The Late Cenozoic Eridanos delta system in the Southern North Sea Basin: a climate signal in sediment supply?

ABSTRACT The Eridanos fluvio‐deltaic system, draining most of north‐western Europe, developed during the Late Cenozoic as a result of simultaneous uplift of the Fennoscandian shield and accelerated subsidence in the North Sea Basin. This seismo‐stratigraphic study aims to reconstruct the large‐scale depositional architecture of the deltaic portion of the basin fill and relate it to external controls. A total of 27 units have been recognized. They comprise over 62×10³ km³ in the Southern North Sea Basin alone, and have an average delta surface area of 28×10³ km², which suggests that the size of the drainage area was about 1.1×10⁶ km². Water depth in the depocentre is seen to decrease systematically over time. This trend is interrupted by a deepening phase between 6.5 and 4.5 Ma that can be correlated with the simultaneous occurrence of increased uplift of the Fennoscandian shield, increased subsidence of the Southern North Sea Basin, and a long‐term eustatic highstand. All these observations point to a tectonic control on long‐term average rates of accommodation and supply. Controls on short‐term variations are inferred from variations in rates of sediment supply and bifurcation of the delta channel network. Both rates were initially low under warm, moist, relatively stable climate conditions. The straight wave‐dominated delta front gradually developed into a lobate fluvial‐dominated delta front. Two high‐amplitude sea‐level falls affected the Pliocene units, which are characterized by widespread delta‐front failures. Changes in relative sea level and climate became more frequent from the late Pliocene onward, as the system experienced the effects of glacial–interglacial transitions. Peaks in sedimentation and bifurcation rates were coeval with cold (glacial) conditions. The positive correlation between rates of supply and bifurcation on the one hand, and climate proxies (pollen and δ¹⁸O records) on the other hand is highly significant. The evidence presented in this study convincingly demonstrates the control of climate on time‐averaged sediment supply and channel‐network characteristics, despite the expected nonuniformity and time lags in system response. The presence of a clearly discernible climate signal in time‐averaged sediment supply illustrates the usefulness of integrated seismo‐stratigraphic studies for basin‐wide analysis of delta evolution on geological time scales.     

Fracture induced emission of alkali atoms from feldspar

Emission of neutral atoms (K and Na) and molecules (H₂O and KOH) observed during fracture of K-feldspar have been accounted for by two independent mechanisms. H₂O and KOH emissions are attributed to the venting of fluid-filled inclusions, while emission of atomic K is due to surface effects accompanying cleavage of crystalline feldspar. The intensity of emitted potassium, at least 6 × 10¹⁴ atoms/cm² of surface area, is sufficient to affect K activities in solution during microbrecciation in the presence of rock-dominated fluids.     

Mössbauer studies of iron silicate spinel at high pressure

We have measured in situ Mössbauer transmission spectra of iron silicate spinel (γ-Fe₂SiO₄) in a diamond anvil cell at room temperature and pressures up to 16 GPa. The observed spectra show a doublet characteristic of the paramagnetic state. The isomer shift and quadrupole splitting at atmospheric pressure are 1.10 and 2.63 mm/s, respectively, which are smaller than those of fayalite (α-Fe₂SiO₄). Both the isomer shift and quadrupole splitting decrease linearly with pressure with slope of ?0.003(1) and ?0.020(1) mm/sec · GPa, respectively. This simple linear trend suggests that no electronic or polymorphic transitions occur under 16 GPa except for those due to the small and continuous changes of volume and local symmetry under pressure. On the basis of a crystalline field calculation, the negative pressure derivative of the quadrupole splitting is associated with a trend towards an ideal cubic symmetry of the oxygen sublattice.     

Sampling for Purgeable Organic Compounds Using Positive-Displacement Piston and Centrifugal Submersible Pumps: A Comparative Study

Positive-displacement piston pumps that minimize sample agitation have no apparent advantage over centrifugal submersible pumps when used to collect ground water samples for analysis of low concentrations of purge-able organic compounds. Analytical uncertainties inherent in laboratory environments appear to influence analytical results of low-concentration purgeable organic compound samples more than either pump type or sampling team. Centrifugal submersible pumps are at least equally efficient as positive-displacement piston pumps in the recovery of carbon tetrachloride, 1,1,1-trichloroethane, trichloroethylene, and chloroform after sampling and analytical influences are made constant.