CMIP5地球系统模式溶解氧模拟结果分析

本文基于常用的统计方法,通过与WOA09观测的海洋溶解氧浓度数据进行比较,定量地评估了9个CMIP5地球系统模式在历史排放试验中海洋溶解氧气候态特征的模拟能力。在海表,由于地球系统模式均能很好地模拟海表温度（SST）,模式模拟的海表溶解氧浓度分布与观测一致,模拟结果无论是全球平均浓度偏差还是均方根误差均接近0,空间相关系数与标准偏差接近1。在海洋中层以及深层这些重要水团所在的区域,各模式的模拟能力则差异较大,尤其在溶解氧低值区（OMZs）所在的500m到1000m,各模式均出现全球平均偏差、均方根误差的极大值以及空间相关系数的极小值。在海洋内部,模式偏差的原因比较复杂。经向翻转环流和颗粒有机碳通量均对模式的偏差有贡献。分析结果表明物理场偏差对溶解氧偏差的贡献较大。一些重要水团,比如北大西洋深水,南极底层水以及北太平洋中层水在极大程度上影响了溶解氧在这些海区的分布。需要指出的是,虽然在海洋内部各模式模拟的溶解氧浓度偏差较大,但是多模式平均结果却能表现出与观测较好的一致性。     

Study of Influence of Regional Geodynamic Background on Strata Behaviors in China's Tongxin Mine

Strata behaviors are mainly affected by regional geodynamic background. The influence of rock mass stress and energy distribution on strata behaviors in the Tongxin mine is studied in terms of regional tectonic movement, seismic activity and tectonic stress field. The results show that the extrusion lifting movement of Kouquan fault adjacent to the Tongxin mine results in the stress concentration in the rock of the Carboniferous coal bed and accumulation of a large amount of elastic energy and forms structural background of Tongxin mine. Due to various seismic activities in the mine area, the strain energy is known to reach much higher levels, up to 0.5×10⁸ J^1/2. Since the stratigraphic structure is sensitive to the mining operation, the strain energy could cause strong strata behaviors. A special geological structure model of the Tongxin mine is established based on the geodynamic division method. The distribution of regional structure stress field is determined by the rock mass stress analysis system. Based on this model, Tongxin mine is divided into five areas with high stress, eight areas with low stress and eight areas with gradient stress. The strong strata behaviors mostly occur in high stress areas. These results could provide guidance to predict the strength of regional or mine pressure and control strata behavior in different areas.     

空化水射流技术在海洋污损生物清除领域的应用研究

文章从海洋污损生物的危害分析入手,首先概述海洋污损生物的清除方法,并结合空化水射流技术的原理与优势开展实例应用研究,指出空化射流清洗技术是一种切实可行的新型清洗技术,可以在不破坏设施表面完整防腐层的基础上,高效、安全地清洗水下设施表面附着的海洋生物污垢层;最后对空化水射流技术进行展望,指出其关键技术在于空化射流喷嘴的设计和ROV自动控制系统的研制。     

An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.     

中国省际人口迁移的多边效应机制分析

区际人口迁移不仅与迁出地和目的地的要素特征以及距离有关,而且还受到周边迁移流的影响.基于网络自相关理论,利用"六普"省际人口迁移数据和相关统计资料,在重力模型的基础上考虑迁移流之间可能存在的几种空间依赖形式,构建中国省际迁移流的空间OD模型,初步揭示区域经济社会等因素及其空间溢出效应对省际人口迁移的影响,并就区域要素变化对整个省际人口迁移系统产生的"连锁反应"进行了模拟.结果表明:① 中国省际迁移流之间存在显著的网络自相关效应.目的地和迁出地的自相关效应皆为正,导致迁入和迁出流的空间效仿行为;迁出地和目的地周边则出现负的自相关效应,导致迁移流的空间竞争行为;② 区域经济社会等因素通过网络空间关系对周边地区产生的多边溢出效应导致迁移流在空间上集聚.其中,距离衰减效应位居各要素之首,其溢出效应进一步加剧距离的摩擦作用;对目的地而言,区域工资水平和迁移存量超过GDP的影响并产生正的溢出效应,促进周边地区吸引更多的外来人口;对迁出地而言,人口规模和迁移存量产生正的溢出效应,推动周边地区人口外迁;③ 区域要素变化潜在地对整个省际人口迁移系统产生一系列"连锁反应",震荡中心及其周边区域的迁移流波动较大.江苏省GDP增长5%的模拟结果表明,江苏迁往全国其他省份的人口数量都有不同程度地减少,而其他省份入迁人口均有所增加.相对而言,江苏周边省份的迁入或迁出流受到的波动较大,偏远省份波及较小,这是传统的重力模型所无法解释的.     

