Pahoehoe and aa in Hawaii: volumetric flow rate controls the lava structure

The historical records of Kilauea and Mauna Loa volcanoes reveal that the rough-surfaced variety of basalt lava called aa forms when lava flows at a high volumetric rate (>5–10 m³/s), and the smooth-surfaced variety called pahoehoe forms at a low volumetric rate (<5–10 m³/s). This relationship is well illustrated by the 1983–1990 and 1969–1974 eruptions of Kilauea and the recent eruptions of Mauna Loa. It is also illustrated by the eruptions that produced the remarkable paired flows of Mauna Loa, in which aa formed during an initial short period of high discharge rate (associated with high fountaining) and was followed by the eruption of pahoehoe over a sustained period at a low discharge rate (with little or no fountaining). The finest examples of paired lava flows are those of 1859 and 1880–1881. We attribute aa formation to rapid and concentrated flow in open channels. There, rapid heat loss causes an increase in viscosity to a threshold value (that varies depending on the actual flow velocity) at which, when surface crust is torn by differential flow, the underlying lava is unable to move sufficiently fast to heal the tear. We attribute pahoehoe formation to the flowage of lava at a low volumetric rate, commonly in tubes that minimize heat loss. Flow units of pahoehoe are small (usually <1 m thick), move slowly, develop a chilled skin, and become virtually static before the viscosity has risen, to the threshold value. We infer that the high-discharge-rate eruptions that generate aa flows result from the rapid emptying of major or subsidiary magma chambers. Rapid near-surface vesiculation of gas-rich magma leads to eruptions with high discharge rates, high lava fountains, and fast-moving channelized flows. We also infer that long periods of sustained flow at a low discharge rate, which favor pahoehoe, result from the development of a free and unimpeded pathway from the deep plumbing system of the volcano and the separation of gases from the magma before eruption. Achievement of this condition requires one or more episodes of rapid magma excursion through the rift zone to establish a stable magma pathway.     

Raman scattering study of the high-temperature vibrational properties and stability of CaGeO3 perovskite

The vibrational properties of metastable Ca-GeO₃ perovskite are investigated as a function of temperature using Raman scattering. Mode-assignments are derived from polarized spectra of optically oriented single crystals. Neither symmetry-breaking structural transformations nor soft-mode behavior is revealed in the Raman spectra between room temperature and 650° C. Only a small decrease in the local static octahedral tilt angles can be inferred from the Raman data over this temperature range. A Landau extrapolation of the lowest frequency A_g modes suggests that these modes become critical near 2000° C, a temperature that is above the extrapolated zero pressure melting point.     

The politics of urban entrepreneurialism in Glasgow

North American literature on the changing role of the local state these past two decades has been dominated by the view of a transition from urban managerialism to urban entrepreneurialism. Associated with the transition has been the emergence of a New Urban Politics (NUP). Within a political economy framework. the NUP has been rooted in the material redistributive effects of the transition. This paper explores the character of this NUP, as experienced by one British city, and highlights some fundamental differences with the established political economy reading. Our argument, based upon the city of Glasgow, draws attention to two distinctive features. First, the institutional structure of urban governance in Glasgow differs from that of cities in the United States. In Glasgow, it has been the Left controlled local Council which has orchestrated the transition to entrepreneurialism, rather than the North American model of a coalition between local capital and the local state. Secondly, the transition in Glasgow has been marked not by a significant transfer of local state revenue from service provision to local economic development, but by a symbolic reorientation of the local state as marked by the central importance of large place marketing hallmark events. These events represent the city in ways which differ from traditional ‘self’ identities. Consequently, the transition has evoked a political response which has focused upon the symbolic posturing of the local state rather than the material consequences of the shift. In focusing upon local identity, the politics of urban entrepreneurialism in Glasgow points to a dimension of conflict which has received inadequate treatment in accounts of the NUP to date.     

The warming of the industrialized middle latitudes 1985–2050: Causes and consequences

The dominant influence on global climate for the indefinite future is expected to be a warming in the middle and high latitudes of both hemispheres. The speed of the warming is uncertain. The warming in winter may exceed 1.0 degree per decade. The warming in summer is expected to be less. The cause is the accumulation of infra-red absorptive gases, especially CO₂ and CH₄, in the atmosphere. The sources are the combustion of fossil fuels, the destruction of forests and their soils, and, possibly, the warming itself, which can be expected to stimulate decay of organic matter in soils. The warming in these latitudes is expected to be accompanied by increased precipitation as climatic zones migrate generally poleward. A 1 °C change in mean temperature is equivalent to a change in latitude of 100–150 km. The changes expected are rapid enough to exceed the capacity of forests to migrate or otherwise adapt. Forest trees will die at their warmer and drier limits of distribution more rapidly than forests can be regenerated in regions where climates become favorable. The destruction of forests will add further to the releases of C to the atmosphere. There is no equivalent countervailing storage that has been identified. The result suggests that a significant enhancement of the warming beyond current predictions is to be expected. An open-ended, accelerating warming of the Earth at rates that bring rapid changes in climatic zones, drive forests to impoverishment, and raise sea level rapidly is beyond the limits of simple adjustments of the human enterprise. Steps to stabilize the atmospheric composition seem inevitable. Because the total emissions of C to the atmosphere are not known, the current rate of transfer from the atmosphere to the oceans is uncertain. But whatever the current total release to the atmosphere, the annual atmospheric increase is about 3.0 G-tons of C as CO₂. At least three possibilities exist for reducing or eliminating the imbalance and moving toward long-term stability:

1. a reduction in the use of fossil fuels globally, now estimated as the source of about 5.6 G-tons of C annually;
2. a reduction or cessation of deforestation, now estimated as releasing 1–3 G-tons annually;
3. a vigorous program of reforestation that would remove from the atmosphere into storage in plants and soils about 1 G-ton of C annually for each 2 × 10⁶ km² tract reforested.

