Relating the reproductive toxicity of five ingested metals in calanoid copepods with sulfur affinity

The sublethal toxicity of dietary Ag, Cd, Hg, Mn, and Zn to marine copepods, measured as depressed egg production, was evaluated as a function of ambient metal concentrations and metal concentrations in copepod tissues. All metals were toxic following 4-h feedings on metal-contaminated phytoplankton food, but there was a four order of magnitude difference between the inhibitory concentration in copepod tissues of the most toxic (2.4 nmol g(-1) dry wt. for Hg) and least toxic (13.4 micromol g(-1) dry wt. for Mn) metals. Metal concentrations in copepods that elicited a toxic response were about 3 times higher than background concentrations for Ag and 9 times higher for Hg, about 2 times higher for Cd, two orders of magnitude higher for Mn, and only 5% higher for Zn. Copepods exposed to lower concentrations of Zn for longer periods (1 week), resulting in tissue Zn concentrations similar to those in the short-term exposures, were not affected, suggesting that copepods were capable of adjusting to slowly increasing Zn by sequestration of this metal. Toxic metal concentrations in copepod tissues were directly proportional (r2 = 0.85) to the affinity of the metals for sulfur, as indicated by the solubility products of the metal sulfides. This relationship, together with protein analysis of eggs, published recently, suggests that metals affect egg production by binding to enzymes involved with vitellogenesis.     

Latitudinal variability of large-scale coronal temperature and its association with the density and the global magnetic field

In this paper we utilize the latitude distribution of the coronal temperature during the period 1984–1992 that was derived in a paper by Guhathakurta et al, 1993, utilizing ground-based intensity observations of the green (5303 Fe XIV) and red (6374 Fe X) coronal forbidden lines from the National Solar Observatory at Sacramento Peak, and estabish its association with the global magnetic field and the density distributions in the corona. A determination of plasma temperature,T, was estimated from the intensity ratio Fe X/Fe XIV (whereT is inversely proportional to the ratio), since both emission lines come from ionized states of Fe, and the ratio is only weakly dependent on density. We observe that there is a large-scale organization of the inferred coronal temperature distribution that is associated with the large-scale, weak magnetic field structures and bright coronal features; this organization tends to persist through most of the magnetic activity cycle. These high-temperature structures exhibit time-space characteristics which are similar to those of the polar crown filaments. This distribution differs in spatial and temporal characterization from the traditional picture of sunspot and active region evolution over the range of the sunspot cycle, which are manifestations of the small-scale, strong magnetic field regions.affiliated to USRA     

Geology and tectonics of Beta Regio,Guinevere Planitia,Sedna Planitia,and Western Eistla Regio,Venus: Results from Arecibo image data

New radar images (resolution 1.5–2.0 km) obtained from the Arecibo Observatory are used to assess the geology of a portion of the equatorial region of Venus (1 S to 45 N and from 270 eastward to 30). Nine geologic units are mapped on the basis of their radar characteristics and their distribution and correspondences with topography are examined. Plains are the most abundant unit, make up 80%; of the area imaged, and are divided into bright, dark, and mottled. Mottled plains contain abundant lava flows and domes suggesting that volcanism forming plains is a significant process in the equatorial region of Venus. Tesserae are found primarily on Beta Regio and its eastern flank and are interpreted to be locally stratigraphically older units, predating episodes of faulting and plains formation. Isolated regions of tesserae concentrated to the north of Western Eistla Regio are interpreted to predate the formation of plains in this area. The volcanoes Sif Mons, Gula Mons, Sappho, Theia Mons, and Rhea Mons, are found exclusively in highland regions and their deposits are interpreted as contributing only a small percentage to the overall volume of the regional topography. The northern 15 of the image data overlap with Venera 15/16 images making it possible to examine the characteristics of geologic units mapped under various illumination directions and incidence angles. Surface panoramas and geochemical data obtained from Venera landers provide ground truth for map units, evidence that plains are made up of basaltic lava flows, and that linear deformation zones contain abundant blocks and cobbles. On the basis of spatial and temporal relationships between geologic units, the highlands of Beta Regio and Western Eistla Regio are interpreted to have formed in association with areas of mantle upwelling which uplift plains, cause rifting, and in the case of Beta Regio, disrupt a large region of tessera. Zones of linear belt deformation in Beta Regio and Western Eistla Regio are interpreted to be extensional and indicate that at least limited extension has occurred in both regions. The images reveal for the first time that southern Devana Chasma is a region of overlapping rift valleys separated by a distance of 600 km. Linear deformation zones in Guinevere Planitia, separating Beta Regio and Eistla Regio, converge at a region of ovoids forming a discontinuous zone of disruption and completes an equatorial encompassing network of highlands and tectonic features. The similarity between ovoids and coronae suggests a mechanism of formation associated with hotspots or mantle plumes. Analysis of the distribution and density of impact craters suggests a surface age for this part of the planet similar to or slightly less than that determined for the northern high latitudes from Venera 15/16 data (0.3 to 1.5 by) and comparable to that calculated for the southern hemisphere.     

