Geological and geophysical studies of the Agoudal impact structure (Central High Atlas,Morocco): New evidence for crater size and age

Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km²) and 1:15,000 (2.25 km²) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (³⁶Cl) constrain the local erosion rates between 220 ± 22 m Ma^?1 and 430 ± 43 m Ma^?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data.     

Efficient propagation of error covariance matrices of gravitational models: application to GRACE and GOCE

We have applied efficient methods for computing variances and covariances of functions of a global gravity field model expanded in spherical harmonics, using the full variance–covariance matrix of the coefficients. Examples are given with recent models derived from GRACE (up to degree and order 150), and with simulated GOCE derived solutions (up to degree and order 200).     

Sedimentary organic matter distributions,burrowing activity,and biogeochemical cycling: Natural patterns and experimental artifacts

The coupling between biogenic reworking activity and reactive organic matter patterns within deposits is poorly understood and often ignored. In this study, we examined how common experimental treatments of sediment affect the burrowing behavior of the polychaete Nephtys incisa and how these effects may interact with reactive organic matter distributions to alter diagenetic transport – reaction balances. Sediment and animals were recovered from a subtidal site in central Long Island Sound, USA. The upper 15 cm of the sediment was sectioned into sub-intervals, and each interval separately sieved and homogenized. Three initial distributions of sediment and organic substrate reactivity were setup in a series of microcosms: (1) a reconstituted natural pattern with surface-derived sediment overlying sediment obtained from progressively deeper material to a depth of 15 cm (Natural); (2) a 15 cm thick sediment layer composed only of surface-derived sediment (Rich); and (3) a 15 cm thick layer composed of uniformally mixed sediment from the original 15 cm sediment profile (Averaged). The two last treatments are comparable to that used in microcosms in many previous studies of bioturbation and interspecific functional interaction experiments. Sediment grain size distributions were 97.5% silt-clay and showed no depth dependent patterns. Sediment porosity gradients were slightly altered by the treatments. Nepthys were reintroduced and aquariums were X-rayed regularly over 5 months to visualize and quantify spatial and temporal dynamics of burrows. The burrowing behaviour of adult populations having similar total biovolume, biomass, abundance, and individual sizes differed substantially as a function of treatment. Burrows in sediment with natural property gradients were much shallower and less dense than those in microcosms with altered gradients. The burrow volume/biovolume ratio was also lower in the substrate with natural organic reactivity gradients. Variation in food resources or in sediment mechanical properties associated with treatments, the latter in part coupled to remineralization processes such as exopolymer production, may explain the burrowing responses. In addition to demonstrating how species may respond to physical sedimentation events (substrate homogenization) and patterns of reactive organic matter redistribution, these experiments suggest that infaunal species interactions in microcosms, including the absolute and relative fluxes of remineralized solutes, may be subject to artifacts depending on exactly how sediments are introduced experimentally. Nonlocal transport and cylinder microenvironment transport – reaction models readily demonstrate how the multiple interactions between burrowing patterns and remineralization rate distributions can alter relative flux balances, decomposition pathways, and time to steady state.     

Evaluation of antifouling properties of non-toxic marine paints

The most common way to prevent biofouling of immersed surfaces is to coat the exposed surfaces with a paint containing a biocide acting on marine organisms by diffusion into the surrounding water. However diffusion of toxins into the marine environment causes pollution and serious economic problems. This paper outlines the anti-microfouling properties of some insolubilized quaternary ammonium salts (grafted onto a vinyl copolymer by means of a covalent non-hydrolyzable bond). After immersion times in sea-water up to 4 months, the microbial cover was limited to bacterial forms, without microalgae or cyanobacteria as observed on the untreated, or tin-salt painted surfaces. Bacteria are mostly on unicell forms and numerous areas appear free of any microorganisms. As microbiofouling is an obligate step to macrofouling, this unleachable antifouling treatment could result in a prolonged protection.     

Criterion of stability and implementation issues of hybrid frequency-time-domain procedure for non-linear dynamic analysis

A criterion of stability pertaining to the hybrid frequency-time-domain procedure is derived. It stems from the initial-value theorem on one side and from the condition of convergence which applies to the harmonic counterpart of the procedure on the other side. The criterion depends on the dynamic stiffnesses of both the original non-linear system and the pseudo-linear system evaluated at the Nyquist frequency. Since at this frequency both stiffnesses are usually controlle by the mass, the criterion of stability is satisfied for most structural systems. The procedure must, however, be applie sequentially to individual time segments. The validity of this criterion is confirmed by a numerical investigation performe for a SDOF system. The solution of non-linear dynamic problems requires consideration of implementation issues which are also discusse in the paper. The analysis of a non-linear soil-structure-interaction system in which the soil's stiffness coefficients an directly defined in the frequency domain also demonstrates the accuracy of the hybrid frequency-time-domain procedure.     

Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.     

Nonlinear least-squares method via an isomorphic geometrical setup

The resolution of a nonlinear parametric adjustment model is addressed through an isomorphic geometrical setup with tensor structure and notation, represented by a u-dimensional “model surface” embedded in a flat n-dimensional “observational space”. Then observations correspond to the observational-space coordinates of the pointQ, theu initial parameters correspond to the model-surface coordinates of the “initial” pointP, and theu adjusted parameters correspond to the model-surface coordinates of the “least-squares” point . The least-squares criterion results in a minimum-distance property implying that the vector Q must be orthogonal to the model surface. The geometrical setup leads to the solution of modified normal equations, characterized by a positive-definite matrix. The latter contains second-order and, optionally, thirdorder partial derivatives of the observables with respect to the parameters. This approach significantly shortens the convergence process as compared to the standard (linearized) method.     

Determination of Fluorine in Eighty International Geochemical Reference Samples by Proton Induced Gamma Ray Emission Spectrometry (PIGE)

Fluorine content has been determined non destructively in eighty international geochemical reference samples (GRS) including rocks, soils, sediments, minerals and ores, by proton induced gamma ray emission spectrometry (PIGE) using the nuclear reaction ¹⁹F(p,αγ) ¹⁶O. Under our operating conditions, the detection limit is around 25 ppm. Our analytical results are compared with the presently preferred values when available or with other published data. The general agreement between this work and reported values is reasonably good. The present paper includes results on several GRS for which existing data are rather scarce or even inexistant.     

Sites occupancy of Fe3+ in Garfield Nontronite: A spectroscopic study

New data on the structure of Garfield nontronite have been produced by the use of different spectroscopic techniques: Mössbauer spectroscopy, optical spectroscopy, X-ray absorption edges and EXAFS and NMR. The tetrahedral iron content is found to be no higher than 1 percent. All iron atoms belong to the octahedral sheet excluding the possibility of the presence of non crystallized phases. Some ambiguities remain about the coherence of the octahedral sheet because of the presence of two doublets in the Mössbauer spectrum and at least two lineshapes in NMR spectra of OH which correspond to different environments.