Natural Cycles and Transfer of Mercury Through Pacific Coastal Marsh Vegetation Dominated by Spartina foliosa and Salicornia virginica

The potential for marsh plants to be vectors in the transport of mercury species was studied in the natural, mature, tidal China Camp salt marsh on San Pablo Bay. The fluxes of organic matter, mercury (THg), and monomethylmercury (MeHg) were studied in natural stands of Spartina foliosa and Salicornia virginica. Seasonal fluxes from the sediment into aboveground biomass of live plants and subsequent transfer into the dead plant community by mortality were measured. Loss of THg and MeHg from the dead plant community through fragmentation, leaching, and excretion were calculated and were similar to net uptake. Seasonal data were added up to calculate annual mass balances. In S. foliosa, annual net production was 1,757 g DW m^?2, and the annual net uptakes in the aboveground biomass were 305 μg THg m^?2 and 5.720 μg MeHg m^?2. In S. virginica, annual net production was 2,117 g DW m^?2, and the annual net uptakes in aboveground biomass were 99.120 μg THg m^?2 and 1.990 μg MeHg m^?2. Of both plant species studied, S. foliosa had a slightly lower production rate but greater mercury species uptake and loss rates than S. virginica, and, consequently, it is to be expected that S. foliosa matter may affect the local and possibly the regional food web relatively more than S. virginica. However, the actual effects of the input of mercury-species-containing plant-derived particulate matter into the food webs would depend on trophic level, food preference, seasonal cycle of the consumer, total sediment surface area vegetated, location of the vegetation in the marsh landscape, and estuary bay landscape. Since the levels of mercury species in dead plant material greatly exceed those in live plant material (on a dry weight basis), detritivores would ingest greater mercury species concentrations than herbivores, and consumers of S. foliosa would ingest more than consumers of S. virginica. The greatest THg and MeHg losses of both plant species due to mortality and to fragmentation–leaching–excretion occurred in late spring and early autumn, which corresponds to peak MeHg levels observed in sediments of coastal systems of previous studies, suggesting enhanced THg–MeHg export from the marsh to the nearshore sediment.     

A sample of mJy radio sources at 1.4 GHz in the Lynx and Hercules fields – I. Radio imaging, multicolour photometry and spectroscopy

With the goal of identifying high-redshift radio galaxies with Fanaroff–Riley class I (FR I) classification, here are presented high-resolution, wide-field radio observations, near-infrared and optical imaging and multi-object spectroscopy of two fields of the Leiden–Berkeley Deep Survey. These fields, Hercules.1 and Lynx.2, contain a complete sample of 81 radio sources with   S _1.4 GHz > 0.5 mJy  within 0.6 deg². This sample will form the basis for a study of the population and cosmic evolution of high-redshift, low-power, FR I radio sources which will be presented in Paper II. Currently, the host galaxy identification fraction is 86 per cent with 11 sources remaining unidentified at a level of   r '≥ 25.2 mag  (Hercules; four sources) or   r '≥ 24.4 mag  (Lynx; seven sources) or   K ≳ 20 mag  . Spectroscopic redshifts have been determined for 49 per cent of the sample and photometric redshift estimates are presented for the remainder of the sample.     

The monitoring of opportunistic macroalgal blooms for the water framework directive

Among the various quality elements which the Water Framework Directive requires should be monitored are macroalgae. One aspect of these is the presence, in transitional waters particularly, of large blooms of opportunistic macroalgae, such as Ulva and Enteromorpha. Within the United Kingdom (UK) and Republic of Ireland (RoI) there are currently no set ecological quality objectives or standards for macroalgae. Nor are there standard methods for monitoring macroalgal blooms, although various combinations of aerial photography, remote sensing and measurements on the ground are used. This paper attempts to set a logical framework for the prioritisation of sites for monitoring, the development of a tiered monitoring procedure and the derivation of thresholds for classification. Draft threshold limits for percentage cover and biomass of macroalgae have been derived from the literature. The importance of secondary effects and physico-chemical parameters is discussed.     

