Comparison between Eulerian diagnostics and finite-size Lyapunov exponents computed from altimetry in the Algerian basin

Transport and mixing properties of surface currents can be detected from altimetric data by both Eulerian and Lagrangian diagnostics. In contrast with Eulerian diagnostics, Lagrangian tools like the local Lyapunov exponents have the advantage of exploiting both spatial and temporal variability of the velocity field and are in principle able to unveil subgrid filaments generated by chaotic stirring. However, one may wonder whether this theoretical advantage is of practical interest in real-data, mesoscale and sub-mesoscale analysis, because of the uncertainties and resolution of altimetric products, and the non-passive nature of biogeochemical tracers. Here we compare the ability of standard Eulerian diagnostics and the finite-size Lyapunov exponent in detecting instantaneous and climatological transport and mixing properties in the south-western Mediterranean. By comparing with sea-surface temperature patterns, we find that the two approaches provide similar results for slowly evolving eddies like the first Alboran gyre. However, the Lyapunov exponent is also able to predict the (sub-)mesoscale filamentary processes occurring along the Algerian current and above the Balearic Abyssal Plain. Such filaments are also observed, with some mismatch, in sea-surface temperature patterns. Climatologies of Lyapunov exponents do not show any compact relation with other Eulerian diagnostics, unveiling a different structure even at the basin scale. We conclude that filamentation dynamics can be detected by reprocessing available altimetric data with Lagrangian tools, giving insight into (sub-)mesoscale stirring processes relevant to tracer observations and complementing traditional Eulerian diagnostics.     

Equilibrium isotopic fractionation in the kaolinite, quartz, water system: Prediction from first-principles density-functional theory

Isotopic fractionation factors for oxygen, hydrogen and silicon have been calculated using first-principles methods for the kaolinite, quartz, water (ice and gas water) system. Good agreement between theory and experiment is obtained for mineral-water oxygen isotope fractionation. This approach gives reliable results on isotopic fractionation factors as a function of temperature, within a relative precision of typically 5%. These calculations provide independent quantitative constraints on the internal fractionation of oxygen in kaolinite, the fractionation of silicon isotopes at equilibrium, or hydrogen fractionation between kaolinite and water. Calculated fractionation factors at 300 K are 12.5‰ for the kaolinite internal-fractionation of oxygen, and 1.6‰ for silicon fractionation between quartz and kaolinite.     

A physically-based method for removing pits in digital elevation models

Spurious pits in digital elevation models (DEMs) are traditionally removed by filling depressions, often creating flat regions that lead to inaccurate estimation of landscape flow directions. In this study, a physical approach based on a simple landscape evolution model is proposed for DEM pit removal. This method, an alternative to traditional geometrical procedures, enforces more realistic slopes and flow directions on topography. The procedure is compared with the method most commonly used in the literature and distributed with commercial GIS software where, generally, elevations of a depression are increased up to the lowest value among neighbouring cells. Several tests are performed and parameters sensitivity is carried out in order to demonstrate the performance of the proposed model as compared to traditional methods.     

Ground deformation modeling of flank dynamics prior to the 2002 eruption of Mt. Etna

On 22 September 2002, 1 month before the beginning of the flank eruption on the NE Rift, an M-3.7 earthquake struck the northeastern part of Mt. Etna, on the westernmost part of the Pernicana fault. In order to investigate the ground deformation pattern associated with this event, a multi-disciplinary approach is presented here. Just after the earthquake, specific GPS surveys were carried out on two small sub-networks, aimed at monitoring the eastern part of the Pernicana fault, and some baselines belonging to the northeastern EDM monitoring network of Mt. Etna were measured. The leveling route on the northeastern flank of the volcano was also surveyed. Furthermore, an investigation using SAR interferometry was performed and also the continuous tilt data recorded at a high precision sensor close to the epicenter were analyzed to constrain the coseismic deformation. The results of the geodetic surveys show a ground deformation pattern that affects the entire northeastern flank of the volcano, clearly shaped by the Pernicana fault, but too strong and wide to be related only to an M-3.7 earthquake. Leveling and DInSAR data highlight a local strong subsidence, up to 7 cm, close to the Pernicana fault. Significant displacements, up to 2 cm, were also detected on the upper part of the NE Rift and in the summit craters area, while the displacements decrease at lower altitude, suggesting that the dislocation did not continue further eastward. Three-dimensional GPS data inversions have been attempted in order to model the ground deformation source and its relationship with the volcano plumbing system. The model has also been constrained by vertical displacements measured by the leveling survey and by the deformation map obtained by SAR interferometry.     

