Statistical techniques for the classification of chromites in diamond exploration samples

A database of 1267 quality-screened major- and trace-element analyses of chromites (s.l.) from kimberlites, lamproites, ultramafic lamprophyres (UMLs) and crustal sources (‘greenstones’, including ophiolites, gabbros, basalts and komatiites) has been subjected to statistical analysis, in order to derive discriminants for use in diamond exploration. The techniques used included nearest-neighbour analysis, CART (classification and regression trees) and MARS (multivariate adaptive regression splines). The results show that both CART and MARS approaches can correctly discriminate kimberlite/lamproite chromites from UML/‘greenstone’ chromites at levels near 90%. Discrimination into the four classes separately is achieved at levels of ca. 80% by MARS and > 70% by CART; much of the misclassification is between the kimberlite and lamproite classes. These results probably represent the maximum probable level of discrimination on chemical criteria, given that ascending magmas may sample both mantle and crustal rocks. The CART approach produces a classification tree that requires no further computation to classify a given grain; the MARS approach requires the use of a simple software package. Tests on known samples illustrate the high level of accuracy of the methods in an exploration context, as well as the useful petrogenetic conclusions that can be drawn from some ‘misclassifications’.     

Accurate GPS measurement of the location and orientation of a floating platform

Abstract

This article describes the design and initial tests of the GPS portion of a system for making seafloor geodesy measurements. In the planned system, GPS antennas on a floating platform will be used to measure the location of an acoustic transducer, attached below the platform, which interrogates an array of transponders on the seafloor. Since the GPS antennas are necessarily some distance above the transducer, a short‐baseline GPS interferometer consisting of three antennas is used to measure the platform's orientation.

A preliminary test of several crucial elements of the system was performed at the Scripps Institution of Oceanography (SIO) in December 1989. The test involved a fixed antenna on the pier and a second antenna floating on a buoy about 80 m away. GPS measurements of the vertical component of this baseline, analyzed independently by two groups using different software, agree with each other and with an independent measurement within a centimeter.

The first test of an integrated GPS/acoustic system took place in the Santa Cruz Basin off the coast of southern California in May 1990. In this test a much larger buoy, designed and built at SIO, was equipped with three GPS antennas and an acoustic transducer that interrogated a transponder on the ocean floor. Preliminary analysis indicates that the horizontal position of the transponder can be determined with a precision of about a centimeter. Further analysis will be required to investigate the magnitude of systematic errors.     

Sodium fluoroacetate (1080) residues in longfin eels,Anguilla dieffenbachii,following exposure to contaminated water and food

Captive longfin eels (Anguilla dieffenbachii) were exposed to the vertebrate pesticide sodium fluoroacetate (1080) in the water column and through the ingestion of cereal pellet baits or possum muscle and gut tissue that contained 1080 residue. No mortality or unusual behaviour (in comparison with the controls) occurred in eels that were exposed to 1080. However, significantly greater weight loss occurred in eels exposed to 1080 compared with those eels that were not. No residue was detected in tissues of eels exposed to 1080 cereal baits through ingestion and direct (dermal and respiratory) absorption, or through direct absorption only. Low concentrations of 1080 were detected in muscle tissue of eels that consumed contaminated possum muscle (x = 0.0174 μg/g) or gut (x = 0.0306 μg/g) tissue. The primary factors affecting the concentration of 1080 detected in eel tissue included the dose of 1080 (mg/kg) that each eel" receiveddate="and number of days since the eel last fed on contaminated tissue. Based on the 1080 concentrations measured in eels in this study, the risk of acute poisoning to humans from eating contaminated eel flesh is considered extremely low. Even so, national and international perceptions and food safety standards have the potential to limit eel exports and/or close an eel fishery if 1080 residue was discovered in tissue.     

Copper in the sediment and sea surface microlayer near a fallowed, open-net fish farm

Sediment and sea surface microlayer samples near an open-net salmon farm in Nova Scotia, were analysed for copper. Copper is a constituent of the feed and is an active ingredient of anti-foulants. The salmon farm was placed in fallow after 15years of production. Sampling was pursued over 27months. Elevated copper concentrations in the sediments indicated the farm site as a source. Bubble flotation due to gas-emitting sediments from eutrophication is a likely process for accumulating copper in the sea surface microlayer at enriched concentrations. Elevated and enriched concentrations in the sea surface microlayer over distance from the farm site led, as a result of wind-drift, to an enlarged farm footprint. The levels of copper in both sediments and sea surface microlayer exceeded guidelines for protection of marine life. Over the 27months period, copper levels persisted in the sediments and decreased gradually in the sea surface microlayer.     

