Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

A Cambrian mixed carbonate–siliciclastic platform in SW Gondwana: evidence from the Western Sierras Pampeanas (Argentina) and implications for the early Paleozoic paleogeography of the proto-Andean margin

International Journal of Earth Sciences - The Western Sierras Pampeanas (WSP) of Argentina record a protracted geological history from the Mesoproterozoic assembly of the Rodinia supercontinent to...     

The effect of medium chemistry on the solubility and morphology of brushite crystals

An experimental study of the particulars of the solubility and crystallization of brushite Ca(HPO₄) · 2H₂O from aqueous solution in conditions of a variable pH (6.0–3.0) and the contents of impurity ions (K⁺, Na⁺, NH ₄ ⁺ , Mg²⁺, SO ₄ ^2? , CO ₃ ^2? ) has been conducted. It is established that brushite solubility markedly rises with a decrease in pH from 6 to 3 and slightly rises with an increase in Mg²⁺ and SO ₄ ^2? concentrations. The enrichment in K⁺, Na⁺, and NH ₄ ⁺ does not affect brushite solubility. The changeable chemistry of the medium results in variation of the synthetic crystal habit, from rhombic tabular to thickened prismatic crystals.     

Stress‐dependent hardening and failure surfaces of dry sand

During several triaxial compression experiments on plastic hardening, softening, and failure properties of dense sand specimens, it was found on various stress paths that the size of the failure surface was not constant. Instead, it changed depending on the current state of hydrostatic pressure. This finding is in contrast to the standard opinion consisting of the fact that the failure surface remains constant, once it has been reached during an experiment or in situ. In general, the behaviour of cohesionless granular‐material‐like sand is somehow characterised in between fluid and solid, where the solid behaviour results from the angle of internal friction and the confining pressure. Although the friction angle is an intrinsic material property, the confining pressure varies with the boundary conditions, thus defining different solid properties like plastic hardening, softening, and also failure. Based on our findings, it was the goal of the present contribution to introduce an improved setting for the plastic strain hardening and softening behaviour including the newly found yield properties at the limit state. For the identification of the material parameters, a complete triaxial experimental analysis of the tested sand is given. The overall elasto‐plasticity concept is validated by numerical computations of several laboratory foundation‐ and slope‐failure experiments. The performance of the proposed approach is compared with the standard concept of a constant failure surface, where the corresponding yield surfaces are understood as contours of equivalent plastic work or plastic strain. Copyright © 2012 John Wiley & Sons, Ltd.     

Staurolite porphyroblast controls on local bulk compositional and microstructural changes during decompression of a St–Bt–Grt–Crd–And schist (Ancasti metamorphic complex,Sierras Pampeanas,W Argentina)

The staurolite–biotite–garnet–cordierite–andalusite–plagioclase–muscovite–quartz metapelitic mineral assemblage has been frequently interpreted in the literature as a result of superimposition of various metamorphic events, for example, in polymetamorphic sequences. The assemblage was identified in schists from the Ancasti metamorphic complex (Sierras Pampeanas of Argentina) where previous authors have favoured the polymetamorphic genetic interpretation. A pseudosection in the MnNCKFMASH system for the analysed XRF bulk composition predicts the stability of the sub‐assemblage staurolite–biotite–garnet–plagioclase–muscovite–quartz, and the compositional isopleths also agree with measured mineral compositions. Nevertheless, the XRF pseudosection does not predict any field with staurolite, andalusite and cordierite being stable together. As a result of more detailed modelling making use of the effective bulk composition concept, our interpretation is that the staurolite–biotite–garnet–plagioclase–muscovite–quartz sub‐assemblage was present at peak metamorphic conditions, 590 °C and 5.2 kbar, but that andalusite and cordierite grew later along a continuous P–T path. These minerals are not in mutual contact and are observed in separate microstructural domains with different proportions of staurolite. These domains are explained as a result of local reaction equilibrium subsystems developed during decompression and influenced by the previous peak crystal size and local modal distribution of staurolite porphyroblasts that have remained metastable. Thus, andalusite and cordierite grew synchronously, although in separate microdomains, and represent the decompression stage at 565 °C and 3.5 kbar.     

