Dissolution of calcitic marble and dolomitic rock in high iron concentrated acid mine drainage: application to anoxic limestone drains

Oxidation of sulphide mining waste can generate acid mine drainage (AMD) that has the potential to seriously affect the ecosystems. Acid mine drainage is characterised by a high acidity, high concentrations of sulphates and metals. To reduce the environmental impacts due to AMD, neutralisation using limestone drains is an option proposed in the literature and used around the world. The present study focuses on the influence of the carbonate rock mineralogy and their particle size on the neutralising capacity. The tests were performed in two different anoxic conditions: in batch reactors, and in columns having a hydraulic retention time of 15?h. The results showed that the neutralisation capacity of calcite was more important than for dolomitic rock, and smaller particle size gave higher alkalinity production (fine calcite dissolved faster in contact with AMD). A characterization of metal precipitate in sludge and in limestone coating was performed and demonstrated that gypsum, lepidocrocite and goethite were the predominant secondary minerals to be formed. Finally, this study underlines that anoxic limestone drain cannot be used alone to treat high iron concentrated AMD.     

IFKIS-Hydro: an early warning and information system for floods and debris flows

IFKIS-Hydro is an information and warning system for hydrological hazards in small- and medium-scale catchments. The system collects data such as weather forecasts, precipitation measurements, water level gauges, discharge simulations and local observations of event-specific phenomena. In addition, IFKIS-Hydro incorporates a web-based information platform, which serves as a central hub for the submission and overview of data. Special emphasis is given to local information. This is accomplished particularly by human observers. In medium-scale catchments, discharge forecast models have an increasing importance in providing valuable information. IFKIS-Hydro was developed in several test regions in Switzerland and the first results of its application are available now. The system is constantly extended to additional regions and may become the standard for warning systems in smaller catchments in Switzerland.     

Groundwater recharge in irrigated semi-arid areas: quantitative hydrological modelling and sensitivity analysis

For semi-arid regions, methods of assessing aquifer recharge usually consider the potential evapotranspiration. Actual evapotranspiration rates can be below potential rates for long periods of time, even in irrigated systems. Accurate estimations of aquifer recharge in semi-arid areas under irrigated agriculture are essential for sustainable water-resources management. A method to estimate aquifer recharge from irrigated farmland has been tested. The water-balance-modelling approach was based on VisualBALAN v. 2.0, a computer code that simulates water balance in the soil, vadose zone and aquifer. The study was carried out in the Campo de Cartagena (SE Spain) in the period 1999–2008 for three different groups of crops: annual row crops (lettuce and melon), perennial vegetables (artichoke) and fruit trees (citrus). Computed mean-annual-recharge values (from irrigation+precipitation) during the study period were 397 mm for annual row crops, 201 mm for perennial vegetables and 194 mm for fruit trees: 31.4, 20.7 and 20.5% of the total applied water, respectively. The effects of rainfall events on the final recharge were clearly observed, due to the continuously high water content in soil which facilitated the infiltration process. A sensitivity analysis to assess the reliability and uncertainty of recharge estimations was carried out.     

Insights on the events surrounding the final drainage of Lake Ojibway based on James Bay stratigraphic sequences

