Raman spectroscopy of olivine in dunite experimentally shocked to pressures between 5 and 59 GPa

Abstract— Previous Raman investigations on experimentally shocked ingle‐crystal olivine indicated that the olivine Raman bands seemingly shift to a higher wave number with increasing shock pressure. If this effect could be confirmed, Raman analysis of natural shock‐metamorphosed minerals could potentially provide an important shock barometric tool. We carried out a Raman spectroscopic study on olivine in a series of natural dunite samples experimentally shocked to pressures between 5 and 59 GPa. In addition, we analyzed olivine grains in a sample of the Cold Bokkeveld C1 meteorite. We studied samples of several dunites with olivine of 90.64–92.00 mole% Fo to determine Raman effects in the region from 200 to 900 cm^?1. Several olivine grains per sample/shock pressure stage were analyzed. Raman analysis, however, showed little or no shift with increasing shock pressure. The shifts to higher or lower frequencies observed were not specific for a given pressure stage, with some grains within a sample showing more shift than others. This finding is unrelated to the crystallographic orientation of analyzed grains and cannot be related systematically to the different degrees of optically determined shock metamorphism of the analyzed grains. We identified an increase in full width at half maximum (FWHM) for the 824 cm^?1 band with increased shock pressure in the shocked Åheim samples above 45 GPa and, to a lesser extent, for the 856 cm^?1 band. Evaluation of band broadening of olivine in the Cold Bokkeveld meteorite showed FWHM values that were much greater (9–20 cm^?1) than those of olivine in the shocked dunite samples (7–12 cm^?1). We concluded that these differences in FWHM are due to differences in chemical composition between the meteoritic and the experimentally shocked olivine. Therefore, using Raman spectroscopy to detect small shifts in wave numbers to higher frequencies with increased shock pressure does not yield consistent effects for polycrystalline dunite. An extra band at 650 cm^?1 was identified in the Raman spectra of the unshocked Mooihoek dunite and the Åheim dunite samples shocked to 5, 29.3, and 59 GPa, as well as another at 696 cm^?1 in all the spectra of the 59 GPa Åheim sample. The cause of these extra bands is not known. Comparison of these results with Raman spectra of olivine from the Cold Bokkeveld C1 meteorite did not allow us to determine shock pressures for the meteoritic olivine.     

Fluorine, a direct indicator of fluorite mineralization in local and regional soil geochemical surveys

Little information is available on the use of fluorine as a direct indicator of fluorite mineralization in geochemical exploration. Until the last five to ten years, analytical methods were generally lacking good precision and were cumbersome, time-consuming and expensive, thus restricting their use in geochemical exploration work. Recently developed, rapid, partial and total fluoride extraction methods with subsequent analysis using the selective-ion electrode have made practicable the use of fluorine as a direct indicator of fluorite mineralization. This paper outlines some results of fluorine studies on soils from the fluorine province of Derbyshire, England. Some partial extraction and total fluoride analytical methods are described. Their applicability to the location of vein fluorite mineralization, concealed below both residual soil and soil developed over transported overburden, is demonstrated. Where drainage is virtually absent and soils offer the only suitable regional sampling medium, as in Derbyshire, England, soil geochemistry is shown to be a reliable tool in reconnaissance exploration work for fluorite deposits.     

Modelling of fluid–solid interactions using an adaptive mesh fluid model coupled with a combined finite–discrete element model

Fluid–structure interactions are modelled by coupling the finite element fluid/ocean model ‘Fluidity-ICOM’ with a combined finite–discrete element solid model ‘Y3D’. Because separate meshes are used for the fluids and solids, the present method is flexible in terms of discretisation schemes used for each material. Also, it can tackle multiple solids impacting on one another, without having ill-posed problems in the resolution of the fluid’s equations. Importantly, the proposed approach ensures that Newton’s third law is satisfied at the discrete level. This is done by first computing the action–reaction force on a supermesh, i.e. a function superspace of the fluid and solid meshes, and then projecting it to both meshes to use it as a source term in the fluid and solid equations. This paper demonstrates the properties of spatial conservation and accuracy of the method for a sphere immersed in a fluid, with prescribed fluid and solid velocities. While spatial conservation is shown to be independent of the mesh resolutions, accuracy requires fine resolutions in both fluid and solid meshes. It is further highlighted that unstructured meshes adapted to the solid concentration field reduce the numerical errors, in comparison with uniformly structured meshes with the same number of elements. The method is verified on flow past a falling sphere. Its potential for ocean applications is further shown through the simulation of vortex-induced vibrations of two cylinders and the flow past two flexible fibres.

     

Water uptake by two river red gum (Eucalyptus camaldulensis) clones in a discharge site plantation in the Western Australian wheatbelt

The heat-pulse technique was used to estimate year-long water uptake in a discharge zone plantation of 9-year-old clonal Eucalyptus camaldulensis Dehnh. near Wubin, Western Australia. Water uptake matched rainfall closely during weter months but exceeded rainfall as the dry season progressed. Average annual water uptake (1148 mm) exceeded rainfall (432 mm) by about 2.7 fold and approached 56% of pan evaporation for the area. The data suggest that at least 37% (i.e. (1/2.7) × 100) of the lower catchment discharge zone should be planted to prevent the rise of groundwater.