Connections between whistlers and pulsation activity

Simultaneous whistler records of one station and geomagnetic pulsation (Pc3) records at three stations were compared. In a previous study correlation was found between occurrence and L value of propagation/excitation for the two phenomena. The recently investigated simultaneous records have shown that the correlation is better on longer time scales (days) than on shorter ones (minutes), but the L values of the propagation of whistlers/excitation of pulsations are correlated, i.e. if whistlers propagate in higher latitude ducts, pulsations have periods longer than in the case when whistlers propagate in lower latitude ducts.     

The nature and origin of pigments in black opal from Lightning Ridge,New South Wales,Australia

Abstract

Black opal (opal-AG) owes its dark coloration to a fine-grained pigment commonly inferred to be mainly carbon, yet chemical compositions for black opals suggest there may be additional components. Here we search for such components in pigment concentrates prepared by dissolving black opal nodules (nobbies) from Lightning Ridge (NSW) in hydrofluoric acid, using electron microscopy (scanning electron microscopy, transmission electron microscopy), X-ray diffraction and laser-ablation ICP-MS. The results demonstrate the presence of sulfides—predominantly pyrite and chalcopyrite, with minor galena and Ti-oxide phases, as additional components of the pigment. ATR-FTIR analysis indicates the presence of C=O and C–H groups, consistent with an organic origin. Transmission electron microscopy images of pigment show variously deformed, originally spherical ～100?nm particles rich in sulfide and carbon, which are interpreted as thin coatings of pigment on now dissolved opaline silica spheres. Laser-ablation ICP-MS analysis identifies remnant silica in pigment concentrates, which may be interpreted as opaline silica surviving HF treatment protected as inclusions in sulfides. When examined within the context of petrographic observations from more than 1000 opal nodules (nobbies) at Lightning Ridge, these new results suggest that pigment carbon and sulfides in the nodules formed microbially under initially anoxic groundwater conditions, within pre-existing cavities concurrently being filled with silica sol ultimately derived from chemical weathering of feldspar-rich volcaniclastic sediment. Intensely black pigment layers observed at the floor of many nodules indicate settling of dark, high-density (sulfide–Ti-oxide-rich) pigment within cavities, with the implication that sulfate-reducing bacterial (SRB) activity commences early during the silica sol-gel ripening process. Microbial activity may persist until after the cavity has completely filled with the silica sol, as illustrated by abundant black opals with uniformly distributed pigment. Pigment formed at this stage may no longer be able to settle out within the ripening and increasingly viscous silica gel, thus forming pigmentation throughout the opal cavity. The existence of ‘amber’, pigment-poor opal with intensely black basal pigment layers is interpreted as signalling a lack of sulfate to sustain further SRB activity, or a change to more oxidising conditions, possibly related to interaction with surface waters within a downward-penetrating weathering front. A change in redox conditions would shut off activity of SRB and thus sulfide pigment production and allow development of aerobic microbial activity as described by others.     

CENSORS: A Combined EIS–NVSS Survey Of Radio Sources – I. Sample definition, radio data and optical identifications

A new sample of radio sources, with the designated name CENSORS (A Combined EIS–NVSS Survey Of Radio Sources), has been defined by combining the National Radio Astronomy Observatory Very Large Array Sky Survey (NVSS) at 1.4 GHz with the ESO Imaging Survey (EIS) Patch D, a 3° by 2° region of sky centred at RA     , Dec. −21°00'00' (J2000). New radio observations of 199 NVSS radio sources with NVSS flux densities   S _{1.4 GHz} > 7.8 mJy  are presented, and are compared with the EIS I -band imaging observations which reach a depth of   I ∼ 23  ; optical identifications are obtained for over two-thirds of the ∼150 confirmed radio sources within the EIS field. The radio sources have a median linear size of 6 arcsec, consistent with the trend for lower flux density radio sources to be less extended. Other radio source properties, such as the lobe flux density ratios, are consistent with those of brighter radio source samples. From the optical information, 30–40 per cent of the sources are expected to lie at redshifts   z ≳ 1.5  .
One of the key goals of this survey is to accurately determine the high-redshift evolution of the radio luminosity function. These radio sources are at the ideal flux density level to achieve this goal; at redshifts   z ∼ 2  they have luminosities which are around the break of the luminosity function and so provide a much more accurate census of the radio source population at those redshifts than the existing studies of extreme, high radio power sources. Other survey goals include investigating the dual-population unification schemes for radio sources, studying the radio luminosity dependence of the evolution of radio source environments, and understanding the radio power dependence of the K – z relation for radio galaxies.     

