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51.
    
The Shangqiu area, situated on the alluvial plain of the lower Yellow River, is traditionally considered the center of the predynastic and early Shang culture. Archaeologic remains dating to predynastic and dynastic Shang periods, however, have remained elusive. The current pattern of Neolithic and Bronze Age sites is characterized by their upland settings; and it has been often assumed that the area had the same landscape from the Neolithic through recent historic time. The potential impact of geomorphic processes on these early sites has been hardly considered in developing archaeologic models of temporal and spatial distribution of these sites. This article first presents a reconstruction of the Holocene floodplain history in the archaeologically significant area. On the basis of stratigraphy and sedimentology, a Holocene landscape evolution model is constructed to explore the interrelationship between evolving landscape and archaeologic record of the Neolithic and Bronze Age. The prolonged landscape stability from very late Pleistocene or early Holocene to 2000 yr B. P. provided potential Neolithic and Bronze Age human occupation with a favorable physical environment. After 2000 yr B. P., the hydrologic regime changed and the floodplain experienced 2-3 m of gradual vertical accretion during the following millennium. In response to the dramatic change of hydro-logic regime after the early 12th century A. D., a new floodplain formed by dominantly overbank deposition, and the old floodplain surfaces are covered by as much as ten meters of the younger alluvium. As a result, a pronounced effect has been imposed on the preservation, visibility, and discovery of the Neolithic and Bronze Age sites, including those sites of predynastic and early Shang phases. Thus, much difficulty has been imparted to our understanding of the configuration of these early archaeologic sites. This study demonstrates the usefulness of landscape reconstruction in developing settlement models of Neolithic and Bronze age sites in the area.  相似文献   
52.
    
In order to assess the source of trace elements and to compare uptake between different bivalve species, oysters and mussels were transplanted to five sites in the upper Patuxent River estuary during 1988. Transplant sites were located above and below the discharge of Chalk Point Steam Electric Station (CPSES)—a historic point source for copper. Organisms were sampled approximately monthly for 1 yr and analyzed for copper and silver. During spring and summer, concentrations of silver and copper increased in oysters at the upstream stations. There was very little change in silver and copper concentrations in the mussels with either time or among stations. Copper concentrations accumulated by oysters approached those found during previous periods when CPSES used Cu?Ni alloy condenser tubes (1966–1987), suggesting that corrosion from the Cu?Ni condenser tubes was only a minor contributor to the copper burdens of oysters in the river nearby. The lack of accumulation by mussels at the same sites suggests that part of the reason for the accumulation by oysters may be a taxonomically specific physiological effect caused by the salinity regime in the upper Patuxent.  相似文献   
53.
The Liverpool Plains in northern New South Wales contain some of the best agricultural land in Australia and are underlain by extensive smectite clay-dominated soils sourced from weathering the alkali basalts of the Liverpool Ranges. It had been thought that a relatively simple geological model explained the underlying Cenozoic sequence with salt-rich clays of the Narrabri Formation overlying sands and gravel aquifers comprising the Gunnedah Formation. Extensive groundwater modelling based upon this simple conceptualisation has been used in management plans proposed by the mining and agricultural industries. A 31.5 m core has been recovered using minimally disturbed triple-tube coring methods at Cattle Lane (Latitude –31.52° S, Longitude 150.47° E) to resolve uncertainty concerning the aquitard status of the upper layer. Recovered core has been examined and tested to determine grainsize, cation-exchange capacity, X-ray diffraction, X-ray fluorescence and microscopic examination of granular components. These measurements complement surface and borehole geophysical techniques, hydrogeological data and hydrochemical analysis of water samples recovered from a series of specially constructed piezometers adjacent to the cored hole. The sequence overlies a Late Cretaceous channel cut into Permian bedrock at 91 m depth with sands and clays below 31.5 m considered to represent various alluvial fill events mostly occurring since the Early Pliocene. Erosion of Late Eocene alkali basalts on the Liverpool Ranges, with the formation of smectite clays, pedogenic carbonates and with the addition of quartz from both eolian sources and locally derived from adjacent Triassic sandstone hills, provides the great majority of the sediment recovered from the cores. Late Pleistocene (114 ka) to Holocene ages were determined for the core from three optically stimulated luminescence (OSL) measurements on fine sands (13, 23 and 29 m BG). Detailed examination has failed to detect any evidence of a boundary between Narrabri and Gunnedah formations revealing rather a gradual change in dominance of clays and silts over sands and gravels embedded in a clay-rich matrix. This result challenges the conceptualisation used to conduct groundwater modelling on the Liverpool Plains.  相似文献   
54.
    
The paper reports newly obtained K-Ar isotopic-geochronological data on the age of three lava flows (Khrami, Mashavera, and Kura), which begin at the Dzhavakheti volcanic highland in southern Georgia. All of the dated rocks, including those from the Kura Flow, which was previously considered as the Pleistocene, are demonstrated to have a Pliocene age. The lavas of the longest Khrami Flow were erupted at 3.25–3.10 Ma, and those of the Kura and Mashavera Flows at 2.20–2.05 Ma, a fact testifying to two pulses of volcanic activity at the Dzhavakheti Highland. The petrogeochemical and isotopic characteristics of the rocks (87Sr/86Sr = 0.7039–0.7042; ∈Nd = 3.4–5.1) indicate that they are subalkaline within-plate basalts formed by the fractional crystallization of a basic mantle melt with the usually discontinuous selective or rarely continuous contamination with material that was not in geochemical equilibrium with the melt. The volcanics of the Khrami Flow are characterized by the less radiogenic Sr isotopic composition and the highest ∈Nd values, while the younger rocks of the Mashavera and Kura Flows have similar and more “crustal” isotopic signatures. The 87Sr/86Sr ratios of the Dzhavakheti subalkaline basalts are close to the initial Sr isotopic ratios of the Quaternary and Middle Pliocene dacite lavas from the same territory. Considered together with petrogeochemical and geological data, this suggests that all young rocks in Southern Georgia were produced in similar tectonic and geodynamic environments.  相似文献   
55.
    
