Climate and regional resource analysis: The effect of scale on resource homogeneity

General Circulation Models (GCMs) are currently used to project future climate. The output of the models is then used to evaluate the effect of a climatic change on resources such as agriculture, forestry, and water resources. The GCMs used in long-term climate studies vary widely in the geographic resolution of their predictions. The approximate matching of resource data to the geographic scale of GCMs is an important step in the evaluation of the effects of climatic change on resources. As gridcell size increases, however, the distribution of resources within cells becomes more heterogeneous, and it becomes more difficult to evaluate the regional effects of climatic change. We quantify the change in resource heterogeneity as a function of gridcell size. Four resource variables (wheat yield, percent forest cover, population density, and percent of land irrigated) are analyzed on the basis of county-averaged data, while assignment to major drainage basins is based on exact watershed boundaries. A major change in resource heterogeneity within gridcells occurs at a grid length of from 1.2° to 3°.     

Understanding pH effects on trichloroethylene and perchloroethylene adsorption to iron in permeable reactive barriers for groundwater remediation

Metallic iron filings have been increasingly used in permeable reactive barriers for remediating groundwater contaminated by chlorinated solvents. Understanding solution pH effects on rates of reductive dechlorination in permeable reactive barriers is essential for designing remediation systems that can meet treatment objectives under conditions of varying groundwater properties. The objective of this research was to investigate how the solution pH value affects adsorption of trichloroethylene (TCE) and perchloroethylene (PCE) on metallic iron surfaces. Because adsorption is first required before reductive dechlorination can occur, pH effects on halocarbon adsorption energies may explain pH effects on dechlorination rates. Adsorption energies for trichloroethylene and perchloroethylene were calculated via molecular mechanics simulations using the Universal force field and a self-consistent reaction field charge equilibration scheme. A range in solution pH values was simulated by varying the amount of atomic hydrogen adsorbed on the iron. The potential energies associated trichloroethylene and perchloroethylene complexes were dominated by electrostatic interactions, and complex formation with the surface was found to result in significant electron transfer from the iron to the adsorbed halocarbons. Adsorbed atomic hydrogen was found to lower the energies of trichloroethylene complexes more than those for perchloroethylene. Attractions between atomic hydrogen and iron atoms were more favorable when trichloroethylene versus perchloroethylene was adsorbed to the iron surface. These two findings are consistent with the experimental observation that changes in solution pH affect trichloroethylene reaction rates more than those for perchloroethylene.     

Laboratory and pilot testing of electrocoagulation for removing scale-forming species from industrial process waters

This study investigated the performance of electrocoagulation using iron and aluminum electrodes for removing silica, calcium and magnesium from cooling tower blowdown and reverse osmosis reject waters. Experiments were conducted at both the bench and pilot scales to determine the levels of target species removal as a function of the coagulant dose. At the bench scale, aluminum removed the target compounds from both cooling tower blowdown and reverse osmosis reject more efficiently than iron. A 2 mM aluminum dose removed 80 % of the silica and 20 to 40 % of the calcium and magnesium. The same iron dose removed only 60 % of the silica and 10 to 20 % of the calcium and magnesium. When operated with iron electrodes, pilot unit performance was comparable to that of the bench unit, which suggests that such systems can be scaled-up on the basis of coagulant dose. However, when operated with aluminum electrodes the pilot unit underperformed the bench unit due to fouling of the electrode surfaces after a few hours of operation. This result was completely unexpected based on the short-term experiments performed using the bench unit.     

Deep groundwater mediates streamflow response to climate warming in the Oregon Cascades

Recent studies predict that projected climate change will lead to significant reductions in summer streamflow in the mountainous regions of the Western US. Hydrologic modeling directed at quantifying these potential changes has focused on the magnitude and timing of spring snowmelt as the key control on the spatial–temporal pattern of summer streamflow. We illustrate how spatial differences in groundwater dynamics can also play a significant role in determining streamflow responses to warming. We examine two contrasting watersheds, one located in the Western Cascades and the other in the High Cascades mountains of Oregon. We use both empirical analysis of streamflow data and physically based, spatially distributed modeling to disentangle the relative importance of multiple and interacting controls. In particular, we explore the extent to which differences in snow accumulation and melt and drainage characteristics (deep ground water vs. shallow subsurface) mediate the effect of climate change. Results show that within the Cascade Range, local variations in bedrock geology and concomitant differences in volume and seasonal fluxes of subsurface water will likely result in significant spatial variability in responses to climate forcing. Specifically, watersheds dominated by High Cascade geology will show greater absolute reductions in summer streamflow with predicted temperature increases.     

Sulphur isotopes in carbonatites and associated silicate rocks from the Superior Province, Canada

Thirty-five S isotope analyses obtained from six carbonatite complexes from the Superior Province, Canadian Shield, ranging in age from 1,897 Ma to 1,093 Ma, have δ³⁴S_CDT values of between ?4.5‰ and +3.4‰. Pyrrhotite, chalcopyrite and pyrite mineral separates were used. Each complex possesses its own distinct range and mean S isotope composition. The range for Schryburt Lake is: ?4.5‰ to ?3.4‰ ( mean?=??3.9‰), for Big Beaver House: ?3.6‰ to ?1.5‰ (mean?=??2.2‰), for Cargill: ?1.5‰–+0.5‰ (mean?=??0.7‰), for Spanish River: ?0.1‰–+0.1‰ (mean?=?0.0‰), and for Firesand River: +1.3‰–+3.4‰ (mean?=?+1.7‰). A single sample from Carb Lake yielded a δ³⁴S_CDT value of +2.8‰. Differences in isotope compositions can be related to isotope effects brought about during melt generation and emplacment, such as variations in fo₂ and temperature. The different S and C isotope data for most complexes, however, suggest that the parental melts could have been generated from a heterogeneous mantle source, although process-driven changes cannot be completely ruled out.     