Quantifying Barrovian metamorphism in the Danba Structural Culmination of eastern Tibet

The Danba Structural Culmination is a tectonic window into the late Triassic to early Jurassic Songpan‐Garzê Fold Belt of eastern Tibet, which exposes an oblique section through a complete Barrovian‐type metamorphic sequence. Systematic analysis of a suite of metapelites from this locality has enabled a general study of Barrovian metamorphism, and provided new insights into the early thermotectonic history of the Tibetan plateau. The suite was used to create a detailed petrographic framework, from which four samples ranging from staurolite to sillimanite grade were selected for thermobarometry and geochronology. Pseudosection analysis was applied to calculate P–T path segments and determine peak conditions between staurolite grade at ～5.2 kbar and 580 °C and sillimanite grade at ～6.0 kbar and 670 °C. In situ U–Pb monazite geochronology reveals that staurolite‐grade conditions were reached at 191.5 ± 2.4 Ma, kyanite‐grade conditions were attained at 184.2 ± 1.5 Ma, and sillimanite‐grade conditions continued until 179.4 ± 1.6 Ma. Integration of the results has provided constraints on the evolution of metamorphism in the region, including a partial reconstruction of the regional metamorphic field gradient. Several key features of Barrovian metamorphism are documented, including nested P–T paths and a polychronic field gradient. In addition, several atypical features are noted, such as P–T path segments having similar slopes to the metamorphic field gradient, and T_max and P_max being reached simultaneously in some samples. These features are attributed to the effects of slow tectonic burial, which allows for thermal relaxation during compression. While nested, clockwise P–T–t loops provide a useful framework for Barrovian metamorphism, this study shows that the effects of slow burial can telescope this model in P–T space. Finally, the study demonstrates that eastern Tibet experienced a significant phase of crustal thickening during the Mesozoic, reinforcing the notion that the plateau may have a long history of uplift and growth.     

Palaeozoic Victoria,Australia: Igneous rocks,ages and their interpretation

A reconnaissance traverse across Victoria yields 160 K‐Ar dates on igneous rocks from 94 localities. These are supplemented by Rb‐Sr dating in critical cases, and major‐element analyses (some new) on a proportion of the samples. All dates quoted in text and tables, new and previously‐published, have been revised in terms of the latest decay‐constant conventions.

The dates range from Early Ordovician (480 Ma) in the west to Late Devonian (360 Ma) among the high‐level intrusives of Central Victoria. The relatively complex age pattern, and the petrochemical character of the rocks, are compared with the published chronology of neighbouring States, and are interpreted in terms of a long‐duration regime of westwards compression, which began in the deformations of the Adelaide System of South Australia, and continued until the Mid‐Devonian Tabberabberan Movement.     

Mesozoic stratigraphy and history of the Canning Desert and Fitzroy Valley,Western Australia

Abstract

Large outcrop areas in the Canning Desert and the Fitzroy Valley of northwestern Australia consist of marine Jurassic and Upper Triassic rocks, not of Permian as formerly believed. On present knowledge, outcrops of the Triassic formations are restricted to parts of the Fitzroy and Bonaparte Gulf Basins, whereas the distribution of Jurassic (Kimmeridgian to Tithonian) rocks provides evidence for a major marine invasion that affected the Canning Desert area and may have advanced into the centre of the Australian continent and beyond. The late Jurassic transgression did not enter the Fitzroy Basin area.

From the distribution and nature of the Mesozoic formations it is concluded that the main phase of post-Permian folding in the Fitzroy Basin is early Triassic. Later movements affected minor northern parts of the Canning Desert area in early Jurassic and in early Cretaceous time.

As an alternative working hypothesis to the traditional basin concept it is suggested that during the Mesozoic the Canning Desert area was an epicontinental shelf platform.     

Application of the revised universal soil loss equation model on landslide prevention. An example from N. Euboea (Evia) Island, Greece

This study aims to evaluate the application of the Revised Universal Soil Loss Equation (RUSLE) on predicting of sites susceptible to slope failures caused by the soil erosion. It was carried out at the northern part of Euboea Island presenting one of the highest frequencies of landslide occurrence in Greece. All required datasets for the application of the RUSLE model were engaged to compile a potential soil erosion map of the study area. In addition, historical slope failure data were used to evaluate the produced map. Moreover, the frequency ratio statistical analysis was applied for the verification of the soil erosion map. The results showed a satisfactory agreement between the soil erosion intensity zones and distribution of landslides events. Therefore, the RUSLE model can be applied for the localization of sites susceptible to landslides that were prepared or triggered by the soil erosion. Finally, taking under consideration the contribution of erosion mechanisms over the landslides manifestation, a combination of measures were proposed for preventing and supporting these catastrophic phenomena.