectively, 25% and 2 × 10⁵ molecule cm^-3 for OH and 30% and 1 × 10⁵ molecule cm^-3 for HO₂ at 10 min integration times. The detection limit for measurements of OH radicals under polluted conditions is 5 × 10⁵ molecules cm^-3 at 10 min integration times. Examples of ambient air measurements during a field campaign near Paris in July 2007 are presented demonstrating the capability of the new instrument, although with reduced performance due to the employment of non isotopic SO₂.     

Litho- and biofacies analysis of postglacial marine mud using CT-Scanning

Marine silty clay deposited during the Late-Wisconsinian postglacial marine transgression of eastern Québec (Goldthwait Sea) is ubiquitous in the sedimentary column of intertidal zones of the St-Lawrence Estuary. This mud is very compact and limits the penetration of organisms composing the modern Macoma balthica community. In order to describe the characteristics of intertidal sediments containing Goldthwait Sea mud, axial tomography (CT-Scan) is used. CT-Scan is a non-destructive method that can be used to describe sediment characteristics (grain size, mineralogy, primary and secondary sedimentary structures, fabric, shape and roundness, bedding contact), and to obtain high resolution, 3D representations of structures within sediment cores. Based on differences in the densities of analysed materials, the different lithologies, lithofacies, and organisms within the core can be discriminated, and a quantification of the volume occupied by the different components of the material can be made. Here, CT-Scan images provide information on the distribution, orientation and interweaving of thanatocœnosis shell beds that alternate with massive or faintly laminated postglacial marine mud beds, as well as on ichnofacies characteristics. In addition, we show 3D images of bioturbation structures within the recent sediment layer, which is distinguished from the underlying Goldthwait Sea mud. When coupled with conventional sedimentary (grain size statistics) and radiochronological (¹⁴C) analyses, these data provide information which is valuable for identifying depositional processes within sedimentary environments.     

Benthic microbial mats: a possible major component of organic matter accumulation in the Lower Aptian oceanic anoxic event

Oceanic anoxic events (OAEs) throughout the Cretaceous were periods of high organic carbon burial leading to drawdown of atmospheric carbon dioxide and lowering of bottom-water oxygen concentration, thereby enhancing the preservation of organic matter (OM). Two dynamic depositional models have been proposed for these events in the Tethyan domain: one is based on strong thermohaline stratification and low surface productivity, the other on high surface productivity with intensified deep-water circulation. Here, we propose another explanation for the concentration of OM, derived essentially from microscopical observations (scanning electron microscope and transmission electron microscope) in the organic-richest interval of an Early Aptian OAE in central Italy (OAE1a or Selli level, 116 Ma). This high-resolution microscopical study of OM highlights benthic microbial mats as the possible source of organic-rich samples where amorphous OM is the major organic constituent. These mats could be more common in OAE black shales than previously thought.     

Volume and surface sources due to laterally varying boundaries of elastic homogeneous layers

Summary. Various methods have been applied to solve propagation problems in media composed of homogeneous layers, the boundaries of which have slight lateral variations. In this paper, volume sources, introduced in a previous paper to describe the effects of lateral irregularities, are replaced by an equivalent body force and by surface sources concentrated on the irregular boundaries. The surface sources we find are similar to those obtained by Kennett for a two-dimensional structure and we generalize his results to a three-dimensional structure and to the case when an external body force is present.     

Structure de la marge continentale Norvégienne au débouché de la mer de Barentz

Reconstructions of the continents prior to the opening of the Norwegian sea indicate an overlap between the Greenland and the Norwegian continental margins just west of the Barentz sea and imply that the basement of this area is of oceanic origin. Seismic profiling shows an oceanic-type basement covered by thick Tertiary sediments. The sedimentary supply is related to the geological history of the Barentz sea where only little unconsolidated sediments are known. Further south the structures of the present margin are directly related to the early opening of the Norwegian sea.     