Big lake records preserved in a little lake’s sediment: an example from Silver Lake,Michigan, USA

We reconstruct postglacial lake-level history within the Lake Michigan basin using soil stratigraphy, ground-penetrating radar (GPR), sedimentology and ¹⁴C data from the Silver Lake basin, which lies adjacent to Lake Michigan. Stratigraphy in nine vibracores recovered from the floor of Silver Lake appears to reflect fluctuation of water levels in the Lake Michigan basin. Aeolian activity within the study area from 3,000 years (cal yr. B.P.) to the present was inferred from analysis of buried soils, an aerial photograph sequence, and GPR. Sediments in and around Silver Lake appear to contain a paleoenvironmental record that spans the entire post-glacial history of the Lake Michigan basin. We suggest that (1) a pre-Nipissing rather than a Nipissing barrier separated Silver Lake basin from the Lake Michigan basin, (2) that the Nipissing transgression elevated the water table in the Silver Lake basin about 6,500 cal yr. B.P., resulting in reestablishment of a lake within the basin, and (3) that recent dune migration into Silver Lake is associated with levels of Lake Michigan. This is the fourth in a series of ten papers published in this special issue of Journal of Paleolimnology. These papers were presented at the 47th Annual Meeting of the International Association for Great Lakes Research (2004), held at the University of Waterloo, Waterloo, Ontario, Canada. P.F. Karrow and C.F.M. Lewis were guest editors of this special issue.     

Persistence of vinyl chloride in ground water at the Woodlawn landfill Superfund site,northeastern Maryland,USA

Since landfill operations ceased in the early 1980s at the Woodlawn landfill Superfund site in northeastern Maryland, USA, the carcinogen vinyl chloride monomer (VCM) has persisted in the site ground water at concentrations in places greater than 100 ppb. Investigations of VCM concentrations from monitoring well data from 1981 through 1991, which were published in 2001, concluded that concentrations were cyclic and were not dissipating. Data from 1991 to 2000 confirm VCM persistence, showing concentration peaks as late as 1997 in the eastern part of the site. These values are significantly above both drinking water standards (>MCL of 2 ppb) and lifetime excess cancer risk (E-6 risk level) from exposure since birth (>0.024 ppb). Sources for VCM are landfill wastes (PVC-sludge) and effluent from an on-site transfer station. In addition to direct release of VCM from wastes, other chlorinated hydrocarbons, trichloroethene and perchloroethene (TCE and PCE) are also present in the ground water, and these compounds can degrade into VCM. Persistence of VCM concentrations is the result of leachate generation, mostly from multi-source wastes in the vadose zone, with subsequent infiltration into the regional aquifer. Increases in VCM concentrations (new leachate generation) alternated with decreases in VCM concentrations (infiltration without leachate) in a cyclic fashion, during this 20-year period.     

