Diatomeenstratigraphische Untersuchungen zur Trophieänderung und Industrieschlammakkumulation im Traunsee/Österreich

Three cores from Traunsee were investigated and compared with respect to diatom stratigraphy concerning dating of incursions into and rate of accumulation of industrial tailings in the profundal zone.

     

The significance of scarp retreat for cenozoic landform evolution on the Colorado Plateau,U.S.A.

Since the beginning of the Cenozoic period several hundreds of metres of the sedimentary cover have been removed from the Colorado Plateau. Palaeoclimatic considerations show that the Colorado Plateau has been dominated by dry climates throughout the Cenozoic with the possible exception of the early Palaeocene. Today in the still prevailing arid climate, which strongly accentuates differences in rock resistance, the relief shows a structurally controlled cuesta scarp topography in the slightly deformed strata of alternating resistance. In examining whether the denudational efficiency of scarp retreat was sufficient to account for the wide erosional gaps in the sedimentary cover, rates of scarp retreat were determined by using the information of dated volcanic material and by applying a new method, which calculates the amount of retreat from the width of beheaded valleys of known age. Rates of retreat range from 0·5 to 6·7 km my^?1. The results show that the rates of retreat are controlled by the thickness and resistance of the caprocks. A model of Cenozoic scarp retreat demonstrates that the rates of recession calculated for the scarps in Upper Cretaceous rocks were sufficient to bring them into their present positions from the centre of the Monument Uplift on the central Colorado Plateau. The late Eocene positions of the cliffs in the Early Tertiary formations give an indication of their maximal extent. After the Upper Cretaceous sediments had been removed from the uplifts, erosion cut through successively older rocks, and activated scarps in stratigraphically lower positions. Scarp retreat can operate simultaneously and independently at different levels, which enabled this erosional mechanism to remove great proportions of the sedimentary cover of the Colorado Plateau during the Cenozoic.     

Elektrosorptionsanalyse: Ein empfindliches Verfahren zum Nachweis grenzflächenaktiver Stoffe im Wasser

Two examples of damages: Damages to waters caused by surfaceactive polyethylene glycolacrylate (PEGA) waste waters and a fire extinguishing substance (30 % fatty alkyl sulphate and 15 % ethylene glycol butyl ether) are analytically evaluated. A new method from polarography was described – the electrosorption analysis –, which was tested on the samples of the waste waters and waters of the events of damage. For comparison, investigations were carried out according to the conventional laboratory routine method. The described new method has shown pronounced advantages with respect to the detectability of substances contained in water and the expenditure of material and time. Individual tensides can be determined if known separation processes are applied in advance.     

Alteration zones around Kupferschiefer-type base metal mineralization in West Germany

Several occurrences of red-colored rocks, which represent an unusual species within the lower Zechstein sediments as well as siderite ribbons and kaolinization have been reported from the West German lower Zechstein sequence. The red-colored rocks had been classified into two types, i.e., the stratiform red layers (SRL) and the Rote Fäule (RF). With regard to the gray beds, both types are characterized by enrichments and depletions of certain elements. As a result, ore-related Rote Fäule could be distinguished from insignificant stratiform red layers. Whereas Rote Fäule, which represents the alteration zone around diagenetic Kupferschiefer-type deposits, is chiefly characterized by apparent red coloring and enrichment in sulfate S, both the siderite ribbons and kaolinization of feldspars refer to formation of Cu-As sulfides and arsenides due to a hydrothermal, epigenetic process. Formation under more oxidizing, synsedimentary conditions is presumed for the stratiform red layers.     

Regional variation of mechanical and chemical denudation,upper Colorado River Basin,U.S.A.

The variation of mechanical and chemical denudation is investigated using discharge and sediment yield data from the Upper Colorado River System. Annual precipitation ranges from approximately 150 mm to 1500 mm. Mean specific yield ranges from 0-2 1/s km² ( = 6 mm p a) to 151/s km² ( = 475 mm p a). The hydrological-geomorphological system adjusts itself to these varying climatic conditions; in some areas, however, the effects of lithology or land use seem to override the climatic controls. It is demonstrated that the increase in the absolute and particularly the relative amount of suspended sediment is closely related to a decrease in annual runoff and to an increase in the importance of high magnitude/low frequency events. This indicates that in areas of low annual runoff and high runoff variability, soluble rocks are more resistant than in more humid areas. During high magnitude/low frequency events, suspended sediment concentrations and loads are very high in semiarid areas due to sparse vegetation cover and dominance of direct runoff. Events of moderate magnitude and frequency, which in more humid areas transport most of the dissolved load, seldom occur. The trend towards increasing mechanical denudation is even observed in areas of very low runoff (0-221/s km² = 7 mm p a). The peak of sediment yield in dry areas seems to approximate the point of no runoff very closely. Mechanical and chemical denudation are of equal importance at a runoff of about 300 mm per year.     

