New constraints on elemental and Pb and Nd isotope compositions of South American and Southern African aerosol sources to the South Atlantic Ocean

Improving the geochemical database available for characterising potential natural and anthropogenic aerosol sources from South America and Southern Africa is a critical precondition for studies aimed at understanding trace metal controls on the marine biogeochemical cycles of the South Atlantic Ocean. We here present new elemental and isotopic data for a wide range of sample types from South America and Southern Africa that are potentially important aerosol sources. This includes road dust from Buenos Aires and lichen samples from Johannesburg, soil dust from Patagonia, volcanic ash from the Andean volcanic belt, and aerosol samples from São Paulo. All samples were investigated for major (Al, Ca, Fe, Mg, Na, K, Mn) and trace element (Cd, Co, Cr, Cu, Ni, Pb, REE, Sc, Th, Y, V, Zn) concentrations and Nd and Pb isotopic compositions. We show that diagrams of ²⁰⁸Pb/²⁰⁷Pb vs. ε_Nd, ²⁰⁸Pb/²⁰⁷Pb vs. Pb/Al, 1/[Pb], Zn/Al, Cd/Al, Cu/Al, and ε_Nd vs. Pb/Al, and 1/[Nd] are best suited to separate South American and South African source regions as well as natural and anthropogenic sources. A subset of samples from Patagonia and the Andes was additionally subjected to separation of a fine (<5?μm) fraction and compared to the composition of the bulk sample. We show that differences in the geochemical signature of bulk samples between individual regions and source types are significantly larger than between grain sizes. Jointly, these findings present an important step forward towards a quantitative assessment of aeolian trace metal inputs to the South Atlantic Ocean.     

Common but differentiated convergence (CDC): a new conceptual approach to long-term climate policy

Abstract

This article describes a new concept for an international climate regime for differentiation of future commitments: the ‘common but differentiated convergence’ approach (CDC). Under CDC, Annex-I countries' per-capita emission allowances converge within a convergence period to a low level. Individual non-Annex-I countries' allowances converge to the same level also within the same period (‘common convergence’), but starting when their per-capita emissions are a certain percentage above global average (‘differentiated’). Until then they may voluntarily take on ‘positively binding’ targets. This approach eliminates two concerns often voiced in relation to gradually converging per-capita emissions: (i) advanced developing countries have their commitment to reduce emissions delayed and their targets are not the same as Annex-I countries with equal per-capita emissions; (ii) CDC does not provide excess emission allowances to the least developing countries. Under CDC, stabilizing greenhouse gas concentrations at 550 and 650 ppm CO₂-equivalent can be reached with participation at roughly 0% and 50% above global average and convergence to around 3 and 4.5 tCO₂-eq/cap within 40 years. Even if the CDC approach is not implemented in its entirety, it is possible that the step-by-step decisions on the international climate regime can be guided by the principles provided in the CDC approach.     

The bombardment history of the Moon as recorded by 40Ar‐39Ar chronology

New petrography and ⁴⁰Ar‐³⁹Ar ages have been obtained for 1–3 mm sized rock fragments from Apollo 16 Station 13 soil 63503 (North Ray crater ejecta) and chips from three rocks collected by Apollo 16 and Apollo 17 missions. Selection of these samples was aimed at the old ⁴⁰Ar‐³⁹Ar ages to understand the early history of the lunar magnetic field and impact flux. Fifteen samples were studied including crustal material, polymict feldspathic fragmental breccias, and impact melts. The impact ages obtained range between approximately 3.3 and 4.3 billion years (Ga). Polymict fragmental breccia 63503,1 exhibits the lowest signs of recrystallization observed and a probable old relic age of 4.547 ± 0.027. The plateau age of 4.293 ± 0.044 Ga obtained for impact melt rock 63503,13 represents the oldest known age for such a lithology. Possibly, this age represents the minimum age for the South Pole‐Aitken (SPA) Basin. In agreement with literature data, these results show that impact ages >3.9 Ga are found in lunar rocks, especially within soil 63503. Impact exhumation of deep‐seated warm crustal material onto the lunar surface is considered to explain the common 4.2 Ga ages obtained for weakly shocked samples from soil 63503 and Apollo 17. This would directly imply that one or more basin‐forming events occurred at that time. Some rock fragments showing none to limited petrologic features indicate thermal annealing. These rocks may have lost Ar while resident within the hot‐ejecta of a large basin. Concurrent with previous studies, these results lead us to advocate for a complex impact flux in the inner solar system during the initial approximately 1.3 Ga.     