Deglaciation of the James Bay region was highly dynamic, with the occurrence of ice (Cochrane) readvances into glacial Lake Ojibway around final deglaciation time, which culminated with the drainage of Ojibway waters into Hudson Bay and subsequent incursion of the Tyrrell Sea at ～8 ka. Renewed interest on these events comes from the possible link between the drainage of the ice-dammed Lake Agassiz-Ojibway and a major climate deterioration known as the 8.2-ka cooling event. Recent glaciological modeling suggests that this drainage may have occurred subglacially, a mechanism that can accommodate more than one lake discharge, as suggested by marine records. The exact number and timing of drainage events, as well as location of the lake discharge pathway(s) remain, however, largely unconstrained. Here we focus on the events that led to the drainage of Lake Ojibway by documenting late-glacial sedimentary sequences located east of James Bay. Our investigations indicate that the deglacial sequence consists of a readvance till, extensive Ojibway rhythmites, and thick marine sediments. The glaciolacustrine and marine units are separated by a 60 cm-thick horizon composed of laminated silt beds containing rounded clay balls and disseminated clasts resulting from the abrupt drainage of the lake. Radiocarbon dating of marine fossils lying above the drainage horizon indicates that the glaciolacustrine episode ended around 8128–8282 cal yr BP. Micropaleontological analyses reveal that freshwater ostracods (Candona sp.) and marine microfossils (foraminifers, dinocysts) occur together in the upper part of the Ojibway sediments. Analysis of oxygen isotopes (δ¹⁸O) of ostracods and foraminifers originating from the same stratigraphic position show highly contrasting values that suggest possible subglacial exchanges between Lake Ojibway and Tyrrell Sea waters prior to the final drainage event. The complexity of the deglacial events is further indicated by radiocarbon dating of marine shells retrieved from a Cochrane till that suggests that the last ice readvance occurred almost simultaneously with the final lake discharge. These results bring additional constraints on the drainage mechanism of the coalesced Lake Agassiz-Ojibway and indicate that the James Bay region formed an important drainage pathway for meltwaters at the end of the last deglaciation.     

The Ereendavaa Range (north-eastern Mongolia): an additional argument for Mesozoic extension throughout eastern Asia

Mesozoic rift basins locally bounding metamorphic core complexes have been recognized in Transbaikalia and northern China. Numerous basement outcrops located between these two regions, in eastern Mongolia, are considered as pre-Palaeozoic in age. One of these, the Ereendavaa Range, appears as a gneissic core marked by amphibolite-facies metamorphic conditions. The range is overlain to the NW by the unmetamorphosed Mesozoic Onon Basin. Below the basin, the upper part of the range consists of a gently NW-dipping shear zone associated with top-to-the-NW motion. The structural pattern is consistent with syn-extensional exhumation of the range. Preliminary geochronological data indicate that the shear zone is late Jurassic to early Cretaceous in age, coeval with the Onon Basin. These new data from eastern Mongolia constitute a link between Transbaikalia and northern China, indicating that NW–SE extensional Mesozoic tectonics occurred throughout the entire region.     

Eruptive history of the Barombi Mbo Maar, Cameroon Volcanic Line, Central Africa: Constraints from volcanic facies analysis

his study presents the first and detail field investigations of exposed deposits at proximal sections of the Barombi Mbo Maar (BMM), NE Mt Cameroon, with the aim of documenting its past activity, providing insight on the stratigraphic distribution, depositional process, and evolution of the eruptive sequences during its formation. Field evidence reveals that the BMM deposit is about 126m thick, of which about 20m is buried lowermost under the lake level and covered by vegetation. Based on variation in pyroclastic facies within the deposit, it can be divided into three main stratigraphic units: U₁, U₂ and U₃. Interpretation of these features indicates that U₁ consists of alternating lapilli-ash-lapilli beds series, in which fallout derived individual lapilli-rich beds are demarcated by surges deposits made up of thin, fine-grained and consolidated ash-beds that are well-defined, well-sorted and laterally continuous in outcrop scale. U₂, a pyroclastic fall-derived unit, shows crudely lenticular stratified scoriaceous layers, in which many fluidal and spindle bombs-rich lapilli-beds are separated by very thin, coarse-vesiculatedash-beds, overlain by a mantle xenolith- and accidental lithic-rich explosive breccia, and massive lapilli tuff and lapillistone. U3 displays a series of surges and pyroclastic fall layers. Emplacement processes were largely controlled by fallout deposition and turbulent diluted pyroclastic density currents under “dry” and “wet” conditions. The eruptive activity evolved in a series of initial phreatic eruptions, which gradually became phreatomagmatic, followed by a phreato-Strombolian and a violent phreatomagmatic fragmentation. A relatively long-time break, demonstrated by a paleosol between U₂ and U₃, would have permitted the feeding of the root zone or the prominent crater by the water that sustained the next eruptive episode, dominated by subsequent phreatomagmatic eruptions. These preliminary results require complementary studies, such as geochemistry, for a better understanding of the changes in the eruptive styles, and to develop more constraints on the maar’s polygenetic origin.