Heterogeneous tectonic inversion of the Mid-Polish Trough related to crustal architecture, sedimentary patterns and structural inheritance

Using a 3-D structural model, we performed a basin-scale analysis of the tectonically inverted Mid-Polish Swell, which developed above the NW–SE-oriented Teisseyre-Tornquist Zone. The later separates the Paleozoic West European Platform from the Precambrian East European Craton. The model permits a comparison between the present depths and sedimentary thicknesses of five layers within the Permian–Mesozoic and Cenozoic successions. The inversion of the NW–SE-trending Mid-Polish Trough during the Late Cretaceous–Paleogene resulted in uplift of a central horst, the Mid-Polish Swell, bounded by two lateral troughs. These structural features are induced by squeezing of a weak crust along the Teisseyre-Tornquist Zone. The swell is characterized by an inherited segmentation which is due to NE–SW transversal faults having crustal roots. From NW to SE, we distinguish the Pomeranian, Kujavian, and Ma opolska segments, that are separated by two transversal faults. During the inversion, the Zechstein salt occurring in the Pomeranian and Kujavian segments in the NW acted as decoupling level between the basement and the post-salt cover, leading to disharmonic deformation. Conversely, because no salt occurs in the SE, both basement and cover were jointly deformed. The vertical tectonic uplift at the surface is estimated to amount to 3 km in the Ma opolska segment. The structural inheritance of the basement is expressed by the heterogeneous geometry of the swell and tectonic instability during Mesozoic sedimentation. The reasons for the inheritance are seen in the mosaic-type Paleozoic basement SW of the Teisseyre-Tornquist Zone, contrasting the Precambrian East European Craton which acted as a stable buttress in the NE. The horst and trough geometry of Cenozoic sediments blanketing the Mid-Polish swell reveals the ongoing intracontinental compressional stress in Poland.     

Dynamics and inversion of the Mesozoic Basin of the Weald–Boulonnais area: role of basement reactivation

The geometry and dynamics of the Mesozoic basins of the Weald–Boulonnais area have been controlled by the distribution of preexisting Variscan structures. The emergent Variscan frontal thrust faults are predominantly E–W oriented in southern England while in northern France they have a largely NW–SE orientation.Extension related to Tethyan and Atlantic opening has reactivated these faults and generated new faults that, together, have conditioned the resultant Mesozoic basin geometries. Jurassic to Cretaceous N–S extension gave the Weald–Boulonnais basin an asymmetric geometry with the greatest subsidence located along its NW margin. Late Cretaceous–Palaeogene N–S oriented Alpine (s.l.) compression inverted the basin and produced an E–W symmetrical anticline associated with many subsidiary anticlines or monoclines and reverse faults. In the Boulonnais extensional and contractional faults that controlled sedimentation and inversion of the Mesozoic basin are examined in the light of new field and reprocessed gravity data to establish possible controls exerted by preexisting Variscan structures.     

The Elbe Fault System in North Central Europe—a basement controlled zone of crustal weakness

The Elbe Fault System (EFS) is a WNW-striking zone extending from the southeastern North Sea to southwestern Poland along the present southern margin of the North German Basin and the northern margin of the Sudetes Mountains. Although details are still under debate, geological and geophysical data reveal that upper crustal deformation along the Elbe Fault System has taken place repeatedly since Late Carboniferous times with changing kinematic activity in response to variation in the stress regime. In Late Carboniferous to early Permian times, the Elbe Fault System was part of a post-Variscan wrench fault system and acted as the southern boundary fault during the formation of the Permian Basins along the Trans-European Suture Zone (sensu [Geol. Mag. 134 (5) (1997) 585]). The Teisseyre–Tornquist Zone (TTZ) most probably provided the northern counterpart in a pull-apart scenario at that time. Further strain localisation took place during late Mesozoic transtension, when local shear within the Elbe Fault System caused subsidence and basin formation along and parallel to the fault system. The most intense deformation took place along the system during late Cretaceous–early Cenozoic time, when the Elbe Fault System responded to regional compression with up to 4 km of uplift and formation of internal flexural highs. Compressional deformation continued during early Cenozoic time and actually may be ongoing. The upper crust of the Elbe Fault System, which itself reacted in a more or less ductile fashion, is underlain by a lower crust characterised by low P-wave velocities, low densities and a weak rheology. Structural, seismic and gravimetric data as well as rheology models support the assumption that a weak, stress-sensitive zone in the lower crust is the reason for the high mobility of the area and repeated strain localisation along the Elbe Fault System.     

