Reaction-induced fluid flow in synthetic quartz-bearing marbles

The reaction kinetics and fluid expulsion during the decarbonation reaction of calcite+quartz=wollastonite+CO₂ in water-absent conditions were experimentally investigated using a Paterson-type gas apparatus. Starting materials consisted of synthetic calcite/quartz rock powders with variable fractions of quartz (10, 20, and 30 wt%) and grain sizes of 10 µm (calcite) and 10 and 30 µm (quartz). Prior to reaction, samples were HIPed at 700 °C and 300 MPa confining pressure and varying pore pressures. Initial porosity was low at 2.7–6.3%, depending on pore pressure during HIP and the amount and grain size of quartz particles. Samples were annealed at reaction temperatures of 900 and 950 °C at 150 and 300 MPa confining pressures, well within the wollastonite stability field. Run durations were between 10 min and 20 h. SEM micrographs of quenched samples show growth of wollastonite rims on quartz grains and CO₂-filled pores between rims and calcite grains and along calcite grain boundaries. Measured widths of wollastonite rims vs. time indicate a parabolic growth law. The reaction is diffusion-controlled and reaction progress and CO₂ production are continuous. Porosity increases rapidly at initial stages of the reaction and attains about 10–12% after a few hours. Permeability at high reaction temperatures is below the detection limit of 10^–21 m² and not affected by increased porosity. This makes persistent pore connectivity improbable, in agreement with observed fluid inclusion trails in form of unconnected pores in SEM micrographs. Release of CO₂ from the sample was measured in a downstream reservoir. The most striking observation is that fluid release is not continuous but occurs episodic and in pulses. Ongoing continuous reaction produces increase in pore pressure, which is, once having attained a critical value (P_crit), spontaneously released. Connectivity of the pore space is short-lived and transient. The resulting cycle includes pore pressure build-up, formation of a local crack network, pore pressure release and crack closure. Using existing models for plastic stretching and decrepitation of pores along with critical stress intensity factors for the calcite matrix and measured pore widths, it results that P_crit is about 20 MPa. Patterns of fluid flow based on mineralogical and stable isotope evidence are commonly predicted using the simplifying assumption of a continuous and constant porosity and permeability during decarbonation of the rock. However, simple flow models, which assume constant pore pressure, constant fluid filled porosity, and constant permeability may not commonly apply. Properties are often transient and it is most likely that fluid flow in a specific reacting rock volume is a short-lived episodic process.Editorial responsibility: J. Hoefs     

The spectral hardening associated with the westward travelling surge

Photometer recordings of auroral emissions from N⁺₂ and OI have demonstrated that the ratios between the emissions show a characteristic plateau just prior to the passage of a westward travelling surge. The plateau may be interpreted as a temporary (approx. 1 min) cessation in the spectral hardening of the precipitating particles associated with the surge. The characteristic energy of the plateau is about one keV above the level prior to the beginning of the surge. The results have been interpreted in terms of an instability that is switched on during the time of the plateau and then turned off when the electron density is increased above a certain limit.     

The earthquake of Carnuntum in the fourth century a.d. – archaeological results, seismologic scenario and seismotectonic implications for the Vienna Basin fault, Austria

Excavations in the former Roman provincial capital of Pannonia Superior, Carnuntum, 40 km east of Vienna revealed damaged masonry structures from many parts of the ancient settlements. A compilation of structurally damaged buildings has formerly been given by Kandler (Acta Archaeol Acad Sci Hung, 41:313–336, 1989), who related damage to an earthquake in the middle of the fourth century a.d. This paper reviews and supplements these data, and discusses the significance of the style of damage. It is concluded that seismic damage is the only likely interpretation for the damaging mechanism. Although archaeological age dating for the individual collapsed buildings only constrains the timing of their destruction to a few decades around 350 a.d., we assume a single damaging event. In spite of the restrictions on damage assessment by the nature of the archaeological data, it is possible to give a reasonable appraisal of macroseismic intensity. The tentative seismological interpretation of damage leads to an intensity estimate of about nine of the European macroseismic scale (EMS-1998). Comparison with macroseismic data of modern earthquakes in the region, which show a rapid decrease of intensity with distance form the epicentre, indicate a near-by seismic source unless exceptionally high epicentral intensities are assumed for the fourth century event. The most likely source is an active sinistral strike-slip fault (Lassee Fault) passing about 8 km NW of the archaeological site. The fault belongs to Vienna Basin fault system with about 2 mm sinistral movement per year. The system is characterized by fault segmentation and distinct seismicity along the different segments. Moderate seismicity during the last centuries at the southern segments (e.g., Schwadorf 1927, I ₀=8) strongly contrasts from the Lassee fault segment with Carnuntum as the only known severe earthquake. The earthquake of Carnuntum provides evidence for the overall seismic style of deformation along this segment, which previously has not been regarded seismically active. Also, the fourth century earthquake is the strongest event known from the Vienna Basin fault so far.     