Water uptake varied with soil environment, season and genotype. Upslope trees used more water than did downslope trees. Water uptake was higher in E. camaldulensis clone M80 than in clone M66 until late spring. The difference reversed as summer progressed. Both clones, however, have the potential to dry out the landscape when potential evapotranspiration exceeds rainfall. This variation in water uptake within the species indicates the potential for manipulating plantation uptake by matching tree characteristics to site characteristics.

Controlled experiments on the heat-pulse technique indicated accuracy errors of approximately 10%. This, combined with the ability to obtain long-term, continuous data and the superior logistics of use of the heat-pulse technique, suggests that results obtained by it would be much more reliable than those achieved by the ventilated chamber technique.     

VLF propagation loss to a buried seismometer

The propagation loss from a shallow underwater explosion to a buried vertically polarized seismometer over the frequency band between 3 and 15 Hz was measured during the 1983 Ngendei Experiment. The data was recorded in 5.5-km-deep water in the southwest Pacific with a triaxial borehole seismograph emplaced 50 m within the basaltic basement. It is found that the average power decays as r^-3 (r is slant range) beyond 30 km and that the propagation loss is minimal between 6-9 Hz. At shorter ranges, the propagation loss is more complicated and exhibits a stronger frequency dependence. Power in the first water wave is estimated for both buried and ocean-bottom sensors. The ocean-bottom power is approximately 7 dB higher than that recorded by the buried sensor, and both exhibit similar decay rates     

Understanding pH effects on trichloroethylene and perchloroethylene adsorption to iron in permeable reactive barriers for groundwater remediation

Metallic iron filings have been increasingly used in permeable reactive barriers for remediating groundwater contaminated by chlorinated solvents. Understanding solution pH effects on rates of reductive dechlorination in permeable reactive barriers is essential for designing remediation systems that can meet treatment objectives under conditions of varying groundwater properties. The objective of this research was to investigate how the solution pH value affects adsorption of trichloroethylene (TCE) and perchloroethylene (PCE) on metallic iron surfaces. Because adsorption is first required before reductive dechlorination can occur, pH effects on halocarbon adsorption energies may explain pH effects on dechlorination rates. Adsorption energies for trichloroethylene and perchloroethylene were calculated via molecular mechanics simulations using the Universal force field and a self-consistent reaction field charge equilibration scheme. A range in solution pH values was simulated by varying the amount of atomic hydrogen adsorbed on the iron. The potential energies associated trichloroethylene and perchloroethylene complexes were dominated by electrostatic interactions, and complex formation with the surface was found to result in significant electron transfer from the iron to the adsorbed halocarbons. Adsorbed atomic hydrogen was found to lower the energies of trichloroethylene complexes more than those for perchloroethylene. Attractions between atomic hydrogen and iron atoms were more favorable when trichloroethylene versus perchloroethylene was adsorbed to the iron surface. These two findings are consistent with the experimental observation that changes in solution pH affect trichloroethylene reaction rates more than those for perchloroethylene.     

Climate and regional resource analysis: The effect of scale on resource homogeneity

General Circulation Models (GCMs) are currently used to project future climate. The output of the models is then used to evaluate the effect of a climatic change on resources such as agriculture, forestry, and water resources. The GCMs used in long-term climate studies vary widely in the geographic resolution of their predictions. The approximate matching of resource data to the geographic scale of GCMs is an important step in the evaluation of the effects of climatic change on resources. As gridcell size increases, however, the distribution of resources within cells becomes more heterogeneous, and it becomes more difficult to evaluate the regional effects of climatic change. We quantify the change in resource heterogeneity as a function of gridcell size. Four resource variables (wheat yield, percent forest cover, population density, and percent of land irrigated) are analyzed on the basis of county-averaged data, while assignment to major drainage basins is based on exact watershed boundaries. A major change in resource heterogeneity within gridcells occurs at a grid length of from 1.2° to 3°.     

Climate change simulated by full and mixed-layer ocean versions of CSIRO Mk3.5 and Mk3.0: Large-scale sensitivity

The CSIRO Mk3.5 coupled atmosphere-ocean model includes upgrades to atmospheric and oceanic processes that remove a cold bias of the earlier Mk3.0. The global mean warming over the 21st century from Mk3.5 is 3.1 K under the CMIP3 A1B scenario, some 25% larger than that from Mk3.0. Two mixed-layer ocean versions of Mk3.5 were constructed, and these are also more sensitive than Mk3.0. To elucidate these differences, a simple feedback analysis is extended to Mk3.5, using changes for doubled CO₂ in each model version. The net feedback for the low-mid latitude region is the main driver of the sensitivity contrast. The clear-sky component is consistently larger in Mk3.5, as is the increase in specific humidity, even after standardizing by the global warming. Cloud forcing provides a small positive feedback, which is stronger in cases that had larger declines in low-layer cloud. The net positive feedback for the higher-latitude region is larger in the coupled Mk3.5 than Mk3.0, which had more stable Arctic sea ice. However, some contrasts differed among the versions. As for Mk3.0, the surface warming in the coupled Mk3.5 is suppressed over that from the MLO case. Over the ocean, the pattern of suppression is similar to the change in energy flux into the surface in the coupled model. There is also a gradient of equatorial warming in the Asia-Pacific region that relates to the change in net convergence of heat transport by ocean currents. The effect of this pattern on regional rainfall is a focus of Part 2 of the study.