Optimisation of a catalytic procedure for the determination of total iodine in seawater

A precise method for the determination of total iodine in seawater, which uses a Technicon Auto-Analyser II system and is based on Truesdale and Spencer's (1974) and Truesdale and Smith's (1975) earlier works with a catalytic procedure, is described. The procedure operates over a range of 30–80 μg1^?1 of iodine. As requested by Mark (1973), the way in which the procedure can be varied to suit other applications, and therefore ranges, is explained in detail. The standard deviation at the 50 μg1^?1 level was found to be 0.12 μ1^?1 showing that the method's precision exceeds most, if not all, previously published procedures for this variable. This high degree of resolution makes the procedure suitable for oceanic investigations. The effects of varying the reaction time, the temperature at which the reaction proceeds and the salinity of samples and standards are described. The advantages of using a Technicon Auto-Analyser II system rather than an Auto-Analyser I system are discussed. With slight modification the procedure can also be used in the measurement of river flow where sodium iodide is used as tracer in the dilution method.     

Iceland and mid-oceanic ridges

Magnetic anomalies over Iceland, measured by Serson et al. (1968), are similar in shape and amplitude to those found over mid-oceanic ridges in general and over Reykjanes Ridge in particular. However, the geology of Iceland does not favour the simple model of sea floor spreading as formulated by Vine and Matthews. The Brunhes period volcanism can neither in place nor in time be related to an opening process of the Central Graben, which actually is a downthrown block and not an opening rift. Furthermore, the structure of Iceland is not symmetric with respect to the Central Graben. The geology of the Central Graben of Iceland does support a model proposed by Thorleifur Einarsson in 1967. In this model elongate ridges of pillow lavas are thought to have piled up on top of parallel volcanic fissures. The actual spreading is negligible. The fissures have been opening at random over a width of about 120 km, and no definite time scale can be set up for the associated magnetic anomalies. This conflict between Icelandic geology and the current views on sea floor spreading, can be evaded by supposing that the mere circumstance that Iceland is an island obscures a spreading process underneath. One might also postulate that Iceland nevertheless should stand as an example of a mid-oceanic ridge which implies that our ideas on sea floor spreading should be thoroughly revised.     

Long-term recovery of a Louisiana brackish marsh plant community from oil-spill impact: vegetation response and mitigating effects of marsh surface elevation

Oil spills can have significant, short-term, negative impacts on coastal marshes, but the long-term effects and eventual recovery are not well documented, particularly in brackish marshes. The goals of this investigation were to: (1) document the long-term recovery of a Louisiana brackish marsh plant community impacted by a 1985 oil spill; (2) separate the effect of the oil spill on marsh deterioration from ambient rates of marsh deterioration; and (3) assess the relative importance of residual oil in the sediment and decreased marsh surface elevation in the failure of certain areas to recover. A total of 68 permanent plots previously established in 1985 were re-surveyed for plant and soil recovery in the fall of 1989. Although substantial (and near total) vegetative recovery was evident by significant increases in live and total vegetative cover, many of the plots that were initially heavily impacted by oil still displayed elevated levels of total saturated hydrocarbons in the soil. August 1990 measurements of plant photosynthetic response and edaphic variables revealed no significant differences between control plots and plots heavily impacted by oil that displayed vegetative regrowth. Rates of wetland land loss in the oiled marsh during an 8-year period that bracketed the time of the spill were within the historical range measured for this site and similar to the land loss rates of adjacent reference marshes. Results from a manipulative field transplant experiment indicated that the long-term failure of certain small areas to revegetate was primarily due to a decrease of marsh surface elevation (increased flooding stress), not a residual oil effect.     

Tropospheric lapse rate and its relation to surface temperature from reanalysis data

Estimates of the tropospheric lapse rate γ and analysis of its relation to the surface temperature T _s in the annual cycle and interannual variability have been made using the global monthly mean data of the NCEP/NCAR reanalysis (1948–2001). The tropospheric lapse rate γ is about 6.1 K/km in the Northern Hemisphere (NH) as a whole and over the ocean and about 6.2 K/km over the continents. The value of γ decreases from 6.5 K/km at low latitudes to 4.5 K/km at polar latitudes. The values of dγ/dT _s, the parameter of sensitivity of γ to the variation of T _s for the NH in the interannual variability, are found to be about 0.04 km^?1 (0.041 km^?1 for the NH as a whole, 0.042 km^?1 over the ocean, and 0.038 km^?1 over the continents). This corresponds to an increase in γ of approximately 0.7% when the surface temperature of the NH is increased by 1 K. Estimates of dγ/dT _s vary from about 0.05 km^?1 in the subtropics to 0.10 km^?1 at polar latitudes. When dγ/dT _s is positive, the surface and tropospheric warming means a temperature decrease above a certain critical level H _cr. The height of the level H _cr with constant temperature, which is defined by the inverse value (dγ/dT _s)^?1, is about 25 km for the NH as a whole, i.e., above the tropopause. In the subtropics, H _cr is about 20 km. At polar latitudes, H _cr decreases to about 10 km. Positive values of dγ/dT _s characterize a positive climatic feedback through the lapse rate and indicate a general decrease in the static stability of the troposphere during global warming. Along with a general tendency of γ to increase with rising T _s, there are regional regimes with the opposite tendency, mainly over the ocean. The negative correlation of γ with T _s is found over the oceanic tropics and midlatitudes, in particular, over the oceanic belt around Antarctica.     

A finite element model of interaction between viscous free surface waves and submerged cylinders

This paper describes the simulation of the flow of a viscous incompressible Newtonian liquid with a free surface. The Navier–Stokes equations are formulated using a streamline upwind Petrov–Galerkin scheme, and solved on a Q-tree-based finite element mesh that adapts to the moving free surface of the liquid. Special attention is given to fitting the mesh correctly to the free surface and solid wall boundaries. Fully non-linear free surface boundary conditions are implemented. Test cases include sloshing free surface motions in a rectangular tank and progressive waves over submerged cylinders.     

Thermodynamic characterization of the partitioning of iron between soluble and colloidal species in the Atlantic Ocean

Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 10¹³ relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange.     

A B-spline based higher order panel method for analysis of steady flow around marine propellers

A higher order panel method based on B-spline representation for both the geometry and the solution is developed for the analysis of steady flow around marine propellers. The self-influence functions due to the normal dipole and the source are desingularized through the quadratic transformation, and then shown to be evaluated using conventional numerical quadrature. By selecting a proper order for numerical quadrature, the accuracy of the present method can be increased to the machine limit. The far- and near-field influences are shown to be evaluated based on the same far-field approximation, but the near-field solution requires subdividing the panels into smaller subpanels continuously, which can be effectively implemented due to the B-spline representation of the geometry. A null pressure jump Kutta condition at the trailing edge is found to be effective in stabilizing the solution process and in predicting the correct solution. Numerical experiments indicate that the present method is robust and predicts the pressure distribution on the blade surface, including very close to the tip and trailing edge regions, with far fewer panels than existing low-order panel methods.