Mineral matter and trace elements in coals of the Gunnedah Basin, New South Wales, Australia

The concentrations of major and trace inorganic elements in a succession of Permian coals from the Gunnedah Basin, New South Wales, have been determined by X-ray fluorescence techniques applied to both whole-coal and high-temperature ash samples. The results have been evaluated in the light of quantitative data on the minerals in the same coals, determined from X-ray diffraction study of whole-coal samples using a Rietveld-based interpretation program ( ™), to determine relationships of the trace elements in the coals to the mineral species present. Comparison of the chemical composition of the coal ash interpreted from the quantitative mineralogical study to the actual ash composition determined by XRF analysis shows a high degree of consistency, confirming the validity of the XRD interpretations for the Gunnedah Basin materials. Quartz, illite and other minerals of detrital origin dominate the coals in the upper part of the sequence, whereas authigenic kaolinite is abundant in coals from the lower part of the Permian succession. These minerals are all reduced in abundance, however, and pyrite is a dominant constituent, in coals formed under marine influence at several stratigraphic levels. Calcite and dolomite occur as cleat and fracture infillings, mostly in seams near the top and bottom of the sequence. The potassium-bearing minerals in the detrital fraction are associated with significant concentrations of rubidium, and the authigenic kaolinite with relatively high proportions of titanium. Zirconium is also abundant, with associated P and Hf, in the Gunnedah Basin coal seams. Relationships exhibited by Ti, Zr, Nd and Y are consistent with derivation of the original sediment admixed with the seams from an acid volcanic source. Pyrite in the coals is associated with high concentrations of arsenic and minor proportions of thallium; no other element commonly associated with sulphides in coals, however, appears to occur in significant proportions with the pyrite in the sample suite. Small concentrations of Cl present in the coal are inversely related to the pyrite content, and appear to represent ion-exchange components associated with the organic matter. Strontium and barium are strongly associated with the cleat-filling carbonate minerals. Ge and Ga appear to be related to each other and to the coal's organic matter. Cr and V are also related to each other, as are Ce, La, Nd and Pr, but none of these show any relationship to the organic matter or a particular mineral component.     

Abundance, variability, and potential grazing impact of planktonic ciliates in the open subaratic Pacific Ocean

The abundance and variability of planktonic ciliates in the open subarctic Pacific were determined during four month-long cruises in 1987 and 1988. The ciliate community, numerically dominated by relatively small aloricate choreotrichs, was comparable in abundance to communities in a range of oceanic and neritic environments, including waters with much higher average chlorophyll concentrations. Integrated (0–80m) ciliate biomass was typically 100–200mgC m⁻², although 3- to 4-fold higher levels were observed on two occasions in spring. Ciliate community biomass, in general, was dominated by large (>20μm width) individuals, although in August 1988 the biomass of smaller cells was as great or greater. The estimated grazing impact of the ciliate community averaged 20% of the primary production. On one instance in May 1988, however, a large biomass of ciliates led to an estimated grazing impact equivalent to 55% of phytoplankton production. While ciliates may be major phytoplankton grazers during sporadic ciliate “blooms”, dino- and other heterotrophic flagellates, which make up the bulk of microheterotroph biomass, must normally be of equal or greater importance as herbivores in this ocean region.     

Methanol masers at 107.0 and 156.6 GHz

From a search of more than 80 southern class II methanol maser sites, we report measurements of 22 masers at 107.0 GHz and four at 156.6 GHz, mostly new discoveries. Class II sites, recognized by their strong emission at the 6.6-GHz methanol transition, are indirect indicators of new-born massive stars, and several hundred have been documented; only a handful of these had previously been found to exhibit maser emission at the 107.0- or 156.6-GHz transition. The present survey increases the number of known 107.0-GHz masers to 25, providing a sufficiently large sample to assess their general properties. For the stronger ones, our position measurements confirm that, to an accuracy of 5 arcsec, they coincide with the dominant maser emission at 6.6 GHz. Intensity variations exceeding 50 per cent have occurred in some 107.0-GHz maser features that we observed in both 1996 October and 1998 June.
We find that masers are rare at the 156.6-GHz transition. Two new detections increase the total now known to four. Each 156.6-GHz maser is substantially weaker than its corresponding 107.0-GHz maser. Despite the scarcity of masers, our 156.6-GHz spectra at most observed sites show emission, but apparently of a quasi-thermal variety; it is usually accompanied by somewhat weaker thermal emission at 107.0 GHz, and the intensity ratio of the transitions allows us to begin exploration of the physical characteristics of the small molecular clouds (diameter less than 60 mpc) at these sites. The thermal emission thus provides estimates of the environmental conditions that are needed to support strong masing from spots that are apparently embedded within these clouds.     

Common bivalve larvae from New Zealand: Mytilacea

The late stage larvae of five common mytilid bivalves (Mollusca: Pelecypoda: Mytilacea) are described and provisionally identified as Mytilus edulis aoteanus, Modiolus areolatus, Perna canaliculus, Xenostrobus pulex, and Modiolarca impacta. All are readily distinguishable on the basis of larval shell features, including hinge structure. However, one common species, Aulacomya maoriana, was not discerned, and thus the identifications must remain tentative.