Water level as the main driver of the alternation between a free-floating plant and a phytoplankton dominated state: a long-term study in a floodplain lake

This 10-year field data study explores the relevance of water level fluctuations in driving the shift from a free-floating plant (FFP) to a phytoplankton dominated state in a shallow floodplain lake from the Lower Paraná River. The multi-year natural flood pulse pattern in the Lower Paraná River drove the ecosystem regime from a FFP-dominant state during very high waters (1998–1999) to absolute phytoplankton prevalence with blooms of nitrogen fixing Cyanobacteria during extreme low waters (2008–2009). Satellite images support the observed changes over the decade and show the decrease of the surface lake area covered by FFP as well as the modification of the spectral firm in open waters, which documents the significant increases in phytoplankton chlorophyll a concentrations. We discuss the possibility that, despite a slow eutrophication in these highly vegetated systems, water level changes and not nutrients account for the shift from a floating macrophyte community to phytoplankton dominance. Cyclic shifts may occur in response to the seasonal floodpulse, but more strongly, as indicated by our results, in association to the extreme drought and flood events related to the El Niño Southern Oscillation, which is linked to discharge anomalies in the Paraná River.     

Saturn lightning recorded by Cassini/RPWS in 2004

During 2004 the Cassini/RPWS (Radio and Plasma Wave Science) instrument recorded about 5400 SEDs (Saturn Electrostatic Discharges), which were organized in 4 storm systems and 95 episodes. A computer algorithm with different intensity thresholds was applied to extract the SEDs from the RPWS data, and a statistical analysis on the main characteristics of these SEDs is performed. Compared to the SEDs recorded by the Voyagers in the early 1980s, some characteristics like SED rate, intensity, signal duration, or power spectrum are similar, but there are also remarkable differences with regard to time occurrence and frequency range: The first appearance of SEDs (storm 0) was recorded by RPWS from a distance of more than 300 Saturn radii at the end of May 2004, followed by storm A in mid-July, storm B at the beginning of August, and the most prominent storm C throughout most of September. There were also significant intervals of time with no detectable SED activity, e.g., SEDs were practically absent from October 2004 until June 2005. No clear indication for SEDs below a frequency of 1.3 MHz could be found. We suggest that the SED storms A, B, C, and possibly also storm 0 originate from the same storm system residing at a latitude of 35° South, which lasted for several months, waxed and waned in strength, and rotated with the Voyager radio period of Saturn. The SED source might be located in the updrafting water clouds beneath the visible cloud features detected in the Cassini images.     

Lunar surface electric potential changes associated with traversals through the Earth's foreshock

We report an analysis of one year of Suprathermal Ion Detector Experiment (SIDE) Total Ion Detector (TID) “resonance” events observed between January 1972 and January 1973. The study includes only those events during which upstream solar wind conditions were readily available. The analysis shows that these events are associated with lunar traversals through the dawn flank of the terrestrial magnetospheric bow shock. We propose that the events result from an increase in lunar surface electric potential effected by secondary electron emission due to primary electrons in the Earth's foreshock region (although primary ions may play a role as well). This work establishes (1) the lunar surface potential changes as the Moon moves through the terrestrial bow shock, (2) the lunar surface achieves potentials in the upstream foreshock region that differ from those in the downstream magnetosheath region, (3) these differences can be explained by the presence of energetic electron beams in the upstream foreshock region and (4) if this explanation is correct, the location of the Moon with respect to the terrestrial bow shock influences lunar surface potential.     

New views of the lunar plasma environment

A rich set of new measurements has greatly expanded our understanding of the Moon–plasma interaction over the last sixteen years, and helped demonstrate the fundamentally kinetic nature of many aspects thereof. Photon and charged particle impacts act to charge the lunar surface, forming thin Debye-scale plasma sheaths above both sunlit and shadowed hemispheres. These impacts also produce photoelectrons and secondary electrons from the surface, as well as ions from the surface and exosphere, all of which in turn feed back into the plasma environment. The solar wind interacts with sub-ion-inertial-scale crustal magnetic fields to form what may be the smallest magnetospheres in the solar system. Proton gyro-motion, solar wind pickup of protons scattered from the dayside surface, and plasma expansion into vacuum each affect the dynamics and structure of different portions of the lunar plasma wake. The Moon provides us with a basic plasma physics laboratory for the study of fundamental processes, some of which we cannot easily observe elsewhere. At the same time, the Moon provides us with a test bed for the study of processes that also operate at many other solar system bodies. We have learned much about the Moon–plasma interaction, with implications for other space and planetary environments. However, many fundamental problems remain unsolved, including the details of the coupling between various parts of the plasma environment, as well as between plasma and the surface, neutral exosphere, and dust. In this paper, we describe our current understanding of the lunar plasma environment, including illustrative new results from Lunar Prospector and Kaguya, and outstanding unsolved problems.