Contribution of long-term hydrothermal experiments for understanding the smectite-to-chlorite conversion in geological environments

The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.     

Modelling larval dispersal and settlement of the reef-building polychaete Sabellaria alveolata: Role of hydroclimatic processes on the sustainability of biogenic reefs

The honeycomb worm Sabellaria alveolata forms biogenic reefs which constitute diversity hotspots on tidal flats. The largest known reefs in Europe, located in the Bay of Mont-Saint-Michel (English Channel), are suffering increasing anthropogenic disturbances which raise the question of their sustainability. As the ability to recover depends partly on the recolonization of damaged reefs by larval supply, evaluating larval dispersal and the connectivity between distant reefs is a major challenge for their conservation. In the present study, we used a 3D biophysical model to simulate larval dispersal under realistic hydroclimatic conditions and estimate larval retention and exchanges among the two reefs of different sizes within the bay. The model takes into account fine-scale hydrodynamic circulation (800×800 m²), advection–diffusion larval transport, and gregarious settlement behaviour. According to the field data, larval dispersal was simulated for a minimal planktonic larval duration ranging from 4 to 8 weeks and the larval mortality was set to 0.09 d⁻¹. The results highlighted the role played by a coastal eddy on larval retention within the bay, as suggested by previous in situ observations. Very different dispersal patterns were revealed depending on the spawning reef location, although the two reefs were located only 15 km apart. The settlement success of the larvae released from the smallest reef was mainly related to tidal conditions at spawning, with the highest settlement success for releases at neap tide. The settlement success of the larvae from the biggest reef was more dependent on meteorological conditions: favourable W and SW winds may promote a ten-fold increase in settlement success. Strong year-to-year variability was observed in settlers’ numbers, with favourable environmental windows not always coinciding with the main reproductive periods of Sabellaria. Settlement kinetics indicated that the ability to delay metamorphosis could significantly improve the settlement success. Although bidirectional exchanges occurred between the two reefs, the highest settlers’ numbers originated from the biggest reef because of its stronger reproductive output. Because of the recent decline of this reef due to increasing anthropogenic disturbances larval supply in the bay may not be sufficient enough to ensure the sustainability of the remarkable habitat formed by Sabellaria alveolata reefs.     

A catalog of tsunamis in New Caledonia from 28 March 1875 to 30 September 2009

In order to establish a tsunami alert system in New Caledonia in April 2008, the French Secretary of State for Overseas Affairs, with the aid of the UNESCO French Commission, mandated an investigation to build a more complete record of the most recent tsunamis. To complete this task, a call for witnesses was broadcast through various media and in public locations. These witnesses were then interviewed onsite about the phenomenon they had observed. Previous witness reports that had been obtained in the last few years were also used. For the most recent events, various archives were consulted. In total, 18 events were documented, of which 12 had not been previously mentioned in past work. These results confirm an exposure to a hazard of: (1) local origin (the southern part of the Vanuatu arc) with a very short post-seismic delay (< 30 min) before the arrival of wave trains; (2) regional origin (Solomon Islands arc, northern part of the Vanuatu arc) with a delay of several hours; and (3) an exposure to trans-oceanic tsunamis (Kamchatka 1952, South Chile 1960, Kuril Islands 2006, North Tonga 2009), unknown until today. These results highlight the necessity for New Caledonia to adopt an alert system, coupled with ocean tide gauges, that liaises with the main alert system for the Pacific (Pacific Tsunami Warning Center), and brings to light the importance of establishing a prevention campaign.     

Extreme Nd isotope homogeneity in a large rhyolitic province: the Estérel massif, southeast France