Melt inclusions in detrital spinel from the SE Alps (Italy–Slovenia): a new approach to provenance studies of sedimentary basins

Detrital spinel is a widespread heavy mineral in sandstones from the Maastrichtian–Middle Eocene sedimentary basins in the SE Alps. Chemistry of detrital spinels from the Claut/Clauzetto and Julian Basins (N Italy and NW Slovenia) is used to constrain petrological and geochemical affinities and tectonic provenance of the source rocks. In addition, we have analysed melt inclusion compositions in the detrital volcanic spinels to better constrain the nature of their parental magmas. This is the first study of melt inclusions in detrital spinels. Two principal compositional groups of detrital spinels are recognised based on their TiO₂ and Fe²⁺/Fe³⁺; one derived from peridotites, the other from basaltic volcanics. Peridotitic spinels are more abundant and have TiO₂ < 0.2 wt% and high Cr/Cr + Al (40–90), characteristic of suprasubduction zone harzburgites. Significant chemical variations among volcanic spinels (TiO₂ up to 3 wt%, Al₂O₃ 12–44 wt%) suggest multiple sources, with geochemically distinct characteristics, including MORB-type and backarc basin basalts, subduction-related magmas and tholeiites produced during early continental rifting. Compositions of homogenised melt inclusions in spinels with TiO₂ > 0.2 better distinguish the differences between the compositions of their host spinels and help to further clarify the geodynamic provenance of extrusive source rocks. Several compositional groups of melt inclusions have been recognised and represent diverse magmatism of marginal basins, including MORB- and subduction-related geochemical types, as well as magmas characteristic of early continental rifting. These results, combined with the data on regional ophiolitic complexes and tectonic reconstructions favour the Internal Dinarides of Yugoslavia as a possible source area for the SE Alps sediments. Received: 20 January 2000 / Accepted: 25 April 2000     

Clinopyroxene of spinel-peridotite mantle xenoliths from Lake Nji (Cameroon Volcanic Line, W Africa): crystal chemistry and petrological implications

The crystal chemistry of six clinopyroxenes enclosed in protogranular spinel-peridotite mantle xenoliths from Lake Nji (Cameroon, W Africa) was studied by means of single-crystal X-ray diffraction and electron microprobe. These spinel-peridotite xenoliths are characterised by clinopyroxene contents distinctly higher than those reported by Lee et al. (1996) for spinel-peridotite xenoliths of the same region (19–11% and 15–8% respectively) and by high clinopyroxene/orthopyroxene ratios: 0.7–2.7 (present study) and about 0.4 (Lee et al. 1996). The clinopyroxene crystal chemistry indicates that the xenoliths show the compositional features of a mantle source contaminated by small-volume melts, responsible for the high clinopyroxene content. The protogranular texture of the Cameroon xenoliths (upper portion of lithospheric mantle) testifies that the spinel peridotite and the associated small-volume melts completely re-equilibrated at the spinel-peridotite facies. This is also supported by the petrological and geochemical data of Lee et al. (1996) on the Etinde–Biu Plateau spinel-peridotite xenoliths, which underwent Late Proterozoic–Early Paleozoic enrichment in incompatible trace elements. Received: 6 October 1999 / Accepted: 27 March 2000