Physical and anthropogenic effects on observed long-term nutrient changes in the Irish Sea

The trend in Irish Sea nutrient concentrations over the last four decades has been considered to reflect changes in anthropogenic loading. Comparison of a long-term database for the Menai Strait, North Wales, with an established historic data set for the Cypris station, Isle of Man, indicates that climate also has a significant influence on observations of nutrient concentrations. Data are presented detailing long-term shifts in nitrate, phosphate and silicate measurements since the 1960s at these two fixed sampling sites in the Irish Sea. Broad systematic changes observed in all three nutrients over the decades show a rise from the 1960s through to the 1980s, followed generally by an overall decline in the 1990s. Decadal-scale salinity changes occur in the opposite sense to nutrient changes. Anthropogenic inputs from freshwater cannot fully account for observed nutrient trends, neither is there evidence for shifts in nutrient concentrations in oceanic waters over the past four decades. Climatically forced movement in the geographical position of the freshwater/seawater mixing zone over a decadal time scale could, however, give rise to the observed shifts in nutrient concentration and salinity. This cannot alter nutrient concentration and salinity per se, but causes the measurements taken at fixed sampling sites to fluctuate inversely over this time scale. It is concluded that there is complex interplay between anthropogenic loading and climate affecting the distribution of nutrients in the Irish Sea.     

Authigenic carbonates from the eastern Black Sea as an archive for shallow gas hydrate dynamics – Results from the combination of CT imaging with mineralogical and stable isotope analyses

Authigenic carbonates associated with cold seeps provide valuable archives of changes in the long-term seepage activity. To investigate the role of shallow-buried hydrates on the seepage strength and fluid composition we analysed methane-derived carbonate precipitates from a high-flux hydrocarbon seepage area (“Batumi seep area”) located on the south-eastern Black Sea slope in ca. 850 m. In a novel approach, we combined computerized X-ray tomography (CT) with mineralogical and isotope geochemical methods to get additional insights into the three-dimensional internal structure of the carbonate build-ups.     

Crustal structure of the Alpine–Pannonian transition zone: a combined seismic and gravity study

 The crustal structure of the transition zone between the Eastern Alps and the western part of the Pannonian depression (Danube basin) is traditionally interpreted in terms of subvertical Tertiary strike-slip and normal faults separating different Alpine tectonic units. Reevaluation of approximately 4000-km-long hydrocarbon exploration reflection seismic sections and a few deep seismic profiles, together with data from approximately 300 wells, suggests a different structural model. It implies that extensional collapse of the Alpine orogene in the Middle Miocene was controlled by listric normal faults, which usually crosscut Alpine nappes at shallow levels, but at depth merge with overthrust planes separating the different Alpine units. The alternative structural model was tested along a transect across the Danube basin by gravity model calculations, and the results show that the model of low-angle extensional faulting is indeed viable. Regarding the whole lithosphere of the western Pannonian basin, gravity modelling indicates a remarkable asymmetry in the thickness minima of the attenuated crust and upper mantle. The approximately 160 km lateral offset between the two minima suggests that during the Miocene extension of the Pannonian basin detachment of the upper crust from the mantle lithosphere took place along a rheologically weak lower crust. Received: 13 July 1998 / Accepted: 18 March 1999     

Content and distribution of trace metals in surface sediments from the northern Bering Sea, Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06-168.21 mg kg(-1) for Zn, 8.91-46.94 mg kg(-1) for Cr, 2.69-49.39 mg kg(-1) for Cu, 32.46-185.54 mg kg(-1) for V, 0.09-0.92 mg kg(-1) for Cd, and 0.95-15.25 mg kg(-1) for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Preliminary observations of solar radio sources with the Culgoora radioheliograph operating at four frequencies

The Culgoora radioheliograph has been modified for observing at 327.4 MHz, which is in addition to the three frequencies (43.25, 80, and 160 MHz) previously available. At the new frequency the array beamwidth is 56, which represents the highest resolution yet available for metre-wavelength solar mapping.At 327.4 MHz the sources of radio emission are mainly in the lowest layers of the corona. Some preliminary four-frequency observations have been made of type I storms. It is found that the source size generally decreases with increasing observing frequency. This result confirms earlier suggestions that the sources of both type I and type III emission are contained in structures whose boundaries diverge outwards in the corona.     