A Rosenbrock‐W method for real‐time dynamic substructuring and pseudo‐dynamic testing

A variant of the Rosenbrock‐W integration method is proposed for real‐time dynamic substructuring and pseudo‐dynamic testing. In this variant, an approximation of the Jacobian matrix that accounts for the properties of both the physical and numerical substructures is used throughout the analysis process. Only an initial estimate of the stiffness and damping properties of the physical components is required. It is demonstrated that the method is unconditionally stable provided that specific conditions are fulfilled and that the order accuracy can be maintained in the nonlinear regime without involving any matrix inversion while testing. The method also features controllable numerical energy dissipation characteristics and explicit expression of the target displacement and velocity vectors. The stability and accuracy of the proposed integration scheme are examined in the paper. The method has also been verified through hybrid testing performed of SDOF and MDOF structures with linear and highly nonlinear physical substructures. The results are compared with those obtained from the operator splitting method. An approach based on the modal decomposition principle is presented to predict the potential effect of experimental errors on the overall response during testing. Copyright © 2009 John Wiley & Sons, Ltd.     

Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction

The mineralogy of natural ferromanganese coatings on quartz grains and the crystal chemistry of associated trace elements Ni, Zn, Ba, and As were characterized by X-ray microfluorescence, X-ray diffraction, and EXAFS spectroscopy. Fe is speciated as ferrihydrite and Mn as vernadite. The two oxides form alternating Fe- and Mn-rich layers that are irregularly distributed and not always continuous. Unlike naturally abundant Fe-vernadite, in which Fe and Mn are mixed at the nanoscale, the ferrihydrite and vernadite are physically segregated and the trace elements clearly partitioned at the microscopic scale. Vernadite consists of two populations of interstratified one-water layer (7 Å phyllomanganate) and two-water layer (10 Å phyllomanganate) crystallites. In one population, 7 Å layers dominate, and in the other 10 Å layers dominate. The three trace metals Ni, Zn, and Ba are associated with vernadite and the metalloid As with ferrihydrite. In vernadite, nickel is both substituted isomorphically for Mn in the manganese layer and sorbed at vacant Mn layer sites in the interlayer. The partitioning of Ni is pH-dependent, with a strong preference for the first site at circumneutral pH and for the second at acidic pH. Thus, the site occupancy of Ni in vernadite may be an indicator of marine vs. continental origin, and in the latter, of the acidity of streams, lakes, or soil pore waters in which the vernadite formed. Zinc is sorbed only in the interlayer at vacant Mn layer sites. It is fully tetrahedral at a Zn/Mn molar ratio of 0.0138, and partly octahedral at a Zn/Mn ratio of 0.1036 consistent with experimental studies showing that the ^VIZn/^IVZn ratio increases with Zn loading. Barium is sorbed in a slightly offset position above empty tetrahedral cavities in the interlayer. Arsenic tetrahedra are retained at the ferrihydrite surface by a bidentate-binuclear attachment to two adjacent iron octahedra, as commonly observed. Trace elements in ferromanganese precipitates are partitioned at a few, well-defined, crystallographic sites that have some elemental specificity, and thus selectivity. The relative diversity of sorption sites contrasts with the simplicity of the layer structure of vernadite, in which charge deficit arises only from Mn⁴⁺ vacancies (i.e., no Mn³⁺ for Mn⁴⁺ substitution). Therefore, sorption mechanisms primarily depend on physical and chemical properties of the sorbate and competition with other ions in solution, such as protons at low pH for Ni sorption.     

Dissolved organic matter fluorescence spectroscopy as a tool to estimate biological activity in a coastal zone submitted to anthropogenic inputs

Here we report on an investigation of the three-dimensional excitation-emission-matrix (EEM) fluorescence spectra of unconcentrated water samples collected in 1996, 1998 and 1999 at a site particularly propitious for macro-algae development. The degradation of these macro-algae was studied to determine the influence of their exudates on natural water EEM fluorescence spectra. This work demonstrates that biological activity is one of the major factors involved in the formation of the blue-shifted fluorescence band observed in marine waters (β component Ex/Em=310–320 nm/380–410 nm); our study also shows that fluorescence can be used to evaluate the biological activity both quantitatively and to determine its different phases.