 Previous detailed studies of large rhyolite bodies propose that their elemental and isotopic characteristics were largely acquired in shallow crustal magma chambers. This model explains the common chemical and isotopic zonations of large volumes of rhyolites as well as the less common chemical and isotopic homogeneity of such bodies. We report an intermediate situation (the Estérel massif, southeast France) in which chemical variations contrast with Nd-isotope homogeneity. We thus infer that, in this case, large volumes of rhyolite resided for enough time in shallow magma chambers to develop chemical zonations through differentiation, but this process was not accompanied by crustal assimilation. The subordinate amount of mafic rocks cropping out in the Estérel probably evolved from basalt to trachyte through assimilation and fractional crystallization. The relatively radiogenic Nd-isotope signatures of the rhyolite compared with the Hercynian crust show that it cannot have been generated by partial melting of exposed basement rocks. Several geological similarities with large rhyolitic provinces could suggest that the rhyolite was purely mantle derived or, alternatively, generated by partial melting of an ad hoc crustal component. However, mineralogical, geochemical, and geodynamic connections between the Estérel rhyolite and the hypersolvus anorogenic granites of Corsica, as well as the extreme Nd-isotope homogeneity of the rhyolite, lead us to propose that the rhyolite was generated by mixing between mantle-derived magmas and a mafic lower crust. This scenario accounts for the relatively radiogenic Nd-isotope signatures of the rhyolite compared with the Hercynian crust. The good Nd-isotope homogeneity observed in the rhyolite implies that the mixing process, which occurred in the deep crust, was complete and provided a shallow magma chamber with isotopically and probably chemically homogeneous magmas. Received: 5 December 1997 / Accepted: 16 June 1998     

The legacy of Venus Express: highlights from the first European planetary mission to Venus

The ESA/Venus Express mission spent more than 8 years in orbit around Venus to extensively study its atmosphere, ionosphere and plasma environment and unveil new aspects of its surface. Extensive reviews of the work of Venus Express are underway, to cover in-depth studies of the new face of Venus revealed by Venus Express and ground-based concurrent observations. This paper intends to give a summarized and wide overview of some of the outstanding results in all the science areas studied by the mission. This paper will first review the main aspects of the mission and its instrumental payload. Then, a selection of results will be reviewed from the outermost layers interacting with the Solar wind, down to the surface of Venus. As Venus Express is already considered by space agencies as a pathfinder for the future of Venus exploration, perspectives for future missions will be given, which will have to study Venus not only from orbital view, but also down to the surface to solve the many remaining mysteries of the sister planet of the Earth.     

Oldest description of a caldera-forming eruption in Southeast Asia unveiled in forgotten written sources

GeoJournal - As one of the most powerful volcanic events of the Holocene era with a Volcanic Explosivity Index of seven, the 1257 CE eruption of Samalas volcano in the Rinjani Volcanic Complex had...     

Comparison of HIPWAC and Mars Express SPICAM observations of ozone on Mars 2006-2008 and variation from 1993 IRHS observations

Ozone is a tracer of photochemistry in the atmosphere of Mars and an observable used to test predictions of photochemical models. We present a comparison of retrieved ozone abundances on Mars using ground-based infrared heterodyne measurements by NASA Goddard Space Flight Center’s Heterodyne Instrument for Planetary Wind And Composition (HIPWAC) and space-based Mars Express Spectroscopy for the Investigation of the Characteristics of the Atmosphere of Mars (SPICAM) ultraviolet measurements. Ozone retrievals from simultaneous measurements in February 2008 were very consistent (0.8 μm-atm), as were measurements made close in time (ranging from <1 to >8 μm-atm) during this period and during opportunities in October 2006 and February 2007. The consistency of retrievals from the two different observational techniques supports combining the measurements for testing photochemistry-coupled general circulation models and for investigating variability over the long-term between spacecraft missions. Quantitative comparison with ground-based measurements by NASA/GSFC’s Infrared Heterodyne Spectrometer (IRHS) in 1993 reveals 2-4 times more ozone at low latitudes than in 2008 at the same season, and such variability was not evident over the shorter period of the Mars Express mission. This variability may be due to cloud activity.     

Performance analysis of multi-GNSS static and RTK techniques in estimating height differences

ABSTRACT

Establishing reliable elevation differences is imperative for most geoscience and engineering applications. This work has traditionally been accomplished through spirit leveling techniques; however, surveyors have been utilizing satellite positioning systems in measuring height differences for more than a decade. Yet the quality of these heights needs to be evaluated in order to adopt them in different applications. In this article, we present the outcome of an accuracy assessment of height differences obtained with static and RTK surveys. Twenty control points with an average baseline length of 1?km were occupied with dual-frequency GNSS receivers for different time periods. Collected signals were processed using open-source software and verified with an online processing tool. Heights were estimated by processing the GPS and the GLONASS data individually, and combined (i.e. GNSS). Height differences were determined and compared with those measured by spirit levels and corrected through geoid models. Best results were achieved by combining GPS and GLONASS solutions for both static and RTK surveys. Solutions with either GPS or GLONASS satellites were comparable, but in most cases, the GPS solutions performed better. For the static surveys, longer occupation provided much accurate height differences. Inconsistencies among 10 different RTK surveys were minimum for the GPS?+?GLONASS solutions and worst for the GLONASS solutions. The ANOVA, LSD, F, and χ² statistical tests confirmed our findings at the 95% confidence level.     