Decompression experiments as an insight into ascent rates of silicic magmas

An experimental study of H₂O exsolution, bubble growth and microlite crystallisation during ascent (decompression) of silicic magmas in the volcanic conduit is presented. Isobaric and decompression experiments were performed on a rhyolitic melt at 860 °C, NNO+1, H₂O saturation, and pressures between 15 and 170 MPa. Two sets of decompression experiments were performed, with decompression rates varying between 0.001 and 960 MPa/min: (1) from 150 to 50 MPa (high-pressure decompression), and (2) from 50 to 15 MPa (low-pressure decompression). The experiments highlight incomplete H₂O exsolution for decompression rates>100 MPa/min, incomplete bubble growth for decompression rates>0.1 MPa/min, crystal nucleation time lags, and incomplete chemical re-equilibration to final pressures. The observed crystallisation process, i.e. growth versus nucleation, depends on the decompression range. Indeed, decompression-induced crystallisation during high-pressure decompressions is dominated by growth of existing crystals, whereas during low-pressure decompressions crystal nucleation is the dominating process. This study provides a means to infer magma ascent rates in eruptions of silicic magmas through a combined petrologic and experimental approach.     

Comparison of Two Wavelet Transform Coherence and Cross-Covariance Functions Applied on Polar Motion and Atmospheric Excitation

The wavelet transform techniques were applied to compute time-frequency spectra, coherence and cross-covariance functions between complex-valued polar motion and atmospheric excitation functions. These wavelet transform approaches are based on the classical wavelet transform with Morlet wavelet and the harmonic wavelet transform. The computed coherence and cross-covariance functions enable comparison of polar motion and atmospheric excitation functions data in the chosen frequency band. In the study we concentrate on short period oscillations with periods ranging from several to about 250 days. The time lag functions show frequency dependent time lags corresponding to maxima of the modules of cross-covariance functions between the polar motion and atmospheric excitation functions.     

Hydrological conditions over the western Mediterranean basin during the deposition of the cold Sapropel 6 (ca. 175 kyr BP)

A new oxygen isotope record is reported from a stalagmite collected in the Argentarola Cave located on the Tyrrhenian coast of Italy. As shown from observations and numerical modeling of δ¹⁸O in modern precipitation, the recorded δ¹⁸O variability for this zone is dominated by the amount of precipitation (so-called ‘amount effect’). The δ¹⁸O profile measured in the stalagmite is characterized by a prominent negative excursion (ca. 2-3‰) between 180 and 170 kyr BP. This paleoclimatic feature is interpreted as being due to a relatively wet period which occurred during the penultimate glacial period, more precisely, during Marine Isotope Stage 6.5. This pluvial phase is shown to correspond chronologically to the deposition of the sapropel event 6 (S6). Although this particular sapropel event occurred during a cold phase, the δ¹⁸O excursion is similar to those corresponding to other sapropels (S4, S3 and S2). The evidence for humid conditions during S6 in the western Mediterranean basin agrees with previous studies based on deep-sea sediment cores. Taken collectively, the data suggest that during sapropel events dilution of ocean surface waters was not restricted to the output of the river Nile but was rather widespread over the entire Mediterranean Sea due to increased rainfall.     

Environmental records of carbon in recent lake sediments

Based on careful sampling and accurate analysis of recent sediments in Lake Chenghai, this paper discusses the staggered positive/negative correlation between organic carbon (OC) concentration and inorganic carbon (IC) concentration. The result indicates that temperature change, and its induced relative changes are the main factors affecting the relationship between IC concentration, δ¹³C of carbonate and OC concentration. When temperature and its induced photosynthesis strength change control autochthonous calcite precipitation, OC concentration is positively correlated with IC concentration and δ¹³C of carbonate. When temperature and its induced physical/chemical changes dominate, OC concentration displays negative correlation with IC concentration and δ¹³C of carbonate. IC concentration and δ¹³C of carbonate in sediments of Lake Chenghai are good proxies for climatic warm/cold changes.     

湖泊现代沉积物碳环境记录研究

通过对云南程海现代沉积物的精细采样和分析, 研究了湖泊沉积物中有机碳与无机碳含量阶段性的正相关和负相关变化. 结果表明, 温度及其引起的相关变化是控制沉积物无机碳含量、碳酸盐δ ¹³C和有机碳含量变化关系的主要因素. 当温度及其引起的光合作用强度变化对湖泊自生碳酸钙沉淀起主导作用时, 沉积物有机碳含量与无机碳含量及碳酸盐δ ¹³C呈正相关变化; 当温度及其引起的蒸发速率等其他物理化学因素变化对湖泊自生碳酸钙沉淀起主导作用时, 沉积物有机碳含量与无机碳含量及碳酸盐δ ¹³C呈负相关变化. 程海沉积物无机碳含量和碳酸盐δ ¹³C是湖区气候冷暖变化的良好代用指标.