The Transfiguration continental red-bed Cu–Pb–Zn–Ag deposit,Quebec Appalachians,Canada

The Transfiguration Cu–Pb–Zn–Ag deposit, enclosed within reduced grey sandstone, is associated with continental red beds of the Lower Silurian Robitaille Formation in the Quebec Appalachians, Canada. The Robitaille Formation rests unconformably on foliated Cambro-Ordovician rocks. The unconformity is locally cut by barite veins. The basal unit of the Robitaille Formation comprises green wacke and pebble conglomerate, which locally contain calcite nodules. The latter have microstructures characteristic of alpha-type calcretes, such as “floating” fabrics, calcite-filled fractures (crystallaria) and circumgranular cracks. Massive, grey sandstone overlies the basal green wacke and pebble conglomerate unit, which is overlain, in turn, by red, fine-grained sandstone. Mineralisation occurred underneath the red sandstone unit, chiefly in the grey sandstone unit, as disseminated and veinlet sulphides. Chalcopyrite, the most abundant Cu sulphide, replaced early pyrite. Calcrete, disseminated carbonate and vein carbonate have stable isotope ratios varying from −7.5‰ to −1.1‰ δ¹³C and from 14.7‰ to 21.3‰ δ¹⁸O. The negative δ¹³C values indicate the oxidation of organic matter in a continental environment. Sulphur isotope ratios for pyrite, chalcopyrite and galena vary from −19‰ to 25‰ δ³⁴S, as measured on mineral concentrates by a conventional SO₂ technique. Laser-assisted microanalyses (by fluorination) of S isotopes in pyrite show an analogous range in δ³⁴S values, from −21‰ to 25‰. Negative and positive δ³⁴S values are compatible with bacterial sulphate reduction (BSR) in systems open and closed with respect to sulphate. We interpret similarly high δ³⁴S values for sulphide concentrates (25.1‰) and for vein barite (26.2‰) to result from rapid and complete thermochemical reduction of pore-water sulphate. Two early to late diagenetic stages of mineralisation best explain the origin of the Transfiguration deposit. The first stage was characterised by the ponding of groundwater over the Taconian unconformity, recorded by calcrete and early pyrite formation via BSR in grey sandstone. Early pyrite contains up to 2 wt.% Pb, which is consistent with Pb fixation by sulphate-reducing bacteria. The second stage (II) is defined by the replacement of early pyrite by chalcopyrite, as well as by sulphide precipitation via either BSR or thermochemical sulphate reduction (TSR) in grey sandstone. This event resulted from the synsedimentary fault-controlled percolation and mixing of (1) an oxidising, sulphate-bearing cupriferous fluid migrating per descensum from the red-bed sequence and (2) a hydrocarbon-bearing fluid migrating per ascensum from the Cambro-Ordovician basement. Mixing between the two fluids led to sulphate reduction, causing Cu sulphide precipitation. The positive correlation between Cu and Fe³⁺/Fe²⁺ bulk rock values suggests that Fe acted as a redox agent during sulphate reduction. Stage II diagenetic fluid migration is tentatively attributed to the Late Silurian Salinic extensional event.     

Nouvelles données pétrographiques et structurales sur le magmatisme du Sud du bassin de Morondava (Sud-Ouest de Madagascar)

New petrological and geochemical data are presented on basic igneous rocks from the south of the Morondova basin located in the southwestern part of Madagascar. The structural setting is well defined and, with the aid of a schematic map, the spatial relationships between the magmatic centres and major faults can be deduced from seismic data. On the other hand, new petrographic and geochemical data enable the different types of basaltic magmatism manifested in this area to be distinguished. It appears that tholeiitic magmatism evolved towards transitional magmatism from the south to the north of the Morondava basin. This geochemical evolution of basaltic magmatism can be linked to the initiation of rifting between Madagascar and Africa along the Mozambique channel and the length of the Davie ridge associated with the opening of the Indian ocean. These observations, together with structural data and recently obtained geochronological data, contribute to a better understanding of the mechanism and evolution of Madagascan rifting.     

