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751.
The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol−1 was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (Kptrue) and colloidal particles (Kctrue) have been calculated, and a Kptrue value of 141 and 102 ml g−1 was obtained for oestrone and 17β-oestradiol, respectively. In addition, Kctrue values for oestrone (222×102 ml g−1) and 17β-oestradiol (135×102 ml g−1) were two orders of magnitude higher than their respective Kptrue values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment. 相似文献
752.
Abstract. The utilization of the spatial resources of refuge type, size and depth placement is investigated in the three sympatric species of Acanthemblemaria at the cape region of Baja California, Mexico. A. balanorum occupies barnacle testes (Balanus tintinnabulum), A. macrospilus occupies barnacles and mollusk tubes (vermetid gastropods and pholadids), and A. crockeri occupies only mollusk tubes (pholadids). Refuge diameter overlap is higher than overlap in depth. A. crockeri consistently occupies depths below 5m. Competition experiments for barnacle refuges among the three species indicate that A. balanorum is a superior competitor for such refuges. Prior residency of a less superior species changes the outcome of refuge competition in its favor. The morphological specialization of A. balanorum and A. macrospilus is evident in a high correlation between head size and standard length. A. balanorum selects refuges with entrance diameters highly correlated to standard length. 相似文献
753.
The growth rate and potential production of bacterioplankton in cold hydrocarbon seeps located along the Louisiana coast were determined using a pulse-labeling technique. Surprisingly, community doubling times are on the order of 1.1 h, which compares to laboratory-grown cultures. We also found that there are differences in growth rates on relatively small geographic scales, suggesting the influence of site-specific geological features (e.g., gas hydrate mounds). Proceeding downslope to deeper waters, methane-oxidizing bacteria appeared to play a more significant role in community productivity. These preliminary experiments indicated, quite unexpectedly, that water column microbes are growing at a more rapid rate than in any other marine system so far studied and that methane may serve as a primary nutrient (carbon) source in these seep-associated microbial assemblages. 相似文献
754.
An extrapolated version of a time-dependent nonreflecting boundary condition is developed for use at artificial boundaries to truncate infinite/semi-infinite domains for transient water wave problems. Test examples include single- and multiple-frequency flap wavemaker problems and free vibrations of a floating circular cylinder. The finite element results compare favorably to analytical solutions. It is shown that with the proposed boundary condition the numerical simulations have little reflections from the artificial boundaries. 相似文献
755.
Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO2, SO4, TH2S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO2/ΔSO4 was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides. 相似文献
756.
Community-based coastal resource management projects facilitated by non-governmental organizations (NGOs) in the Philippines have explored approaches to decrease poverty-driven over-exploitation of coastal resources. There has been little reporting and analysis of such activities until recently. Nine case studies have recently been published and this paper presents a brief summary of these, along with an analysis of the trends and themes identified. Though diverse and covering the Philippines from Mindanao to Luzon, the case studies highlight the value of community commitment and participation in decisions regarding, and in the implementation of, resource management in ways that consider not only the bio-physical aspects of resource management but the social, economic and legal implications. Experience in working with local government has been both successful and limited. Successful projects raise hopes for further progress through education and organization of communities to improve livelihoods and protect coastal resources. 相似文献
757.
Quality control in mud coring 总被引:1,自引:0,他引:1
W. R. Parker 《Geo-Marine Letters》1991,11(3-4):132-137
Consideration of factors influencing the interaction between a corer and sediment suggest the likelihood of significant and
anisotropic straining of the particle framework during coring. Direct observations allow the coring process to be discretised,
the relative motion of corer, core and sediment to be visualized and confirm that the development of differences between corer
penetration and core length is not a continuous process. Records suggest the possibility of dislocation of the relative positions
of porewater and particle framework, which may lead to the disequilibration of sorbed species. 相似文献
758.
A densely populated soft-sediment community was experimentally analysed for interspecific competition for space in laboratory experiments. No interspecific competitive interactions leading to a decrease in survivorship could be documented over a five-week period. The four most abundant species all coexisted in laboratory microcosms. The two tube-buiding species, the tanaid Leptochelia dubia and the polychaete Rhynchospio arenincola, could not exclude the mobile bivalve Transennella tantilla or the burrowing amphipod Paraphoxus spinosus. None of the species increases its emigration frequency when other species are present. Paraphoxus is found to be a browsing predator on Phynchospio but inflicts no detectable mortality. The coexistence of these species is permitted by virtue of the fact that none of the species can alter the soft-sediment habitat sufficiently to make the habitat unsuitable for the other species. 相似文献
759.
760.