Survival of organic phases in porous IDPs during atmospheric entry: A pulse‐heating study

Abstract— In this study, we have performed pulse‐heating experiments at different temperatures for three organic molecules (a polycyclic aromatic hydrocarbon [PAH], a ketone, and an amino acid) absorbed into microporous aluminum oxide (Al₂O₃) in order to imitate the heating of the organic molecules in interplanetary dust particles (IDPs) and micrometeorites (MMs) during atmospheric entry and to investigate their survival. We have shown that modest amounts (a few percent) of these organic molecules survive pulse‐heating at temperatures in the 700 to 900 °C range. This suggests that the porosity in IDPs and MMs, combined with a sublimable phase (organic material, water), produces an ablative cooling effect, which permits the survival of organic molecules that would otherwise be lost either by thermal degradation or evaporation during atmospheric entry.     

A sensitivity study of the role of continental location and area on Paleozoic climate

The seasonal variation of the surface temperature is calculated for various idealized paleogeographic conditions with a 1.5-dimensional (1.5-D) coupled climate-sea ice model. The sensitivity of the annual and summer polar temperatures to the meridional oceanic heat transport and to the parameterizations adopted for the snow and sea ice albedos is examined in connection with the location and size of a polar global super-continent. It is shown that the high latitude summer temperatures remain below the freezing point in all numerical simulations with a polar super-continent, thus suggesting the potential role played by a large polar continental mass in the initiation of glaciations. These results are in agreement with a previous 1.5-D energy balance model (EBM) study but in conflict with two-dimensional (2-D) EBMs suggesting above-freezing high latitude summer temperatures in the case of a polar-centered super-continent. It is also found that the amount of seasonality is strongly dependent on the details of the surface albedo feedback parameterizations and could explain the various model diverging results.If a simplified temperature dependence of the silicate weathering rate controlling the long-term carbon cycle is included, the atmospheric CO₂ level is significantly increased in the case of a polar-centered continent but summer temperatures still remain below freezing.     

A non-coherent surface backscattering model for radar observation of planetary bodies and its application to Cassini radar altimeter

Mission and hardware constraints make the Cassini radar altimeter working in the beam limited or pulse limited mode dependent on the radar operative mode (Low and High Resolution, respectively), but never allows work in a condition such that the pulsewidth limited circle is much smaller than the beamwidth limited circle. Unfortunately this latter condition is vital for the application of the so-called Brown model widely and successfully used in Earth (ocean) observation missions where the quoted condition is really met. In the paper a new model is discussed which is based on the same general hypotheses of the Brown model but is worked out by means of a different approach which makes it more general and independent of the specific operative conditions. An extension of the new model to take into account large mispointing angles is considered as well based on a series expansion of the Bessel function and on the analysis of the truncation error. Finally a comparison with the classical Brown model is discussed too.     

Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.