U-series disequilibrium in arc magmas induced by water-magma interaction

Volcanic rocks from subduction zones are widely believed to originate by partial melting of mantle lherzolite modified by the addition of a fluid or melt extracted from the down-going slab. U-series disequilibrium in such magmas is commonly attributed to this particular melting process. A detailed study of U-series isotopes in the 650 y. B.P. eruptive sequence of Mt. Pelée (Martinique) shows that plinian products are in radioactive equilibrium, whereas dome-forming products of the same eruption are characterized by ²³⁸U-²³⁰Th disequilibrium. The same features apply to other plinian and dome-forming products of this volcano and systematically correspond to different eruptive styles. We attribute these characteristics to variable superficial interaction of magmas with the hydrothermal system during the final stages of eruption rather than to deep magma genesis processes. This conclusion might be generally applicable to arc magmas.     

Ophiolites and the oceanic crust: New evidence from the Tyrrhenian sea and the Western Alps

The succession recovered in ODP hole 107–651 in the young oceanic Vavilov basin (Tyrrhenian Sea) comprises, beneath a thick Pleistocene to Upper Pliocene sedimentary cover (chiefly volcanoclastics), four basement units: (1) MORB-type basaltic pillows and breccias; (2) a complex succession made of dolerites, albitites, basaltic breccias, metadolerite pebbles (including an intercalated sandy layer with periodotite clasts); (3) MORB-type basaltic pillows and breccias; (4) highly serpentinized peridotite. Between units 3 and 4, granitoid pebbles occur.This sequence is surprisingly similar to successions known in the Western Alps' Tethyan ophiolites. There, the sediments (Callovian-Oxfordian radiolarian cherts) lie stratigraphically upon breccias mostly derived from underlying serpentinite, and sometimes gabbroic basement. At some places, thin basaltic (tholeiitic) pillows and breccias occur between the radiolarian cherts and the breccias.From the comparison between a present day setting (the central Tyrrhenian Sea) and a formerly emplaced basement succession (the Western Alps), we stress the following (a) both the here-discussed ophiolites and oceanic basement are different from classical ophiolite sequences; (b) both occurrences imply unroofing of mantle rocks that therefore were directly outcropping on the seafloor; (c) such a comparison may indicate a very slow spreading rate for the Alpine Tethyan ocean.     

On the product of legender functions as encountered in geodynamics

Résumé On rencontre souvent des produits de fonctions de Legendre en géodésie mathématique, en mécanique céleste et quantique, et en géophysique. Nous donnons les expressions générales des coefficients de la décomposition d'un produit quelconque sur la base des fonctions de Legendre ellesmêmes. Quelques applications immédiates sont envisagées.     

Evolution cristallochimique des amphiboles dans la série granitique de Fort-Trinquet (Mauritanie)

The precambrian postorogenic pluton of the Fort-Trinquet area (Northern Mauretania) is composed by a series of granitic rocks in which amphiboles are the characteristic mafic minerals. Twenty six amphiboles have been separated and chemically analysed; the optical properties and the unit-cell data are also given.The crystallographic and chemical differences between these minerals reflect the variations in bulk composition of the host-rocks. In the plutonic suite, two igneous trends have been recognized: 1) a granitic trend (quartz monzonite-adamellite-granite) and 2) a syenitic trend (syenite-quartz bearing syenite-alkali granite). The amphiboles of the first trend belong to the tremolite-hastingsite series; they become richer in hastingsite mole with increasing proportion of quartz and decreasing Mg/(Mg+Fe) ratio in the rocks. The granitoids of the second trend are characterized by the occurrence of two amphiboles: a primary prismatic green-coloured actinolitic hornblende generally surrounded by a dark blue rim of riebeckite composition; the riebeckite may also form some acicular crystals associated to needles of stilpnomelane. These coexisting amphiboles would result from autometasomatic reactions which affected the rocks of the syenitic trend and which gave rise to the late alkali pegmatites where the constituent is a low arfvedsonitic riebeckite. The major substitutions involved in that amphibole transformation are Na^x R³⁺Ca^x R²⁺ and Na^xSiCa^xAl^IV.Comparison with experimental data allows to estimate the physical conditions during the emplacement and the tardimagmatic evolution of this granitoid series.     

Considerations generales sur la distribution de l'uranium dans les roches granitoides

Using definite examples the authors show that it is possible to find, in a given granite, relations between uranium and the other elements, but these relations cannot be generalized. They cannot depend on the petrographical and mineralogical properties rather than on the chemical composition. One finds with the essential minerals some apparent relations but they are valid only for a given rock. The nature of a granite depends, mainly, on its formation and consequently on the original material from which it derived. The present data on radioactivity of granites cannot be generalized.