Ultrasonic Velocities, Acoustic Emission Characteristics and Crack Damage of Basalt and Granite

Acoustic emissions (AE), compressional (P), shear (S) wave velocities, and volumetric strain of Etna basalt and Aue granite were measured simultaneously during triaxial compression tests. Deformation-induced AE activity and velocity changes were monitored using twelve P-wave sensors and eight orthogonally polarized S-wave piezoelectric sensors; volumetric strain was measured using two pairs of orthogonal strain gages glued directly to the rock surface. P-wave velocity in basalt is about 3 km/s at atmospheric pressure, but increases by > 50% when the hydrostatic pressure is increased to 120 MPa. In granite samples initial P-wave velocity is 5 km/s and increases with pressure by < 20%. The pressure-induced changes of elastic wave speed indicate dominantly compliant low-aspect ratio pores in both materials, in addition Etna basalt also contains high-aspect ratio voids. In triaxial loading, stress-induced anisotropy of P-wave velocities was significantly higher for basalt than for granite, with vertical velocity components being faster than horizontal velocities. However, with increasing axial load, horizontal velocities show a small increase for basalt but a significant decrease for granite. Using first motion polarity we determined AE source types generated during triaxial loading of the samples. With increasing differential stress AE activity in granite and basalt increased with a significant contribution of tensile events. Close to failure the relative contribution of tensile events and horizontal wave velocities decreased significantly. A concomitant increase of double-couple events indicating shear, suggests shear cracks linking previously formed tensile cracks.     

Ground ice and slope sediments archiving late Quaternary paleoenvironment and paleoclimate signals at the margins of El'gygytgyn Impact Crater, NE Siberia

An accumulation terrace close to the El'gygytgyn Impact Crater in northeastern Siberia contains stratigraphic and periglacial evidence of the paleoenvironmental and paleoclimatic history and permafrost dynamics during late Quaternary time. A succession of paleo active-layer deposits that mirror environmental changes records periods favorable for the establishment and growth of ice-wedge polygonal networks and sediment variations. These two elements of the periglacial landscape serve as complementary paleoenvironmental archives that can be traced back to ∼ 14,000 cal yr BP. The slope sediments and the ground ice contained therein have prominent relative maxima and minima in properties (grain size, total organic content, oxygen isotopes). They document a regional early Holocene thermal maximum at about 9000 cal yr BP, followed by a transition to slightly cooler conditions, and a subsequent transition to slightly warmer conditions after about 4000 cal yr BP. Results from sedimentary analysis resemble morphological and geochemical (oxygen and hydrogen isotopes) results from ice wedge studies, in which successive generations of ice-wedge polygonal networks record warmer winters in late Holocene time. Moreover, peaks of light soluble cation contents and quartz-grain surface textures reveal distinct traces of cryogenic weathering. We propose a conclusive sedimentation model illustrating terrace formation in a permafrost terrain.     

Natronamphibol- (Osannit-) Aegirinschiefer in den Tarntaler Bergen

Ohne ZusammenfassungMit 14 Textabbildungen.Aus Raumgründen kann hier nur ein enger Ausschnitt aus der einschlägigen Literatur gebracht werden.     

Three Dimensional Plate Kinematics in Romania

Since 1996 the Collaborative Research Center (CRC) 461``Strong Earthquakes: A Challenge for Geosciences andCivil Engineering' is funded by the DeutscheForschungsgemeinschaft (German Research Foundation) asa German contribution to the UN initiative``International Decade of Disaster Reduction' (IDNDR).A central project of this CRC is the subproject B1``Three Dimensional Plate Kinematics in Romania', whichis installed to detect borders of the geotectonicplates in Romania, to quantify their three-dimensionalmovement rates and to determine in detail thedeformation of each geotectonic unit in the VranceaRegion as a contribution to the research of thetectonic cause of the intermediate depth earthquakesin this region. These aims shall be accomplished byrepeated GPS-measurements in a network which has beeninstalled in 1997 and measured until now in 1997 and1998. This network is consisting of 26 stations,covering an area of 250 km × 380 km with the Vranceaarea as the centre. The geodetic frame is given by sixstations of the CEGRN (Central European GeodynamicRegional Network) of the CEI-initiative CERGOP, forwhich coordinates and velocities in a global tectonicscenario are available. The paper gives informationabout the tectonic background, the geodetic network,the GPS-measurements and the achieved accuracies andfirst results of deformation analyses. It is shownthat until now no significant deformations could bedetected. But the extension of the GPS network andremeasurements with time intervals of two years willallow statements about the recent crustal movementswithin the lifetime of the CRC 461.     

反演寿县TMI微波频率的地表比辐射率(英)

利用一个微波辐射传输模式,晴天下的大气探测廓线,地面的部分观测资料以及卫星观测的亮温,计算了淮河流域能量和水循环实验(HUBEX)中,寿县地区的热带降雨观测卫星微波成像仪(TRMM/TMI)微波频率的地表比辐射率。通过比较所计算的微波地表比辐射率随地表状况的改变,发现地表微波比辐射率随地表状况的变化存在敏感性,并且其变化是合理的。本文中,地表肤温设定等于地表空气温度,并且仅计算了寿县的地表比辐射率,在HUBEX区域上的地表比辐射率的计算需要更多的观测资料。