Calibration of the New Certified Reference Materials ERM‐AE633 and ERM‐AE647 for Copper and IRMM‐3702 for Zinc Isotope Amount Ratio Determinations

The commonly used, but no longer available, reference materials NIST SRM 976 (Cu) and ‘JMC Lyon’ (Zn) were calibrated against the new reference materials ERM^®‐AE633, ERM^®‐AE647 (Cu) and IRMM‐3702 (Zn), certified for isotope amount ratios. This cross‐calibration of new with old reference materials provides a continuous and reliable comparability of already published with future Cu and Zn isotope data. The Cu isotope amount ratio of NIST SRM 976 yielded δ^65/63Cu values of ?0.01 ± 0.05‰ and ?0.21 ± 0.05‰ relative to ERM^®‐AE633 and ERM^®‐AE647, respectively, and a δ^66/64Zn_IRMM‐3702 value of ?0.29 ± 0.05‰ was determined for ‘JMC Lyon’. Furthermore, we separated Cu and Zn from five geological reference materials (BCR‐2, BHVO‐2, BIR‐1, AGV‐1 and G‐2) using a two‐step ion‐exchange chromatographic procedure. Possible isotope fractionation of Cu during chromatographic purification and introduction of resin‐ and/or matrix‐induced interferences were assessed by enriched ⁶⁵Cu isotope addition. Instrumental mass bias correction for the isotope ratio determinations by MC‐ICP‐MS was performed using calibrator‐sample bracketing with internal Ni doping for Cu and a double spike approach for Zn. Our results for the five geological reference materials were in very good agreement with literature data, confirming the accuracy and applicability of our analytical protocol.     

A Giant Water Maser Flare in the Galactic Source IRAS 18316-0602

Astronomy Reports - The results of long-term monitoring of the Galactic maser source IRAS 18316–0602 (G25.65+1.05) in the water-vapor line at frequency f = 22.235 GHz (616–523...     

The role of climate-related information in pest management

Summary A distinction is made between climate information and climate-related information. The former pertains to any expression of climate data used for decision making. Climaterelated information for pest management results from quantifying relationships between host, environment, and pest and presenting the consequences of different actions, a decisionmaking format. It is suggested that in order to develop climate-related information for pest management, automated weather stations in climatological networks should be expanded from these site specific locations to crop specific locations. Combining physical and biological data can be the basis for developing or improving crop/pest interaction models and can also serve as a database for verifying existing models. These models can be run under different economic and climatic scenarios with different risk preferences to present end users with results from different pest management options.With 2 Figures     

An Assessment of Snow Avalanche Paths and Forest Dynamics Using Ikonos Satellite Data

Abstract

Ikonos panchromatic and multispectral satellite data were acquired in October 2000 and August 2002 for a test area along US Highway 2, the southern border of Glacier National Park (GNP), Montana, USA. The research goals were to map snow avalanche paths and to characterize vegetation patterns in selected paths for longitudinal (i.e., source, track, and runout) and transverse (i.e., inner, flanking, outer) zones as part of a study of forest dynamics and nutrient flux from paths into terrestrial and aquatic systems. In some valleys, as much as 50 percent of the area may be covered by snow avalanche paths, and as such, serve as an important carbon source servicing terrestrial and aquatic ecosystems. Snow avalanches move woody debris down‐slope by snapping, tipping, trimming, and excavating branches, limbs, and trees, and by injuring and scaring trees that remain in‐place. Further, snow avalanches alter the vegetation structure on paths through secondary plant succession of disturbed areas. Contrast and edge enhancements, Normalized Difference Vegetation Index (NDVI), and the Tasseled Cap greenness and wetness transformations were used to examine vegetation patterns in selected paths that were affected by high magnitude snow avalanches during the winter of 2001-2002. Using image transects organized in longitudinal patterns in paths and in forests, and transects arranged in transverse patterns across the sampled paths, the Tasseled Cap transforms (and NDVI values) were plotted and assessed. Preliminary results suggest that NDVI patterns are different for paths and forests, and Tasseled Cap greenness and wetness patterns are different for longitudinal and transverse zones that describe the morphology of snow avalanche paths. The differentiation of paths from the background forest and the characterization of paths by morphometric zones through remote sensing has implications for mapping forest disturbances and dynamics over time and for large geographic areas and for modeling nutrient flux in terrestrial and aquatic systems.     

