Trace metals in mussels from the N.W. Mediterranean

A coastal survey in the northwestern Mediterranean region was initiated to measure existing levels of selected trace metals in mussels. For most metals the highest values were found in samples from port cities and areas in the vicinity of river discharge. Marked seasonal variation for many metals was evident; an overall increase in metal concentration in mussels from most stations during March 1974 was attributed to high precipitation and attendant run-off rather than to local pollution. Data comparison indicates that average metal levels in northwestern Mediterranean mussels do not differ markedly from those measured in similar species from different localities throughout the world.     

Simulated changes in daily rainfall intensity due to the enhanced greenhouse effect: implications for extreme rainfall events

In this study we present rainfall results from equilibrium 1 ×– and 2 × CO₂ experiments with the CSIRO 4-level general circulation model. The 1 × CO₂ results are discussed in relation to observed climate. Discussion of the 2 × CO₂ results focuses upon changes in convective and non-convective rainfall as simulated in the model, and the consequences these changes have for simulated daily rainfall intensity and the frequency of heavy rainfall events. In doing this analysis, we recognize the significant shortcomings of GCM simulations of precipitation processes. However, because of the potential significance of any changes in heavy rainfall events as a result of the enhanced greenhouse effect, we believe a first examination of relevant GCM rainfall results is warranted. Generally, the model results show a marked increase in rainfall originating from penetrative convection and, in the mid-latitudes, a decline in largescale (non-convective) rainfall. It is argued that these changes in rainfall type are a consequence of the increased moisture holding capacity of the warmer atmosphere simulated for 2 × CO₂ conditions. Related to changes in rainfall type, rainfall intensity (rain per rain day) increases in the model for most regions of the globe. Increases extend even to regions where total rainfall decreases. Indeed, the greater intensity of daily rainfall is a much clearer response of the model to increased greenhouse gases than the changes in total rainfall. We also find a decrease in the number of rainy days in the middle latitudes of both the Northern and Southern Hemispheres. To further elucidate these results daily rainfall frequency distributions are examined globally and for four selected regions of interest. In all regions the frequency of high rainfall events increases, and the return period of such events decreases markedly. If realistic, the findings have potentially serious practical implications in terms of an increased frequency and severity of floods in most regions. However, we discuss various important sources of uncertainty in the results presented, and indicate the need for rainfall intensity results to be examined in enhanced greenhouse experiments with other GCMs.     

Bioavailability of technetium from artificially labelled north-east atlantic deep-sea sediments

Laboratory experiments were designed to measure the uptake of Tc by clams from North-East Atlantic sediments which were contaminated with different oxidation states of ^95mTc. Distribution coefficients between solid sediment and pore water were similar for Tc IV and VII and never exceeded 3·5 during the 36-day experiment. Furthermore, ^95mTc was rapidly leached from the sediments with a half-time of about 4·5 days. Biological uptake was low, with transfer factors between clam tissues and sediment ranging between 0·04 and 0·6. Greater relative uptake was noted in the soft tissues than in shell, although the latter contained the largest fraction (70%) of the clam's whole body ^95mTc content. Contaminated clams, transferred to uncontaminated sediments, displayed a very long biological half-life (～120 days) for ^95mTc. This observation suggests that following acute contamination, clams living in an environment of this type would still retain Tc in their tissues long after the radionuclide had been leached from the sediments.     

Comparison of derivative-free optimization methods for groundwater supply and hydraulic capture community problems

Management decisions involving groundwater supply and remediation often rely on optimization techniques to determine an effective strategy. We introduce several derivative-free sampling methods for solving constrained optimization problems that have not yet been considered in this field, and we include a genetic algorithm for completeness. Two well-documented community problems are used for illustration purposes: a groundwater supply problem and a hydraulic capture problem. The community problems were found to be challenging applications due to the objective functions being nonsmooth, nonlinear, and having many local minima. Because the results were found to be sensitive to initial iterates for some methods, guidance is provided in selecting initial iterates for these problems that improve the likelihood of achieving significant reductions in the objective function to be minimized. In addition, we suggest some potentially fruitful areas for future research.     