HST and UKIRT imaging observations of z∼ 1 6C radio galaxies – II. Galaxy morphologies and the alignment effect

Powerful radio galaxies often display enhanced optical/ultraviolet emission regions, elongated and aligned with the radio jet axis. The aim of this series of papers is to investigate separately the effects of radio power and redshift on the alignment effect, together with other radio galaxy properties. In this second paper, we present a deeper analysis of the morphological properties of these systems, including both the host galaxies and their surrounding aligned emission.
The host galaxies of our 6C subsample are well described as de Vaucouleurs ellipticals, with typical scale sizes of  ∼10 kpc  . This is comparable to the host galaxies of low- z radio sources of similar powers, and also the more powerful 3CR sources at the same redshift. The contribution of nuclear point source emission is also comparable, regardless of radio power.
The 6C alignment effect is remarkably similar to that seen around more powerful 3CR sources at the same redshift in terms of extent and degree of alignment with the radio source axis, although it is generally less luminous. The bright, knotty features observed in the case of the z ∼ 1 3CR sources are far less frequent in our 6C subsample; neither do we observe such strong evidence for evolution in the strength of the alignment effect with radio source size/age. However, we do find a very strong link between the most extreme alignment effects and emission-line region properties indicative of shocks, regardless of source size/age or power. In general, the 6C alignment effect is still considerably stronger than that seen around lower redshift galaxies of similar radio powers. Cosmic epoch is clearly just as important a factor as radio power: although aligned emission is observed on smaller scales at lower redshifts, the processes which produce the most extreme features simply no longer occur, suggesting considerable evolution in the properties of the extended haloes surrounding the radio source.     

The evolution of active galaxies in clusters

The results of deep radio, sub-mm and X-ray observations of samples of high redshift (z∼1) clusters are presented. These reveal significant excesses of active galaxies associated with the clusters at all three wavelengths. The cluster radio source population shows evolution consistent with the (1+z)³ evolution typical of many AGN classes. A large fraction of the AGN are hosted by apparently passive early-type galaxies, often with a close companion. These results essentially constitute the detection of a counterpart of the Butcher-Oemler effect for both strongly star bursting galaxies and AGN. This revised version was published online in July 2006 with corrections to the Cover Date.     

The distribution of active galactic nuclei in a large sample of galaxy clusters

We present an analysis of the X-ray point source populations in 182 Chandra images of galaxy clusters at   z > 0.1  with exposure time >10 ks, as well as 44 non-cluster fields. The analysis of the number and flux of these sources, using a detailed pipeline to predict the distribution of non-cluster sources in each field, reveals an excess of X-ray point sources associated with the galaxy clusters. A sample of 148 galaxy clusters at  0.1 < z < 0.9  , with no other nearby clusters, shows an excess of 230 cluster sources in total, an average of ∼1.5 sources per cluster. The lack of optical data for these clusters limits the physical interpretation of this result, as we cannot calculate the fraction of cluster galaxies hosting X-ray sources. However, the fluxes of the excess sources indicate that over half of them are very likely to be active galactic nuclei (AGN), and the radial distribution shows that they are quite evenly distributed over the central 1 Mpc of the cluster, with almost no sources found beyond this radius. We also use this pipeline to successfully reproduce the results of previous studies, particularly the higher density of sources in the central 0.5 Mpc of a few cluster fields, but show that these conclusions are not generally valid for this larger sample of clusters. We conclude that some of these differences may be due to the sample properties, such as the size and redshift of the clusters studied, or a lack of publications for cluster fields with no excess sources. This paper also presents the basic X-ray properties of the galaxy clusters, and in subsequent papers in this series the dependence of the AGN population on these cluster properties will be evaluated.
In addition the properties of over 9500 X-ray point sources in the fields of galaxy clusters are tabulated in a separate catalogue available online or at http://www.sc.eso.org~rgilmour .