Fission track study: heating and denudation of marginal ridge of the Ivory Coast–Ghana transform margin

 Six sandstone blocks sampled during dives along the southern slope of the Ivory Coast–Ghana continental margin have been studied using fission tracks in apatite and zircon. Measurements demonstrate that the rocks were heated above 120°C but below 390°C and cooled quickly. The ages of cooling recorded by the apatite crystals are 90 Ma in the western part of the margin, and 80–70 Ma in the central and eastern part. Heating is interpreted by the heat liberation due to the friction along the active transform fault and by the vicinity of an oceanic spreading center, which slipped along the margin. Cooling is interpreted by two stages of denudation due to minor faults and landslides produced by the increasing of the bathymetric step between the continental margin and the oceanic crust. Received: 12 April 1995 / Revision received: 20 December 1995     

Al speciation in tropical podzols of the upper Amazon Basin: A solid-state Al MAS and MQMAS NMR study

In the upper Amazon Basin, aluminum previously accumulated in lateritic formations is massively remobilised in soils by podzolization and exported in waters. We have investigated the speciation of aluminum in the clay-size fractions of eight horizons of waterlogged podzols lying in a depression of a plateau. The horizons illustrate the main steps involved in the podzolization of laterites. They belong to eluviated topsoil A horizons and illuviated subsoil Bhs, Bh and 2BCs horizons of weakly and better-expressed podzols located at the margin and centre of the depression. For the first time, aluminum speciation is quantitatively assessed in soils by spectroscopic methods, namely FTIR, ²⁷Al magic angle spinning (MAS) and multiple-quantum magic angle spinning (MQMAS), nuclear magnetic resonance (NMR). The results thus obtained are compared to chemical extraction data.Solid-state ²⁷Al MAS NMR spectra enable to distinguish Al bound to organic compounds from that incorporated in secondary mineral phases detected by FTIR. MQMAS experiments additionally show that both chemical shifts and quadrupolar constants are distributed for Al nuclei linked with organic compounds. Similar amounts of chelated Al are obtained from NMR spectra and chemical extractions. The study enables to highlight three major steps in the fate of aluminum. (i) Aluminum is first released by mineral weathering, feeds complexing sites of organic matter and accumulates in subsurface Bhs horizons of weakly expressed podzols (acidocomplexolysis). (ii) Complexes of aluminum with organic matter (Al-OM) then migrate downwards in sandy horizons of better-expressed podzols and accumulate at depth in less permeable 2BCs horizons. (iii) The minor amounts of aluminum present in the 2BCs horizon of the downslope podzol show that aluminum is eventually exported towards the river network, either complexed with organic matter or as Al³⁺ ions after desorption from organic compounds, due to decreasing pH or biodegradation of organic ligands. The direct spectroscopic determination of Al-speciation during the formation of podzolic soils opens new perspectives to trace metal loads in the rivers of the upper Amazon Basin.     

Seismic evidence for stepwise thickening of the crust across the NE Tibetan plateau

We performed a receiver function analysis on teleseismic data recorded along two 550 km-long profiles crossing the northeastern Tibetan plateau. Results from time to depth migration, grid-search V_p/V_s determination and simulated annealing inversion of waveforms, reveal that the crust thickens from ∼50 km near the northern edge of the plateau to ∼80 km south of the Jinsha suture in the Qiang Tang block. Crustal thickening occurs in staircase fashion with steps located beneath the main, reactivated sutures. The V_p/V_s ratio, close to the global continental average does not suggest widespread partial melting but rather a more usual separation between an upper felsic and a lower mafic part within the northeastern Tibetan crust.     

Continuous ambient‐vibration monitoring of the arch dam of Mauvoisin

This paper presents the experimental programme and results of a continuous ambient vibrations recording programme carried out on the 250 m arch dam of Mauvoisin. This project follows a series of previous measurements completed for seven different water levels. An automated system was set up on the dam and the ambient vibrations were recorded twice daily for a period of 6 months. Frequency shifts were tracked throughout the testing period and the effects of the varying water level were identified. The results confirmed the behaviour observed in previous ambient‐ and forced‐vibration tests. The added‐mass effects are overcome by the stiffening of the dam due to increasing hydrostatic pressure for lower reservoir levels. This trend is then reversed for higher water levels. Any temperature‐related effects were not identified. The experimental techniques are briefly described and the frequency identification process and its limitations are discussed. Copyright © 2001 John Wiley & Sons, Ltd.