Further adjustments in emissions will be appropriate as experience accumulates. Such steps are appropriate now and possible. They will bring widespread ancillary benefits to the human enterprise.     

Some models of the geomagnetic field in western Europe from 1960 to 1980

Achache et al.'s averages over 10 west European observatories of the annual mean magnetic components X, Y, Z are studied from 1953 to 1979. A 1970 jerk is fitted to the data by least squares, and the fit is quantitatively compared with that of a polynomial having the same number of free parameters as the jerk (a quintic). A crude correction for the 11-y sunspot cycle is also attempted. The jerk and quintic are equally good fits to X, the jerk is clearly better for Y, and the quintic is modestly better for Z. The jerk amplitudes of X and Z but not Y depend heavily on whether a sunspot correction is made, and such a correction may be required to estimate the energy of the internal part of the jerk in the manner of Malin and Hodder. The sunspot correction to Y probably cannot be brought above the noise because it is small and highly correlated with both the jerk and the quintic. The sunspot corrections to X and Z are statistically significant but depend on whether the core signal is taken as a jerk or a quintic. Courtillot and Le Mouël's physical model for the jerk predicts that the jerk amplitudes of X, Y, Z will be proportional to the longitudinal derivatives of X, Y and Z. This prediction is roughly verified for the magnitudes but not the signs; it is just possible that the signs in X and Z are not statistically significant.     

Tank damage during the may 1983 coalinga earthquake

The magnitude M = 6-5 Coalinga earthquake of 2 May 1983 caused intense ground shaking throughout the epicentral region. Unanchored cylindrical ground supported tanks located at six sites within this oil producing area were damaged; damages included elephant's foot buckling at the base of three moderate sized tanks, joint rupture and top shell buckling in one large old rivetted tank, bottom plate rupture of a relatively new welded tank and damage to the floating roofs of 11 tanks. Also oil spilled over the top of many tanks and secondary damages occurred in pipe connections, ladders, etc. In this paper an estimate is made of the intensity of ground motion at each of the tank sites, based on strong motion records made during the main shock and the strongest aftershock. Then response parameters specified by current codes are correlated with the damages observed at each tank site. Based on this comparison, it is concluded that current U.S. practice under-estimates the sloshing response of tanks with floating roofs and does not adequately address the uplifting mechanism of unanchored ground supported tanks.     

Hydrogen speciation in synthetic quartz

The dominant hydrogen impurity in synthetic quartz is molecular H₂O. H-OH groups also occur, but there is no direct evidence for the hydrolysis of Si-O-Si bonds to yield Si-OH HO-Si groups. Molecular H₂O concentrations in the synthetic quartz crystals studied range from less than 10 to 3,300 ppm (H/Si), and decrease smoothly by up to an order of magnitude with distance away from the seed. OH^? concentrations range from 96 to 715 ppm, and rise smoothly with distance away from the seed by up to a factor of three. The observed OH^? is probably all associated with cationic impurities, as in natural quartz. Molecular H₂O is the dominant initial hydrogen impurity in weak quartz. The hydrolytic weakening of quartz may be caused by the transformation H₂O + Si-O-Si → 2SiOH, but this may be a transitory change with the SiOH groups recombining to form H₂O, and the average SiOH concentration remaining very low. Synthetic quartz is strengthened when the H₂O is accumulated into fluid inclusions and cannot react with the quartz framework.     

Scattering of seismic waves by cracks in multi-layered geological regions: II. Numerical results

The mechanical model for plane strain, time-harmonic seismic wave propagation problems in cracked, multi-layered geological regions with surface topography and non-parallel interfaces was described in the first part of this work. Here, this model is used to investigate the response of such a region to the presence of traveling elastic waves generated by a seismic source. The computational methodology that was developed in the first part is based on a combination of both the regular (displacement-based) and the hypersingular (traction-based) Boundary Integral Equation Method (BIEM). First, the accuracy and convergence characteristics of this hybrid BIEM are studied. Then, a series of problems involving four different configurations of a reference geological deposit with both interface and internal cracks are solved, for a loading that is due to a seismically-induced pressure wave propagating upwards from the underlying rigid half-plane. The purpose of the numerical study is to investigate the influence of various key parameters of the problem, such as frequency and incidence angle of the incoming wave, size of the surface relief, location and size of the buried cracks, interaction effects between cracks and finally the presence of layers, on both the scattered displacement field and the stress concentration field.