Selection of hazardous waste dumpsites based on parameters effecting soil adsorption capacity – a case study

A careful selection of waste dumpsites, particularly hazardous ones, is very important for sustainable water resources management. Several laboratory experiments were carried out on the field samples to study adsorption capacity using p-dichlorobenzene (a solvent used in various industrial processes) as the test contaminant. The effect of parameters such as organic matter, clay, and iron and aluminium oxides, which are known to influence the soil adsorption capacity, are studied in the present work. Several soil samples from the Patancheru Industrial Area (Hyderabad, India) were collected and characterized. Only three soils, which had a comparatively high percentage of organic matter, clay, iron and aluminium oxide contents were used for the adsorption studies. The results clearly indicated a decrease in the adsorption capacity of the soils by as much as 75% when organic matter was removed. The other parameters such as clay and iron and aluminium oxides also play an important role in adsorption (57 and 39.8% reduction respectively). It was observed that out of the selected factors organic matter in the soils has the maximum effect regarding the adsorption of p-dichlorobenzene. Since the selected soils contain comparatively more organic matter, clay and iron and aluminium oxides in the selected industrial area, these can be used as sites for dumping hazardous waste, which can be further treated by methods like bioremediation.     

Nd and Sr isotopic constraints on the origin of igneous rocks resulting from the opening of the Japan Sea, southwestern Japan

Strontium and Nd isotopic compositions and trace element abundances were determined for Cretaceous to late Cenozoic igneous rocks from the Japan Sea side of Southwest Japan in order to investigate the effect of the opening of the Japan Sea on igneous activity. The ⁸⁷Sr/⁸⁶Sr ratios for both high and low silica rocks decrease with decreasing age since the middle Miocene, when the opening occurred. Similarly, ¹⁴³Nd/¹⁴⁴Nd values for these rocks increase with decreasing age, and are negatively correlated with ⁸⁷Sr/⁸⁶Sr ratios. A two-component mixing process can best account for these isotopic and chemical characteristics. One end-member is likely the subcontinental lithospheric mantle (SCLM) and its derivative mafic to intermediate materials which had ɛ_Nd values of around +3. The other endmember consists of mafic to intermediate rocks with low ɛ_Nd values (e.g., −8), probably located in the lower crust. The mantle upwelling associated with the opening of the Japan Sea did not supply typical MORB or MORB-source materials to the crust, but did provide the heat that caused the melting of lithospheric mantle and lower crust. Received: 29 August 1996 / Accepted: 6 May 1997     

Observations of Low-Latitude Coronal Plumes

Using Fe ix/x 17.1 nm observations from the Extreme-Ultraviolet Imaging Telescope (EIT) on the Solar and Heliospheric Observatory (SOHO), we have identified many coronal plumes inside low-latitude coronal holes as they transited the solar limb during the late declining phase of cycle 23. These diffuse, linear features appear to be completely analogous to the familiar polar plumes. By tracking them as they rotate from the limb onto the disk (or vice versa), we confirm that EUV plumes seen against the disk appear as faint, diffuse blobs of emission surrounding a brighter core. When the EIT images are compared with near-simultaneous magnetograms from the SOHO Michelson Doppler Imager (MDI), the low-latitude, on-disk plumes are found to overlie regions of mixed polarity, where small bipoles are in contact with unipolar flux concentrations inside the coronal hole. The birth and decay of the plumes are shown to be closely related to the emergence of ephemeral regions, their dispersal in the supergranular flow field, and the cancellation of the minority-polarity flux against the dominant-polarity network elements. In addition to the faint polar and nonpolar plumes associated with ephemeral regions, we note the existence of two topologically similar coronal structures: the giant plume-like features that occur above active regions inside coronal holes, and the even larger scale “pseudostreamers” that separate coronal holes of the same polarity. In all three cases, the basic structure consists of open field lines of a given polarity overlying a photospheric region of the opposite polarity; ongoing interchange reconnection at the X-point separating the open field domains from the underlying double-arcade system appears to result in the steady evaporation of material from the closed into the open region.     

