Rheological characteristics of debris-flow material in South-Gargano watersheds

In recent years, debris flows have represented a severe natural hazard in South-Gargano watersheds (Puglia Region, Southern Italy). Hill slopes erosion, caused by the inadequate protection of the degraded forests, produces large amounts of soil and debris that are conveyed downstream during heavy rainstorms. The involved material is characterized by limestone fragments and blocks in a sandy-silt matrix. In this paper, the rheological properties of such debris-flow materials have been investigated. Eight specimens of particulated sediments of particle diameter of d ≤ 4 mm have been analysed using a rheometric tool for large particle suspensions, the ball measuring system (BMS). The influence of sediment concentration on the bulk rheological behaviour has been evaluated at concentrations by volume obtained in fully water-saturated conditions (volumetric sediment concentration C _V ~ 0.8) and with fixed water content (C _V = 0.42). The rheological data were fitted to the Bingham, Herschel–Bulkley, and O’Brien and Julien models to define viscosity and yield stress dependency on sediment concentration, to provide viscosity information for hazard mitigation as well as for comparison to other debris-flow events.     

Water quality and relationship between superficial and ground water in Rome (Aniene River basin,central Italy)

Chemical, physical, and biological features of streams and ground water of the North-Eastern area of Rome are jointly analyzed in order to assess the status of water resources. Ground water was investigated with classical survey methods (pH, temperature, and electric conductivity). Microbiological pollution, faunal composition, and stream surrounding area conditions of surface waters were studied, in order to quantify the residual value of these ecosystems from both a human and an environmental point of view. Results show a general impairment of the system and the comparison between superficial waters and shallow ground waters makes it possible to detect the presence of a connection between the two levels. This relationship occurs as an exchange from superficial waters (streams and rivers) to the shallow aquifers. Where superficial waters are contaminated, as in the Tor Sapienza stream, pollutants move to the shallow aquifers too, due to the decreased pressure of the over-exploited aquifer. Moreover, uncontrolled drilling activity, diffused in urban areas, makes it possible the connection between shallow and deep ground water. Notwithstanding this, the mixing between superficial and deep ground water system in Rome is not very widespread and, apparently, limited to restricted areas.     

Collaborative Web‐GIS Design: A Case Study for Road Risk Analysis and Monitoring

This article presents a methodology for designing a WebGIS framework intended for automatically analyzing spatial data and updating statistics of interest with new information inserted daily by multiple users via a Web portal. A practical example is used on vehicle accident data for assessing risk in specific road segments. Two main blocks integrated together will be described: the collaborative block and the data‐analysis block. The former gives end‐users computer‐aided tools to view, insert, modify and manage data related to accidents and traffic monitoring sensors, whereas the latter is developed to automatically analyze the accident data coming from user's collaboration. Because different agencies can survey accident sites, a collaborative environment is necessary – and a Web‐based solution is ideal – for permitting multi‐user access and data insertion. A centralized approach to process the data in real time is described in all its components. Server‐side Structured Query Language functions optimize performance by using dedicated libraries for spatial processing and re‐structuring the attributes associated with elements which are consequently re‐classified for correct color‐scaling. The end‐product is a system that provides a seamless integration of front‐end tools for user collaboration and back‐end tools to update accident risk statistics in real time and provide them to stakeholders.     

The collapse of primordial stars: importance of radiation

We simulate the collapse of a primordial protostellar cloud by means of a 1D hydrodynamics code accounting for chemical evolution, radiative transfer and radiation pressure. We find that the role of radiation pressure is negligible throughout the whole simulations, i.e. Until shortly after the formation of a central hydrostatic core. We also estimate the luminosity and the spectrum of such collapsing clouds. The luminosity is initially due to a number of H₂ lines and is of the order of 10^33-34 erg s^-1. It then grows to values ≳10³⁶ erg s^-1 by the time the core forms, and results from both HH lines and continuum radiation. This revised version was published online in September 2006 with corrections to the Cover Date.     

Structural performance of automated multi-depth shuttle warehouses (AMSWs) under low-to-moderate seismic actions

Bulletin of Earthquake Engineering - Automated Multi-Depth Shuttle Warehouses (AMSWs) are compact storage systems that provide a large surface occupation and therefore maximum storage density....     

OH incorporation in nearly pure MgAl2O4 natural and synthetic spinels

Four nearly pure MgAl₂O₄ spinels, of both natural and synthetic occurrence, have been studied by means of X-ray single crystal diffraction and FTIR spectroscopy in order to detect their potential OH content. Absorption bands that can be assigned to OH incorporated in the spinel structure were only observed in spectra of a non-stoichiometric synthetic sample. The absorption intensity of two bands occurring at 3350 and 3548 cm⁻¹ indicate an OH content of 90 ppm H₂O. Based on correlations of OH vibrational frequencies and O-H?O distances, the observed absorption bands correspond to O-H?O distances of 2.77 and 2.99 Å, respectively, which is close to the values obtained by the structure refinements for ^VIO-O_unsh (2.825 Å) and ^IVO-O (3.001 Å). This indicates that one probable local position for hydrogen incorporation is the oxygens coordinating a vacant tetrahedral site. The present spectra demonstrate that the detection limit for OH in Fe-free spinels is in the range 10-20 ppm H₂O. However, at appreciable Fe²⁺ levels, the detection of OH bands becomes hampered due to overlap with strong absorption bands caused by electronic d-d transitions in Fe²⁺ in the tetrahedral position.     