The decomposition of palmitic (C16), stearic (C18) and behenic (C22) acids with and without montmorillonite was studied in an inert atmosphere under isothermal (250 C) “bulk flow” conditions, using a CDS-820ZA automated pyro-analyser. The C8C21 hydrocarbons and the CO2 evolved were determined. It appears that in this open system montmorillonite affected the retention time of the acids and hence the kinetics of the reactions rather than the nature of the hydrocarbons formed. The reaction kinetics were very sensitive to changes in experimental conditions.The rate of hydrocarbon formation depended on the chain length of the carboxylic acid. In the absence of montmorillonite palmitic acid tended to sublimate before appreciable amounts of hydrocarbons were formed, stearic acid decomposed to give a range of n alkanes and alkanes while behenic acid yielded only very minor amounts of hydrocarbons. The presence of montmorillonite retarded hydrocarbon evolution with stearic acid. The hydrocarbon with one carbon atom less than the parent acid predominated in all one hour runs and the yield was increased by the presence of montmorillonite. The amount of CO2 evolved never exceeded 10% of the maximum possible. It appears that the reaction mechanism is complex with several processes occurring concurrently.  相似文献   
56.
    
The valence and distribution of iron in vivianite, lazulite, babingtonite, rockbridgeite, acmite, aegirine-augite, hedenbergite, and ilvaite were studied with optical and Mössbauer spectroscopy. Optically activated intervalence charge transfer between Fe2+ and Fe3+ in neighboring sites through common edges or faces is observed in all these minerals irrespective of the polymerization of the iron-oxygen polyhedra ranging from finite clusters to infinite structural units. However, a distinct decrease occurs in the energy of the corresponding optical absorption band with increasing number of Fe2+ and Fe3+ ions involved in the charge transfer process. Thermally activated electron delocalization between Fe2+ and Fe3+ occurs only if Fe2+ and Fe3+ occupy crystallographically equivalent or geometrically very similar neighboring sites which share common edges to form extended structural units such as the ribbon in ilvaite. If the Fe-O polyhedra form finite clusters of two, three, or four polyhedra (e.g., in vivianite, lazulite, and babingtonite, respectively) no thermally-activated mixed-valence states of iron are observed. In aegirine, extended regions of the M1 chain are statistically occupied by Fe2+ and Fe3+ giving rise to thermally-activated electron delocalization in addition to the intervalence band in the optical absorption spectrum. The intensity of the optical intervalence absorption has been measured in a number of systems: ? values range from 60 to 210.  相似文献   
57.
The paper presents a method of estimating parameters in two competitive functional models. The models considered here are concerned with the same observation set and are based on the assumption that an observation may result from a realization of either of two different random variables. These variables differ from one another at least in the main characteristic (for example, outliers can be realizations of one variable). A quantity that describes the opportunity of identifying a single observation with one random variable is assumed to be known. That quantity, called the elementary split potential, is strictly referred to the amount of information that an observation can provide about two competitive assumptions concerning the observation distribution. Parameter assessments that maximize the global elementary split potential (concerning all observations), are called M split estimators. A generalization of M split estimation presented in the paper refers to the theoretical foundation of M-estimation. An erratum to this article can be found at  相似文献   
58.
59.
    
A total of 120 grab samples of the surficial sediments in the Cap-Breton submarine canyon and surrounding continental shelf were collected and analyzed by grain-size sieving. A Q-mode Factor Analysis was made on the grain-size data in order to define the most meaningful facies types. Four distinct lithological facies were found to exist: silt and clay, very fine sand, fine sand, and coarse sand. Comparison with previous work and a 14C date on the silt and clay facies showed that the facies are not contemporaneous. The sands and coarse sands on the shelf were emplaced during the pre-Würm and Würm regressions, and later probably reworked during the Holocene (Flandrian) transgression. The silty clays found in the canyon and on the shelf to the south are younger and represent sediments brought in as suspended load by the Adour and other nearby rivers during the Holocene (Flandrian) transgression.  相似文献   
60.
    
Fruiting of cotton plant is determined and influenced by cultivar, climatic conditions, management practices and pests. An understanding of the flowering and boll retention patterns of cotton cultivars can contribute to more efficient and economical crop management. The objective of this investigation was to study the effect of various climatic factors on flower and boll production of Egyptian cotton. This could be used in formulating advanced predictions of the effect of certain climatic conditions on the production of Egyptian cotton. Two uniform field trials, using cotton Gossypium barbadense cv. Giza 75 were carried out in 1992 and 1993 at the Agricultural Research Station, Agricultural Research Center, Ministry of Agriculture, Giza, Egypt, to investigate the relationships between climatic factors, flower and boll production. Climatic factors included maximum and minimum air temperatures along with their difference, evaporation, surface soil temperature (grass temperature or green cover temperature) at 0600 and 1800 h°C−1, sunshine duration, maximum and minimum humidity and wind speed. The effects of climatic factors on flower and boll production were quantified in the absence of water and nutritional deficits and damage effects of insects. Results obtained indicate that evaporation, sunshine duration, humidity, surface soil temperature at 1800 h, and maximum air temperature, were the important climatic factors that significantly affect flower and boll production of Egyptian cotton. Consequently, applying appropriate specific cultural practices that minimize the deleterious effect of these factors will lead to an improvement in cotton yield.  相似文献   
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