Clustering of groundwater chemistry data with implications for reservoir appraisal in West Siberia

Division of sedimentary strata according to groundwater chemistry is discussed with implications for petroleum reservoir potential. It is suggested to process multiparametric water chemistry data from West Siberia using formalized clustering techniques. The efficiency of this approach has been tested for Neocomian clinoform reservoirs with reference to regional-scale appraisal and subregional petroleum division.     

Application of thermomagnetic analysis to picroilmenite investigation

Picroilmenite samples from five kimberlite pipes of the Yakutian kimberlite province have been studied. Point microprobe analyses of two mutually perpendicular profiles of each sample were carried out to study the compositional inhomogeneity of picroilmenite. Thermomagnetic curves were also recorded for each sample. A model for the processing of thermomagnetic curves is proposed on the basis of the relationship between the Curie point of picroilmenite and the content of the hematite end-member. The compositions determined by the thermomagnetic curves and microprobe analysis are rather similar. The conclusion has been drawn that thermomagnetic analysis can be used for the rapid determination of the picroilmenite composition. The possibilities and restrictions of this method are shown.     

Numerical modelling of soil nails in loose fill slope under surcharge loading

A plane–strain numerical model has been developed to mimic a nailed loose fill slope under surcharge loading. The model has been used to back-analyse a field test that was conducted to examine the behaviour of soil nails in loose fill slopes under surcharge loading. Incremental elasto-plastic analyses coupled with pore water diffusion have been performed to study the internal deformation, water content redistribution in the soil, and the performance of the soil nails during and after the application of surcharge loading. The model parameters describing the mechanical and hydraulic properties of the nailed slope were obtained from field or laboratory tests. Different modelling techniques and boundary conditions for mimicking soil–nail interaction in loose fill material have been examined. Comparisons between numerical predictions and field measurements demonstrate that a new interfacial model, denoted as the embedded bond–slip interface model, is more suitable for mimicking the interfacial behaviour. Despite the simplicity of the numerical model, the predicted responses are in close agreement with the field test results, in particular the mobilisation and distribution of nail forces in response to surcharge loading. Both the numerical and the field test results suggest that soil nails are capable of increasing the overall stability of a loose fill slope for the loading conditions considered in this study. The increase in confining stress along the soil nails near the surcharge area is central to the overall stabilising mechanism. On the contrary, the nail forces mobilised near the nail heads are much smaller, indicating that the beneficial effect of having a structural grillage system at the slope face is limited for the range of surcharge pressures considered in this study.     

Electron microbeam analysis of urban road-deposited sediment,Manchester, UK: Improved source discrimination and metal speciation assessment

Road-deposited sediment (RDS) is an accumulation of particulates upon street surfaces in urban centres. It is commonly highly contaminated and has major potential impacts upon surface water quality and human health, as well as becoming a waste material upon street sweeping. Although significant research has been undertaken upon the fine fraction within these systems, there is a lack of detailed, high-resolution grain-specific mineralogical and chemical data for the coarser fractions, which contain the bulk of the contamination by mass. The study reported here utilizes backscatter electron microscopic, electron microprobe and Raman spectroscopic analysis to provide novel data on RDS material from Manchester, UK, with significant implications for the improved understanding of source discrimination and contaminant metal speciation. The RDS samples studied are highly heterogeneous and the abundant nature of anthropogenic grains is particularly apparent. The RDS material has been found to be composed of a number of grain types: (i) silicate and alumino-silicate grains derived from a wide range of sources; (ii) iron oxide grains derived from the corrosion of galvanized steel; (iii) iron-rich glass grains derived as slag material from metal and waste processing activities and (iv) spherical Fe oxide and Fe-rich glass grains derived from high temperature combustion processes. Elemental metallic grains (Fe, Cu, Pb) are also present in minor amounts.     

Iron(III) accumulations in inland saline waterways,Hunter Valley,Australia: Mineralogy,micromorphology and pore-water geochemistry

Discharge of Fe(II)-rich groundwaters into surface-waters results in the accumulation of Fe(III)-minerals in salinized sand-bed waterways of the Hunter Valley, Australia. The objective of this study was to characterise the mineralogy, micromorphology and pore-water geochemistry of these Fe(III) accumulations. Pore-waters had a circumneutral pH (6.2–7.2), were sub-oxic to oxic (Eh 59–453 mV), and had dissolved Fe(II) concentrations up to 81.6 mg L⁻¹. X-ray diffraction (XRD) on natural and acid-ammonium-oxalate (AAO) extracted samples indicated a dominance of 2-line ferrihydrite in most samples, with lesser amounts of goethite, lepidocrocite, quartz, and alumino-silicate clays. The majority of Fe in the samples was bound in the AAO extractable fraction (Fe^Ox) relative to the Na-dithionite extractable fraction (Fe^Di), with generally high Fe^Ox:Fe^Di ratios (0.52–0.92). The presence of nano-crystalline 2-line ferrihydrite (Fe₅HO₃·4H₂O) with lesser amounts of goethite (α-FeOOH) was confirmed by scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED). In addition, it was found that lepidocrocite (γ-FeOOH), which occurred as nanoparticles as little as ∼5 lattice spacings thick perpendicular to the (0 2 0) lattice plane, was also present in the studied Fe(III) deposits. Overall, the results highlight the complex variability in the crystallinity and particle-size of Fe(III)-minerals which form via oxidation of Fe(II)-rich groundwaters in sand-bed streams. This variability may be attributed to: (1) divergent precipitation conditions influencing the Fe(II) oxidation rate and the associated supply and hydrolysis of the Fe(III) ion, (2) the effect of interfering compounds, and (3) the influence of bacteria, especially Leptothrix ochracea.     