The larvae were recovered from plankton samples from Bay of Islands (35° 15’ S, 174° 10’ E), Wellington Harbour (41° 16’ S, 174° 51’ E), and Raumati Beach (40° 56’ S, 174° 58’ E), New Zealand, during 1970–72. Their seasonal occurrences in the plankton are described and related to the condition index of the adults as far as possible.     

Use of Kendall's coefficient of concordance to assess agreement among observers of very high resolution imagery

Ground-based vegetation monitoring methods are expensive, time-consuming and limited in sample size. Aerial imagery is appealing to managers because of the reduced time and expense and the increase in sample size. One challenge of aerial imagery is detecting differences among observers of the same imagery. Six observers analysed a set of 1-mm ground sample distance aerial imagery for graminoid species composition and important ground-cover characteristics. Kendall's coefficient of concordance (W) was used to measure agreement among observers. The group of six observers was concordant when assessed as a group. When each of the observers was assessed independently against the other five, lack of agreement was found for those graminoid species that were difficult to identify in the aerial images.     

Measurement of vertical noise directionality with a mixed-polarity vertical array

A novel array was designed and tested in the eastern Pacific Ocean for the measurement of the vertical directionality of ambient noise. The results of the test, conducted in 1983, illustrate the existence of a 5-dB "noise notch" for arrival angles associated only with submerged acoustic sources. A measurement system based on improvements to the design and processing is described.     

Orbital parameters, masses and distance to β Centauri determined with the Sydney University Stellar Interferometer and high-resolution spectroscopy

The bright southern binary star β Centauri (HR 5267) has been observed with the Sydney University Stellar Interferometer (SUSI) and spectroscopically with the European Southern Observatory Coude Auxiliary Telescope and Swiss Euler telescope at La Silla. The interferometric observations have confirmed the binary nature of the primary component and have enabled the determination of the orbital parameters of the system. At the observing wavelength of 442 nm the two components of the primary system have a magnitude difference of  0.15 ± 0.02  . The combination of interferometric and spectroscopic data gives the following results: orbital period  357.00 ± 0.07 d  , semimajor axis  25.30 ± 0.19 mas  , inclination  674 ± 03  , eccentricity  0.821 ± 0.003  , distance  102.3 ± 1.7 pc  , primary and secondary masses   M ₁= M ₂= 9.1 ± 0.3 M_⊙  and absolute visual magnitudes of the primary and secondary   M _{1 V} =−3.85 ± 0.05  and   M _{2 V} =−3.70 ± 0.05  , respectively. The high degree of accuracy of the results offers a fruitful starting point for future asteroseismic modelling of the pulsating binary components.     

The importance of population,climate change and CO2 plant physiological forcing in determining future global water stress

Future levels of water stress depend on changes in several key factors including population, climate-change driven water availability, and a carbon dioxide physiological-forcing effect on evaporation and run-off. In this study we use an ensemble of the HadCM3 climate model forced with a range of future emissions scenarios combined with a simple water scarcity index to assess the contribution of each of these factors to the projected population living in water stress over the 21st century.Population change only scenarios increase the number of people living in water stress such that at peak global population 65% of people experience some level of water stress. Globally, the climate model ensemble projects an increase in water availability which partially offsets some of the impacts of population growth. The result is 1 billion fewer people living in water stress by the 2080s under the high end emissions scenarios than if population increased in the absence of climate change.This study highlights the important role plant-physiological forcing has on future water resources. The effect of rising CO₂ is to increase available water and to reduce the number of people living in high water stress by around 200 million compared to climate only projections. This effect is of a similar order of magnitude to climate change.     

Imaging glacial sediment inclusions in 3‐D using ground‐penetrating radar at Kongsvegen,Svalbard

The quiescent‐phase surge‐type glacier, Kongsvegen, flows confluent with the continuously fast‐flowing Kronebreen in northwestern Spitsbergen. The lower regions of Kongsvegen overlie glaciomarine sediments, which have been incorporated into the ice during multiple surge events. The resulting englacial structures are exposed at the surface and on a cliff section. These structures have variously been interpreted as thrusts, formed by compression, or sediment‐filled crevasses, formed by extension. We collected a grid of closely spaced ground‐penetrating radar profiles in the area adjacent to the cliff section. Several structures were imaged in 3‐D, including a strong subhorizontal basal reflector, which was underlain by a second, weaker subhorizontal reflector. The basal reflector was occasionally reverse faulted, suggesting compression. Clear englacial features extended upwards from it, dipping up‐glacier at angles of <40° and steepening towards the glacier surface; they had complex geometries that changed rapidly cross‐glacier. The structures were orientated at ～30° to ice flow, suggesting modification by lateral compression from Kronebreen. Some of these englacial structures clearly crossed the basal reflector. We conclude that the englacial features imaged are not likely to be derived from crevasse filling and were probably formed by thrusting. The results contribute to our understanding of surge initiation and termination processes, and interpretation of features in the palaeorecord. Copyright © 2009 John Wiley & Sons, Ltd.