Planktic foraminiferal porosity: a water mass proxy for latest Cenomanian paleoceanography, Greenhorn Sea, Western Interior USA and Canada

Planktic foraminiferal porosity analyses can be used as a water mass proxy and were conducted on samples from above the latest Cenomanian Neocardioceras or B bentonite from the Western Interior Seaway of North America. This time slice provides a snapshot of water mass characteristics in this vast epicontinental sea during the early phase of Oceanic Anoxic Event 2. Mean sample porosity decreases northward and is interpreted as northward decrease in water temperature at the depth Hedbergella delrioensis (Carsey) calcified. Four water masses are defined by porosity, their boundaries are extremely similar to water mass boundaries previously identified by others using the distributions of macrofossils, microfossils and lithology. The boundary between the Subtropical–Tropical Water Mass and Central Subtropical Water Mass was located in southern Colorado. The boundary between the Central Subtropical Water Mass and the Northern Temperate Water Mass lay at approximately 48°N latitude. This boundary is displaced northward approximately 8° latitude as compared to the Holocene planktic foraminiferal temperate ocean province. Within-sample porosity variation suggests all water masses except the Temperate Water Mass were thermally stratified. Samples from the south indicate that the Subtropical–Tropical Water Mass was the most stratified. The porosity data support a previously published data-based paleoceanographic circulation of the southwestern seaway.     

Dissolved and particulate organic carbon in Chesapeake Bay

We measured dissolved and particulate organic carbon (DOC and POC) in samples collected along 13 transects of the salinity gradient of Chesapeake Bay. Riverine DOC and POC end-members averaged 232±19 μM and 151±53 μM, respectively, and coastal DOC and POC end-members averaged 172±19 μM and 43±6 μM, respectively. Within the chlorophyll maximum, POC accumulated to concentrations 50–150 μM above those expected from conservative mixing and it was significantly correlated with chlorophylla, indicating phytoplankton origin. POC accumulated primarily in bottom waters in spring, and primarily in surface waters in summer. Net DOC accumulation (60–120 μM) was observed within and downstream of the chlorophyll maximum, primarily during spring and summer in both surface and bottom waters, and it also appeared to be derived from phytoplankton. In the turbidity maximum, there were also net decreases in chlorophylla (?3 μg l^?1 to ?22 μg l^?1) and POC concentrations (?2 μM to ?89 μM) and transient DOC increases (9–88 μM), primarily in summer. These occurred as freshwater plankton blooms mixed with turbid, low salinity seawater, and we attribute the observed POC and DOC changes to lysis and sedimentation of freshwater plankton. DOC accumulation in both regions of Chesapeake Bay was estimated to be greater than atmospheric or terrestrial organic carbon inputs and was equivalent to ≈10% of estuarine primary production.     

Vibracoring from lake ice with a lightweight monopod and piston coring apparatus

A monopod and piston coring apparatus for coring water-saturated sediment is described. The lightweight apparatus can be used from either an ice platform or the ground surface and can be transported by aircraft. Using a piston, core recovery is increased to better than 90%, and depending upon the monopod height, 7 m-long cores can be obtained. Tips for coring in freezing temperatures are also given.     

A freshwater population of the mummichog,Fundulus heteroclitus,from the Susquehanna River drainage in Pennsylvania

An established population of mummichog,Fundulus heteroclitus, in the Susquehanna drainage is reported from Pennsylvania for the first time. Three year classes of this brackish water species were taken on 17 August 1976 from Letort Spring Run, a tributary of the Conodoguinet Creek in Cumberland County. A survey of unpublished records and museum specimens revealed occurrences in Wissahickon Creek, Montgomery County, and Brandywine Creek, Chester County; both Delaware drainage. Presence in these drainages is believed the result of bait bucket introduction.     

Correction of ground-water chemistry and carbon isotopic composition for effects of CO2 outgassing

Direct measurements on water samples from several CO₂-charged warm springs are significantly higher than values calculated from field pH and alkalinity (and other constituents). In addition, calcite saturation indices calculated from field pH and solution composition indicated supersaturation in samples which, on the basis of hydrogeologic concepts, should be near saturation or undersaturated. We attribute these discrepancies to uncertainties in field pH, resulting from CO₂ outgassing during pH measurement. Because samples for direct measurement can be taken with minimal disturbance to the water chemistry, we have used the measured to back calculate an estimate of the field pH and the carbon isotopic composition of the water before outgassing. By reconstructing water chemistry in this way, we find generally consistent grouping of $\text{δ}{}^{13}\text{C}$, pH, and degree of calcite saturation in samples taken from the same source at different times, an observation which we expect based on our understanding of the hydrogeology and geochemistry of the ground-water systems. This suggests that for very careful geochemical work, particularly on ground-waters much above ambient temperature, measurements may provide more information on the system and a better estimate of its state of saturation with respect to carbonate minerals than can field measurements of pH.