Convection of a fluid with strongly temperature and pressure dependent viscosity

Plate tectonics on the Earth is a surface manifestation of convection within the Earth’s mantle, a subject which is as yet improperly understood, and it has motivated the study of various forms of buoyancy-driven thermal convection. The early success of the high Rayleigh number constant viscosity theory was later tempered by the absence of plate motion when the viscosity is more realistically strongly temperature dependent, and the process of subduction represents a continuing principal conundrum in the application of convection theory to the Earth. A similar problem appears to arise if the equally strong pressure dependence of viscosity is considered, since the classical isothermal core convection theory would then imply a strongly variable viscosity in the convective core, which is inconsistent with results from post-glacial rebound studies. In this paper we address the problem of determining the asymptotic structure of high Rayleigh number convection when the viscosity is strongly temperature and pressure dependent, i.e. thermobaroviscous. By a method akin to lid-stripping, we are able to extend numerical computations to extremely high viscosity contrasts, and we show that the convective cells take the form of narrow, vertically-oriented fingers. We are then able to determine the asymptotic structure of the solution, and it agrees well with the numerical results. Beneath a stagnant lid, there is a vigorous convection in the upper part of the cell, and a more sluggish, higher viscosity flow in the lower part of the cell. We then offer some comments on the possible meaning and interpretation of these results for planetary mantle convection.     

Using satellite altimetry data to augment flow estimation techniques on the Mekong River

Satellite altimetry is routinely used to provide levels for oceans or large inland water bodies from space. By utilizing retracking schemes specially designed for inland waters, meaningful river stages can also be recovered when standard techniques fail. Utilizing retracked waveforms from ERS‐2 and ENVISAT along the Mekong, comparisons against observed stage measurements show that the altimetric measurements have a root mean square error (RMSE) of 0·44–0·65 m for ENVISAT and 0·46–0·76 m for ERS‐2. For many applications, however, stage is insufficient because discharge is the primary requirement. Investigations were therefore undertaken to estimate discharges at a downstream site (Nakhon Phanom (NP)) assuming that in situ data are available at a site 400 km upstream (Vientiane). Two hypothetical, but realistic scenarios were considered. Firstly, that NP was the site of a de‐commissioned gauge and secondly, that the site has never been gauged. Using both scenarios, predictions were made for the daily discharge using methods with and without altimetric stage data. In the first scenario using a linear regression approach the altimetry data improved the Nash‐Sutcliffe r² value from 0·884 to 0·935. The second scenario used known river cross‐sections while lateral inflows were inferred from a hydrological model: this scenario gave an increase in the r² value from 0·823 to 0·893. The use of altimetric stage data is shown to improve estimated discharges and further applications are discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

Aliphatic and aromatic hydrocarbons in marine biota and coastal sediments from the Gulf and the Gulf of Oman

The composition and spatial distribution of aliphatic and polycyclic aromatic hydrocarbons (PAHs) were investigated in biota and coastal sediments from four countries surrounding the Gulf (Bahrain, Qatar, United Arab Emirates and Oman). The levels of total petroleum hydrocarbons (TPH), aliphatic unresolved mixture and PAHs in sediments and biota were relatively low compared to world-wide locations reported to be chronically contaminated by oil. Only in the case of the sediments collected near the BAPCO oil refinery in Bahrain, having concentrations of 779 μg g⁻¹ total petroleum hydrocarbon equivalents and 6.6 μg g⁻¹ ∑PAHs, can they be categorized as chronically contaminated. Some evidence of oil contamination was also apparent in sediments and bivalves around Akkah Head and Abu Dhabi in the UAE, and near Mirbat in Oman. Contaminant patterns in sediments and biota indicated that the PAHs were mainly from fossil sources, with the exception of the high PAH concentrations in sediments near the BAPCO refinery that contained substantial concentrations of carcinogenic PAH combustion products.