Effects of CO<Subscript>2</Subscript> flushing on crystal textures and compositions: experimental evidence from recent K-trachybasalts erupted at Mt. Etna

Changes in magmatic assemblages and crystal stability as a response of CO₂-flushing in basaltic systems have rarely been directly addressed experimentally, making the role of CO₂ in magma dynamics still controversial and object of scientific debate. We conducted a series of experiments to understand the response of magmas from Etna volcano to CO₂ flushing. We performed a first experiment at 300 MPa to synthesize a starting material composed of crystals of some hundreds of µm and melt pools. This material is representative of an initial magmatic assemblage composed of plagioclase, clinopyroxene and a water-undersaturated melt with 1.6 wt% H₂O. In a second step, the initial assemblage was equilibrated at 300 and 100 MPa with fluids having different XCO ₂ ^fl (CO₂/(H₂O + CO₂)). At low XCO ₂ ^fl (< 0.2 to 0.4), plagioclase is completely dissolved and clinopyroxene show dissolution textures. For relatively high XCO ₂ ^fl (0.9 at 300 MPa), the flushing of a CO₂-rich fluid phase leads to an increase of the amount of clinopyroxene and a decrease of the abundance of plagioclase at 300 MPa. This decrease of plagioclase proportion is associated with a change in An content. Our experiments demonstrate that flushing basaltic systems with fluids may drastically affect crystal textures and phase equilibria depending on proportions of H₂O and CO₂ in the fluid phase. Since texture and crystal proportions are among the most important parameters governing the rheology of magmas, fluid flushing will also influence magma ascent to the Earth’s surface. The experimental results open new perspectives to decipher the textural and compositional record of minerals observed in volcanic rocks from Mt. Etna, and at the same time offer the basis for interpreting the information preserved in minerals from other basaltic volcanoes erupting magmas enriched in CO₂.     

Formation of an ‘a’ā lava delta: insights from time-lapse multibeam bathymetry and direct observations during the Stromboli 2007 eruption

Five consecutive multibeam bathymetries collected before, during, and after the 2007 Stromboli eruption, combined with visual inspections, allowed us to document the morphological evolution of an ‘a’ā lava-fed delta and to reconstruct the main processes acting during its submarine emplacement. The 2007 Stromboli delta extended down to 600-m water depth and covered an area of 420?×?10³ m², with a maximum thickness of 65 m and a total estimated volume of ≈7?×?10⁶ m³, i.e., three times larger than its subaerial counterpart. The lava delta grew mainly through the emplacement of discrete lobes about 50–150 m in size. Lobes were fed from point sources along the paleoshoreline, and their subaqueous pathways seem to be mainly controlled by the submarine morphology, with flows mostly filling in depressions left by previous lobes. The main controlling factors on the lobe morphology and thickness are the effusion rates and the pre-eruption morphology, i.e., the geometry and gradients of the basal surface. Data also shows that sudden slope failure of portions of the submarine delta may occur simultaneously with accretion, implying that a significant part of the delta material can be transported to greater depths by submarine gravity flows. The present study is relevant for future monitoring and hazard assessment during the growth of active lava-fed deltas as well as for a better interpretation of ancient volcaniclastic successions inland.     

Structural trends and palaeogeography of the central and western Sicily belt: new insights

The geology of the Sicilian mainland is summarized by N–S geological sections. A continuous late Cenozoic orogenic belt through central and western Sicily resulted from a complex deformative history, recorded by several tectonic events. The deformation mainly involved the sedimentary cover of the old African continental margin, formed in a large basinal area, bordered at its southern margin by a shallow-water carbonate environment attached to Gondwana. The orogenic belt involves a complex architecture of thrust systems, of different size, geometry and palaeogeographical origin. Deformation, which mainly developed in the earlier stages of thrusting in the basinal rock assemblages, mainly gave rise to a stack of three different duplex structures, respectively, composed of Palaeozoic, Mesozoic–Palaeogene and Neogene strata. Large-scale clockwise rotation of the thrusts predated transpressional movements in the hinterland during the latest Miocene to Pliocene. High- angle reverse faults, with lateral components, modified earlier tectonic contacts within the allochthons. Contemporaneous southwards- directed imbrications affected the external southern areas, progressively incorporating foreland and piggyback basirts. The stratigraphic relationships of basin-fills to the tectonic structures reveals that reactivation processes have been active during the last Plio-Pleistocene.