Volcanic hazards at Mount Semeru,East Java (Indonesia), with emphasis on lahars

Mt. Semeru, the highest mountain in Java (3,676 m), is one of the few persistently active composite volcanoes on Earth, with a plain supporting about 1 million people. We present the geology of the edifice, review its historical eruptive activity, and assess hazards posed by the current activity, highlighting the lahar threat. The composite andesite cone of Semeru results from the growth of two edifices: the Mahameru ‘old’ Semeru and the Seloko ‘young’ Semeru. On the SE flank of the summit cone, a N130-trending scar, branched on the active Jonggring-Seloko vent, is the current pathway for rockslides and pyroclastic flows produced by dome growth. The eruptive activity, recorded since 1818, shows three styles: (1) The persistent vulcanian and phreatomagmatic regime consists of short-lived eruption columns several times a day; (2) increase in activity every 5 to 7 years produces several kilometer-high eruption columns, ballistic bombs and thick tephra fall around the vent, and ash fall 40 km downwind. Dome extrusion in the vent and subsequent collapses produce block-and-ash flows that travel toward the SE as far as 11 km from the summit; and (3) flank lava flows erupted on the lower SE and E flanks in 1895 and in 1941–1942. Pyroclastic flows recur every 5 years on average while large-scale lahars exceeding 5 million m³ each have occurred at least five times since 1884. Lumajang, a city home to 85,000 people located 35 km E of the summit, was devastated by lahars in 1909. In 2000, the catchment of the Curah Lengkong River on the ESE flank shows an annual sediment yield of 2.7 × 10⁵ m³ km⁻² and a denudation rate of 4 10⁵ t km⁻² yr⁻¹, comparable with values reported at other active composite cones in wet environment. Unlike catchments affected by high magnitude eruptions, sediment yield at Mt. Semeru, however, does not decline drastically within the first post-eruption years. This is due to the daily supply of pyroclastic debris shed over the summit cone, which is remobilised by runoff during the rainy season. Three hazard-prone areas are delineated at Mt. Semeru: (1) a triangle-shaped area open toward the SE has been frequently swept by dome-collapse avalanches and pyroclastic flows; (2) the S and SE valleys convey tens of rain-triggered lahars each year within a distance of 20 km toward the ring plain; (3) valleys 25 km S, SE, and the ring plain 35 km E toward Lumajang can be affected by debris avalanches and debris flows if the steep-sided summit cone fails.     

Impact of recent climate change on the hydrology of coastal Mediterranean rivers in Southern France

The purpose of this paper is to analyse the regional impact of recent climate change on the water resources in southern France. We produced spatial reconstructions of the monthly evolutions of temperature, precipitation and water discharge in 15 watersheds of six coastal river basins and examined the major changes based on trend analysis for the last 40 years. In this part of the Mediterranean, the general warming trend was strongly enhanced by changes in the atmospheric circulation patterns, characterized by a northward extension of the subtropical high pressure domain during spring and summer. During these seasons, monthly warming rates could achieve almost twice the mean annual warming rates. Although annual precipitation did not follow clear trends, water discharge significantly decreased in one third of the watersheds and accounted for an estimated 20% reduction of the water resources in this region. This concerns both the highest and lowest watersheds. In the former, the reduction is likely the result of a temperature induced switch of snowfall to rainfall at high altitudes. In the latter, the reduction of discharge seems to come from lower groundwater levels, which may be related to the temperature increase too, but also have other origins. The recent climatic evolution is consistent with most modelling simulations for the future, indicating that the reduction of the water resources will hold on, probably still enhanced by decreases in precipitation.