The geomorphic function and characteristics of large woody debris in low gradient rivers, coastal Maine, USA

The role, function, and importance of large woody debris (LWD) in rivers depend strongly on environmental context and land use history. The coastal watersheds of central and northern Maine, northeastern U.S., are characterized by low gradients, moderate topography, and minimal influence of mass wasting processes, along with a history of intensive commercial timber harvest. In spite of the ecological importance of these rivers, which contain the last wild populations of Atlantic salmon (Salmo salar) in the U.S., we know little about LWD distribution, dynamics, and function in these systems. We conducted a cross-basin analysis in seven coastal Maine watersheds, documenting the size, frequency, volume, position, and orientation of LWD, as well as the association between LWD, pool formation, and sediment storage. In conjunction with these LWD surveys, we conducted extensive riparian vegetation surveys. We observed very low LWD frequencies and volumes across the 60 km of rivers surveyed. Frequency of LWD ≥ 20 cm diameter ranged from 15–50 pieces km^− 1 and wood volumes were commonly < 10–20 m³ km^− 1. Moreover, most of this wood was located in the immediate low-flow channel zone, was oriented parallel to flow, and failed to span the stream channel. As a result, pool formation associated with LWD is generally lacking and < 20% of the wood was associated with sediment storage. Low LWD volumes are consistent with the relatively young riparian stands we observed, with the large majority of trees < 20 cm DBH. These results strongly reflect the legacy of intensive timber harvest and land clearing and suggest that the frequency and distribution of LWD may be considerably less than presettlement and/or future desired conditions.     

SHORELINE CHANGE AT THOMPSON ISLAND,BOSTON HARBOR,MASSACHUSETTS, 1938-1977

A photogrammetric and sediment analysis is presented to illustrate the relationship between beach erosion and seacliff recession on Thompson Island, Boston Harbor, Massachusetts. Aerial photographs taken in 1938, 1952, 1963, and 1977 were measured to determine rates of shoreline change around the island. The 39-year average rate of beach erosion is 0.3 m/yr ± 2% with an average rate of cliff recession at 0.2 m/yr ± 2%. Rates of beach erosion between six orientations that reflect principal wave approach to the island were not found to be significantly different (0.05) for the 39-year period. The rank order correlation between beach erosion and cliff recession for these six orientations was moderately well correlated (0.63). To determine possible controls of cliff erosion, 58 sediment samples were collected from glacial cliffs along the shoreline. The textural composition was determined, and then tested with discriminant function analysis. Partial correlation analysis between beach erosion and cliff recession holding a surrogate for sediment size constant improved the rank order from 0.63 to 0.84. The results indicate that coarser-grained cliffs recede at faster rates, but with less erosion occurring on adjacent beaches. Alternatively, finer-grained cliffs recede at slower rates, but with greater erosion occurring on adjacent beaches.     

Double vagueness: uncertainty in multi-scale fuzzy assignment of duneness

In the automation of identification of landscape features the vagueness arises from the fact that the attributes and parameters that make up a landscape vary over space and scale. In most of existing studies, these two kinds of vagueness are studied separately. This paper investigates their combination in identification of coast landscape units. Fuzzy set theory is used to describe the vagueness of geomorphic features due to the continuity in space. The vagueness resulted from the scale of measurement is evaluated by statistic indicators. The differences of fuzzy objects derived from data at differing resolutions (in size from 3×3 cells to 25×25 cells) are studied in order to examine these higher-order uncertainties.     

Spatial variation in fluid flow and geochemical fluxes across the sediment-seawater interface at the Carlos Ribeiro mud volcano (Gulf of Cadiz)

Submarine mud volcanism is an important pathway for transfer of deep-sourced fluids enriched in hydrocarbons and other elements into the ocean. Numerous mud volcanoes (MVs) have been discovered along oceanic plate margins, and integrated elemental fluxes are potentially significant for oceanic chemical budgets. Here, we present the first detailed study of the spatial variation in fluid and chemical fluxes at the Carlos Ribeiro MV in the Gulf of Cadiz. To this end, we combine analyses of the chemical composition of pore fluids with a 1-D transport-reaction model to quantify fluid fluxes, and fluxes of boron, lithium and methane, across the sediment-seawater interface. The pore fluids are significantly depleted in chloride, but enriched in lithium, boron and hydrocarbons, relative to seawater. Pore water profiles of sulphate, hydrogen sulphide and total alkalinity indicate that anaerobic oxidation of methane occurs at 34-180 cm depth below seafloor. Clay mineral dehydration, and in particular the transformation of smectite to illite, produces pore fluids that are depleted in chloride and potassium. Profiles of boron, lithium and potassium are closely related, which suggests that lithium and boron are released from the sediments during this transformation. Pore fluids are expelled into the water column by advection; fluid flow velocities are 4 cm yr⁻¹ at the apex of the MV but they rapidly decrease to 0.4 cm yr⁻¹ at the periphery. The associated fluxes of boron, lithium and methane vary between 7-301, 0.5-6 and 0-806 mmol m⁻² yr⁻¹, respectively. We demonstrate that fluxes of Li and B due to mud volcanism may be important on a global scale, however, release of methane into the overlying water column is suppressed by microbial methanotrophy.     

Terrestrial sensitivity to abrupt cooling recorded by aeolian activity in northwest Ohio, USA

Lower slopes of the Sandia Mountains are characterized by granitic corestone topography and weathering-limited slopes with thin grusy colluvium and weakly developed soils. In contrast, thick soils with illuvial clay and pedogenic carbonate have developed below aplite outcrops. Aplite is resistant to chemical decomposition, but physically weathers to blocky clasts that enhance surface roughness and erosional resistance of colluvium, promoting accumulation of eolian fines. Thick B horizons on aplite slopes indicate limited erosion and prolonged periods of stability and soil development. Accretion of eolian material limits runoff and prevents attainment of a steady-state balance between soil production and downslope transport.