Mass physical properties, sliding and erodibility of experimentally deposited and differently consolidated clayey muds (Approach, equipment, and first results)

On experimentally deposited kaolinite, illite, and Ca-bentonite consolidated under their own load or by additional vertical pressure, the progress of compaction in relation to excess pore water pressure, mass physical properties, gravitational mass movements in a tilted tank, and erodibility under running water in a flume were studied. The very low consolidated sediments near the mud/water interface do not obey the generally used theory in soil mechanics. They show a different, non-linear relationship between void ratio or water content and depth below the sedimentary surface on the one hand, or effective overburden pressure and shear strength on the other. The same is true of other physical properties such as permeability, which changes considerably with depth and time of consolidation. High sedimentation rates on slopes induce shallow sediment flow, whereas at low rates and critical slope angles different types of slope failures including the breaking up of water-rich sediment into sharp boundered blocks are observed. Flume studies on soft clay muds show three different types of erosion: continuously suspending, discontinuous erosion of crumbs or shreds, and wavy deformation of the clay surface with disintegration of particles from the crests. The critical tractive stress depends not only on clay type, void ratio, and shear strength, but significantly also on the ‘geologic history’of the clay (i.e. deposition from thin suspension or dense slurry, fabric, consolidation and swelling generating minute inhomogeneities etc.). The experiments may lead to a better understanding of all mechanical processe's including pore-water flow taking place near or not far below the sediment/ water interface.     

The impact of hydrological changes on travertine deposits related to thermal springs in the Pamukkale area (SW Turkey)

Pamukkale thermal waters (35 °C), exhibiting calcium-bicarbonate-sulfate composition and high carbon dioxide concentration, are of a predominantly meteoric origin. The meteoric fluid, circulating through faults and fractures, is heated by magmatic intrusions at great depth, and ascends from deep reservoirs to the surface. Mixing with relatively cold groundwater in the near surface zone promotes different saturation conditions with respect to calcium carbonate that later precipitates at depth and/or the surface. Dissolution-deposition processes of calcium carbonate both at surface and depth environments may help to reconstruct past climate direction in the field. During wet climate conditions a high-rate of calcium carbonate accumulation would be expected to occur at the surface because thermal fluid would be under-saturated with respect to calcium carbonate at depth because of a relatively higher mixing ratio with cold groundwater. During dry climate conditions the thermal fluid would be super-saturated at depth because of the highly acidic environment. Hydrometeorological studies reveal that the annual precipitation at the Pamukkale hydrothermal field tends to decrease with time. This climatic change in the area was also detected from geological records. While humid climate conditions prevailed during the late Quaternary, the area has recently been affected by arid/semi-arid climate conditions, followed by some episodic transitions. This study has shown how the system has possibly reacted to different climate conditions since antiquity.     

Decimetric type III radio bursts and associated hard X-ray spikes

A detailed comparison is made between hard X-ray spikes and decimetric type III radio bursts for a relatively weak solar flare on 1981 August 6 at 10: 32 UT. The hard X-ray observations were made at energies above 30 keV with the Hard X-Ray Burst Spectrometer on the Solar Maximum Mission and with a balloon-born coarse-imaging spectrometer from Frascati, Italy. The radio data were obtained in the frequency range from 100 to 1000 MHz with the analog and digital instruments from Zürich, Switzerland. All the data sets have a time resolution of 0.1 s or better. The dynamic radio spectrum shows many fast drift type III radio bursts with both normal and reverse slope, while the X-ray time profile contains many well resolved short spikes with durations of 1 s. Some of the X-ray spikes appear to be associated in time with reverse-slop bursts suggesting either that the electron beams producing the radio bursts contain two or three orders of magnitude more fast electrons than has previously been assumed or that the electron beams can trigger or occur in coincidence with the acceleration of additional electrons. One case is presented in which a normal slope radio burst at 600 MHz occurs in coincidence with the peak of an X-ray spike to within 0.1 s. If the coincidence is not merely accidental and if it is meaningful to compare peak times, then the short delay would indicate that the radio signal was at the harmonic and that the electrons producing the radio burst were accelerated at an altitude of 4 × 10⁹ cm. Such a short delay is inconsistent with models invoking cross-field drifts to produce the electron beams that generate type III bursts but it supports the model incorporating a MASER proposed by Sprangle and Vlahos (1983).