Boundary layer characteristics and turbulent exchange mechanisms in highly complex terrain

The Mesoscale Alpine Programme’s Riviera project investigated the turbulence structure and related exchange processes in an Alpine valley by combining a detailed experimental campaign with high-resolution numerical modelling. The present contribution reviews published material on the Riviera Valley’s boundary layer structure and discusses new material on the near-surface turbulence structure. The general conclusion of the project is that despite the large spatial variability of turbulence characteristics and the crucial influence of topography at all scales, the physical processes can accurately be understood and modelled. Nevertheless, many of the “text book characteristics” like the interaction between the valley and slope wind systems or the erosion of the nocturnal valley inversion need reconsideration, at least for small non-ideal valleys like the Riviera Valley. The project has identified new areas of research such as post-processing methods for turbulence variables in complex terrain and new approaches for the surface energy balance when advection is non-negligible. The exchange of moisture and heat between the valley atmosphere and the free troposphere is dominated by local “secondary” circulations due to the curvature of the valley axis. Because many curved valleys exist, and operational models still have rather poor resolution, parameterization of these processes may be required.     

On the magnetic field in pores

The magnetic field in an axisymmetric pore is current free and can be represented by a flux tube with a magnetic potential of the formAJ ₀(kr)e ^-kz. For a given magnetic flux the field in this pore model is uniquely defined if the magnetic pressure balances the gas pressure at two levels. For models with fluxes of 0.5–3.0 × 10²⁰ mx the surface radius varies from 1100–2700 km (diameters of 3–8 arc-sec) and the Wilson depression is estimated at 200 km. As the flux increases, the field becomes nearly horizontal at the edge of the pore and eventually a penumbra is formed. The distinction between pores and sunspots is investigated; the critical flux is about 10²⁰ Mx, corresponding to a radius of 1500 km.Visitor, as a member of the High Altitude Observatory Solar Project, at Sacramento Peak Observatory, Sunspot, N.M., U.S.A.     

Geomagnetic induction in a heterogeneous sphere: fully three-dimensional test computations and the response of a realistic distribution of oceans and continents

Long-period geomagnetic data can resolve large-scale 3-D mantle electrical conductivity heterogeneities which are indicators of physiochemical variations found in the Earth's dynamic mantle. A prerequisite for mapping such heterogeneity is the ability to model accurately electromagnetic induction in a heterogeneous sphere. A previously developed finite element method solution to the geomagnetic induction problem is validated against an analytic solution for a fully 3-D geometry: an off-axis spherical inclusion embedded in a uniform sphere. Geomagnetic induction is then modelled in a uniform spherical mantle overlain by a realistic distribution of oceanic and continental conductances. Our results indicate that the contrast in electrical conductivity between oceans and continents is not primarily responsible for the observed geographic variability of long-period geomagnetic data. In the absence of persistent high-wavenumber magnetospheric disturbances, this argues strongly for the existence of large-scale, high-contrast electrical conductivity heterogeneities in the mid-mantle. Lastly, for several periods the geomagnetic anomaly associated with a mid-mantle spherical inclusion is calculated. A high-contrast inclusion can be readily detected beneath the outer shell of oceans and continents. A comparison between observed and computed c responses suggests that the mid-mantle contains more than one order of magnitude of lateral variability in electrical conductivity, while the upper mantle contains at least two orders of magnitude of lateral variability in electrical conductivity.