Seasonal variation of Mn adsorption on to calcareous surfaces in the English Channel, and its implication on the manganese distribution coefficient

Dissolved and particulate manganese in seawater samples derived from the English Channel has been analyzed using graphite furnace atomic absorption (GFAAS), and inductively coupled plasma atomic emission (ICP—AES) spectroscopies. Because of the high contents of carbonate minerals found in the suspended matter samples, the English Channel constitutes an ideal field area for the study of the Mn²⁺/Ca²⁺/CaCO₃ system. Owing to the chemical speciation of particulate manganese and the combined use of the X-ray diffraction and electron spin resonance spectroscopy we have shown the importance of the carbonate phase in the stabilization of manganese (II). This has been confirmed by p-pH measurements in the field. All these studies have also indicated that: (1) manganese is associated with calcite in the form of a solid solution, Mn_xCa_1−xCO₃; and (2) significant increases in the concentrations of particulate manganese, especially in offshore waters, occur in summer. This seasonal phenomenon has been attributed to the proliferation of coccolithophorids, which are known to be covered with calcified skeletons at high specific surface areas. To appraise the implication of the coccolithophorid-blooms phenomenon on the Mn²⁺/Ca²⁺/CaCO₃ system, we have used the manganese distribution coefficient, D_i, between the liquid phase and CaCO₃ particles. Overall we have shown that: (1) D_i in summer (i.e. when coccoliths considered as very fine-grained calcite are abundant) is much higher than that obtained in winter; and (2) in the vicinity of the French coast, D_i does not vary significantly even in summer. This is because of the high content of chalk-derived particles found in the near-shore waters.     

Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

Numerical reconstruction of trajectory of small-size surface drifter in the Mediterranean sea

In this study, we addressed the effects of wind-induced drift on Lagrangian trajectories of surface sea objects using high-resolution ocean forecast and atmospheric data. Application of stochastic Leeway model for prediction of trajectories drift was considered for the numerical reconstruction of the Elba accident that occurred during the period 21.06.2009–22.06.2009: a person on an inflatable raft was lost in the vicinity of the Elba Island coast; from the initial position, the person on a raft drifted southwards in the open sea and later he was found on a partially deflated raft during rescue operation. For geophysical forcing, we used high-resolution currents from the Mediterranean Forecasting System and atmospheric wind from the European Centre for Medium-Range Weather Forecasts. To investigate the effect of wind on trajectory behavior, numerical simulations were performed using different categories of drifter-like particles similar to a person on an inflatable raft. An algorithm of spatial clustering was used to differentiate the most probable search areas with a high density of particles. Our results showed that the simulation scenarios using particles with characteristics of draft-limited sea drifters provided better prediction of an observed trajectory in terms of the probability density of particles.     

A note on the deflection of a baroclinic current by a continental shelf

The deflection, at a step-shelf fronted coast, of a constant potential vorticity current in a reduced-gravity, inviscid model ocean is studied theoretically. The step shelf, with a depth smaller than the reservoir depth, forces the uplifting of the approaching current and causes water column foreshortening, leading to relative vorticity generation that enhances current deflection to the right (facing the coast). As a consequence, in comparison to the case of a vertical wall coast, the proportion of the transport to the right is increased. For normal incidence for a shelf-depth/reservoir-depth ratio of 0.3 and shelf width to deformation radius ratio of 1.5, more than 90% of the approaching current transport goes to the right and less than 10% to the left. In addition, the (barotropic) dynamic pressure at the coast is low to the right and high to the left (with the highest pressure at the stagnation point). In the vertical wall case, the wall pressures on the flank are equal. For oblique incidence from the left, the deflection to the left is drastically reduced. In fact, there is practically no steady-state flow diverted to the left (less than 2%) when the approach angle is greater than 60° to the left of normal. In the vertical wall case, the same angle would have to be 90° for the flow to the left to vanish, namely only when the approach current is parallel to the coast to the right.