Tephrostratigraphy and paleo-environmental implications of Late Quaternary sediments and interstitial water in the western Ulleung Basin, East/Japan Sea

Two piston cores, collected from the western Ulleung Basin of the East/Japan Sea, were used to investigate the Late Quaternary tephrostratigraphy, lithology, and mineralogy of the sediments, as well as the elemental composition of both sediments and interstitial water, and their paleo-environmental implications. The cores show two lapilli tephra layers and one rhyolitic ash layer at the boundaries between sedimentary lithofacies units I, II, and III. These layers can be correlated with the well-known Ulleung-Oki (ca. 9.3 ka; boundary of units I/II), Ulleung-Yamato (ca. 25–33 ka), and Aira-Tanzawa (ca. 25.1 ka; boundary of units II/III) layers, respectively. These data suggest that the cores cover the period from the middle stage of marine isotope stage (MIS) 3 to the Holocene. In each core, a so-called dark laminated mud (DLM) layer in unit II commonly has high contents of Si and Al, suggesting that the DLM layer generally contains significant amounts of fine-grained silicates and/or aluminosilicates. In addition, these DLM layers are enriched in Fe relative to Mn, iron being predominantly bound in framboidal pyrite. The size distribution of pyrite in the DLM layers suggests that these have formed under anoxic (euxinic) conditions at times of reduced water circulation in the basin during sea-level lowstand (euxinic environment). The C/N ratios [5–12] suggest that sedimentary organic matter in the cores is predominantly of marine origin. Total organic carbon (TOC) contents increased shortly before Termination I. This could have been caused by an increased flux of marine organic matter in association with sea-level rise. The C and S values of units II and III (Late Pleistocene sediments; C: <2.0%; S: 0.5–2.1%) suggest a more euxinic environment than that of unit I (Holocene sediments; C: 1.0–3.5%; S: <1.0%). Concentrations of SO₄^2– in the interstitial water decrease with increasing burial depth, whereas CH₄ concentrations show the reverse trend. Therefore, it seems that sulfate reduction, probably related to microbial activity, predominates in the upper core sections (<5 m), shifting to methanogenesis in the lower core sections.     

Marine mammals from northeast Atlantic: relationship between their trophic status as determined by delta13C and delta15N measurements and their trace metal concentrations

The relationship between trophic position through delta13C and delta15N and trace metal concentrations (Zn, Cd, Cu and Hg) was investigated in the tissues of six marine mammal species from the Northeast Atlantic: striped dolphin Stenella coeruleoalba, common dolphin, Delphinus delphis, Atlantic white-sided dolphin Lagenorhynchus acutus, harbour porpoise Phocoena phocoena, white beaked-dolphin Lagenorhynchus albirostris, grey seal Halichoerus grypus stranded on French Channel and Irish coasts. White-beaked dolphins, harbour porpoises, white-sided dolphins, common and striped dolphins display the same relative and decreasing trophic position, as measured by delta15N values, along both the Irish and French channel coasts, reflecting conservative trophic habits between these two places. Hepatic and renal Cd concentrations were significantly correlated to muscle delta13C and delta15N values while Hg, Zn and Cu did not. These results suggest that Cd accumulation is partly linked to the diet while other factors such as age or body condition might explain Hg, Zn or Cu variability in marine mammals. Combined stable isotope and trace metal analyses appear to be useful tools for the study of marine mammal ecology.     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Viscous model of plate tectonics for the Black Sea region (in relation to the problem of the late Cenozoic evolution of the Black Sea basins)

A numerical model of the Black Sea region (Northeastern Mediterranean) is presented in which it is regarded as a part of the mosaic plate ensemble consisting of the fixed East European platform; the active Arabian, Adriatic, and Pannonian plates; and passive East and West Black Sea and Mysian microplates, which are embedded in a plastically deformable regional orogenic matrix. The fields of displacements, stresses, and deformations in the region are calculated by means of the finite element method within the framework of a linear-viscous rheology approach to a system with nonhomogeneous viscosities. The velocity field obtained is in good agreement with published data of direct observations of plate displacements in the region. In the pressure field, areas of low pressure and decompression are established in the western part of Black Sea and in the south of the Mysian microplate. The poles of rotation of the East and West Black Sea microplates and of the Mysian microplate are computed. For the latter two microplates, significant rotational components are suggested. The East Black Sea microplate acts mostly as indenter, which transmits the collisional motion from the Arabian plate to the southern edge of the East European platform including the Crimea. According to the geodynamical model, the rates of the Cenozoic sedimentation in the Black Sea depression at the collision stage (Oligocene-Pliocene) result from the greater compression of the East Black Sea microplate as compared to the West Black Sea microplate, which, probably, experienced a kind of extension.     

Numerical investigation of the influence of various factors on the propagation and transformation of solitary waves in the sea

For various stratifications and different types of bottom patterns we study the transformations of solitary perturbations of density appearing in the depth of the sea. In the two-dimensional case, under the assumption that the average dynamic characteristics weakly vary in time as compared with the wave characteristics, we deduce the equations for mean currents and waves taking into account vertical and horizontal viscosity and the diffusion of density. Numerical examples show that the stratification, bottom topography, nonlinearity, mean currents, and dissipation strongly affect both the process of splitting of a solitary wave into wave trains and their amplitude and length. The wave currents exhibit the oscillatory (train-like) character. It is emphasized that, in the case of propagation of solitary perturbations of density with dissipation, it is also important to take into account the combined influence of nonlinearity, currents, bottom topography, and stratification. Translated by Peter V. Malyshev and Dmitry V. Malyshev     

Structural monitoring of offshore platforms using impulse and relaxation response

Monitoring offshore platforms, long span bridges, high rise buildings, TV towers and other similar structures is essential for ensuring their safety in service. Continuous monitoring assumes even greater significance in the case of offshore platforms, which are highly susceptible to damage due to the corrosive environment and the continuous action of waves. Also, since a major part of the structure is under water and covered by marine growth, even a trained diver cannot easily detect damage in the structure. In the present work, vibration criterion is adopted for structural monitoring of jacket platforms. Artificial excitation of these structures is not always practicable and ambient excitation due to wind and waves may not be sufficient for collecting the required vibration data. Alternate methods can be adopted for the same purpose, for example, the application of an impact or a sudden relaxation of an applied force for exciting the structure. For jacket platforms, impact can be applied by gently pushing the structure at the fender while relaxation can be accomplished by pulling the structure and then suddenly releasing it using a tug or a supply vessel in both cases. The present study is an experimental investigation on a laboratory model of a jacket platform, for exploring the feasibility of adapting vibration responses due to impulse and relaxation, for structural monitoring. Effects of damage in six members of the platform as well as changes in deck masses were studied. A finite element model of the structure was used to analyze all the cases for comparison of the results as well as system identification. A data acquisition and analysis procedure for obtaining the response signatures of the platform due to the impulse and relaxation procedure was also developed for possible adoption in on-line monitoring of offshore platforms. From the study, it has been concluded that both impulse and relaxation responses are useful tools for monitoring offshore jacket platforms. The present work forms the basis for the development of an automated, on-line monitoring system for offshore platforms, using neural networks.