Neoproterozoic to Early Cambrian history of an active plate margin in the Teplá–Barrandian unit—a correlation of U–Pb isotopic-dilution-TIMS ages (Bohemia, Czech Republic)

The Teplá–Barrandian unit (TBU) of the Bohemian Massif shared a common geological history throughout the Neoproterozoic and Cambrian with the Avalonian–Cadomian terranes. The Neoproterozoic evolution of an active plate margin in the Teplá–Barrandian is similar to Avalonian rocks in Newfoundland, whereas the Cambrian transtension and related calc-alkaline plutons are reminiscent of the Cadomian Ossa–Morena Zone and the Armorican Massif in western Europe. The Neoproterozoic evolution of the Teplá–Barrandian unit fits well with that of the Lausitz area (Saxothuringian unit), but is significantly distinct from the history of the Moravo–Silesian unit.The oldest volcanic activity in the Bohemian Massif is dated at 609+17/−19 Ma (U–Pb upper intercept). Subduction-related volcanic rocks have been dated from 585±7 to 568±3 Ma (lower intercept, rhyolite boulders), which pre-dates the age of sedimentation of the Cadomian flysch ( t chovice Group). Accretion, uplift and erosion of the volcanic arc is documented by the Neoproterozoic Dob í conglomerate of the upper part of the flysch. The intrusion age of 541+7/−8 Ma from the Zgorzelec granodiorite is interpreted as a minimum age of the Neoproterozoic sequence. The Neoproterozoic crust was tilted and subsequently early Cambrian intrusions dated at 522±2 Ma (T ovice granite), 524±3 Ma (V epadly granodiorite), 523±3 Ma (Smr ovice tonalite), 523±1 Ma (Smr ovice gabbro) and 524±0.8 Ma (Orlovice gabbro) were emplaced into transtensive shear zones.     

Cenozoic tectonic events at the border of the Paraná Basin, São Paulo, Brazil

In the last decade, even in areas that had been considered tectonically stable, a great amount of Cenozoic, including the Quaternary period, structural data have been collected throughout Brazil. The main goal of this study is to describe the Cenozoic structures and tectonic evolution of an area that is located at the border of the Paraná Basin in the state of São Paulo.The research methods consisted of the analysis of: (1) brittle structure data, mainly conjugate fractures and fault slip data; (2) lineaments traced on air photos and TM Landsat and radar images; and (3) a second-order base surface map.The study area, during the Cenozoic, has been affected by five strike–slip tectonic events, which generated mainly strike–slip faults, and secondarily normal and reverse ones. The events were named, from the oldest to the youngest, E1-NE, E2-EW, E3-NW, E4-NS, and E5-NNE; and the maximum principal stresses σ1 strike approximately NE–SW, E–W, NW–SE, N–S, and NNE–SSW, respectively. Event E2-EW seems to have been contemporaneous with the deposition of the Rio Claro Formation, the most important Cenozoic deposit of probable Neogenic age, and also to have controlled the distribution of its deposits. Event E3-NW was the strongest one in the area, as is pointed out by structural data, and the maximum principal stress σ1 of event E5-NNE is partially concordant with the orientation of σH-max of well break-out data in the Paraná Basin, suggesting a Neotectonic activity for this event. Finally, discontinuities parallel and correlated to the directions of strike–slip faults of the Cenozoic events seem to have actively controlled the sculpturing of the relief in the study area.     

A Model for the polar motion of the deformable Earth adequate for astrometric data

Refined analytical expressions for the frequencies corresponding to the Chandler motion of the pole and the diurnal rotation of the deformable Earth are derived. Numerical estimates of the period and amplitude of the polar oscillations are presented. The trajectory of the Chandler polar motion derived via numerical modeling is in qualitative and quantitative agreement with experimental data from the International Earth Rotation Service (IERS). An evolutionary model describing slow variations in the Earth’s rotation parameters under the action of the dissipative moments of the tidal gravitational forces on time scales considerably longer than the precession period of the Earth’s axis is constructed. The axis of the Earth’s figure tends to approach the angular momentum vector of the proper rotation.     

Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.