新疆东准乌须克劳格岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素特征及其地质意义

新疆东准噶尔琼河坝地区近年来找矿获得重大突破,发现了一系列重要的矿产,这些矿产基本上围绕该地区出露面积最大的乌须克劳格岩体分布。该岩体组成比较复杂,主要岩性为二长花岗岩和花岗闪长岩。采用LA-ICP-MS技术测得花岗闪长岩和二长花岗岩锆石~(206)Pb/~(238)U年龄分别为428.9±1.9Ma和427.2±1.7Ma,被解释为岩石的结晶年龄。2类岩石都属于过铝质-钙碱性系列花岗岩,具有较高的铝、钙含量,K_2O/Na_2O值普遍偏低,介于0.15~0.40之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显;在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集,具有高Ba、Sr含量和高(La/Yb)_N、Sr/Y值,显示出高Ba-Sr花岗岩的特征;同时岩体具有高正ε_(Hf)(t)值和年轻的模式年龄。这些地球化学和同位素特征表明,晚志留世乌须克劳格岩体是大陆边缘弧环境下大洋板片熔融的产物。     

专题地质填图及有关问题讨论

面积性地质调查及填图是今后地质调查的主要工作,如何做好这个工作,并实现地质调查和科研一体化,特别是在已有填图基础上,如何部署和开展新的填图工作,是一个亟待回答的新问题。专题地质填图是针对存在的重要地质或资源、环境问题,或是针对特定目标地质体等,以解决特定问题或满足社会特定需求为主要目的、填图与研究融为一体的地质填图,填图的范围和比例尺依据解决问题和目标地质体而定。专题地质填图是以问题和需求为驱动,是对已有的综合地质填图的补充和提高,是高效实现地调科研一体化的一种方式。论述了专题填图的内涵、必要性,以及开展专题填图的方式和方法。     

Characteristics of deuterium excess parameters for geothermal water in Beijing

This study investigates the characteristics of geothermal water in 10 geothermal fields in Beijing. The relationships between the deuterium excess parameter (d) and temperature, depth, age of geothermal groundwater, groundwater flow field, and Eh were investigated using geothermal groundwater samples. Results showed that (1) the average d value of geothermal water is 5.4, whereas that of the groundwater in normal temperature is 6.04. The differences are induced by the oxygen isotope exchange during the water–rock interaction, which may be more easily completed in geothermal water than in cold groundwater. (2) The d value increases remarkably with the age of the geothermal groundwater. The d value increases from 11.2 to 14.6 when the age of the geothermal water is 12,760 ± 130 a and 38,960 ± 630 a, respectively. Moreover, the isotope heat exchange for composition of the hydrogen and oxygen isotopes in the geothermal groundwater proceeds sufficiently with time. (3) The d value decreases from 5.72 to 3.03 when the depth increases from 125.13 to 3221 m. Generally, in the same area, the d value decreases with depth because the temperature is increasing. (4) The d value of the groundwater gradually reduces from the northern recharge area to the southern discharge area. The average d value is 7.31 in the northern recharge area and 5.68 in the middle Beijing Depression, whereas the d value in the southern area of Fengheying is ?9.20. The larger difference in d values between the recharge and discharge areas is due to the slower velocity of underwater flow, which induces longer time for oxygen exchange. (5) The relationship between the d and Eh is complex. When Eh is <200 mV, the d value of the geothermal water decreases with the decrease in Eh. When Eh is higher than 200 mV, the d value increases slightly with the decrease in Eh. The study of the characteristics of deuterium excess parameters for geothermal water could provide a scientific isotopic evidence for assessment and exploitation measures in geothermal groundwater systems.     

Numerical Analysis of Gravity Coring Using Coupled Eulerian-Lagrangian Method and a New Corer

The shortcomings of gravity corers in sampling marine sediments have been observed extensively in various field tests. In order to optimize the coring, this article provides an alternative numerical way to model the gravity coring and analyze the sampling effect. Based on this analysis, a new hydraulic hammer corer is devised. A coupled Eulerian-Lagrangian method with capability of simulating the problem involving extreme deformation, penetration is used to simulate the coring process. The results show that the hydrostatic pressure and deviator stress increase and reach their peak when the pile tip is slightly above or at the level of the observation point and then drop rapidly when the pile tip slides below the observation point. In addition, the stress path indicates that the soil element sustains plastic compression before yielding and then expands until recovering to the original state. The obvious “under-sampling” phenomenon is also well-captured by the finite element model.