Raman spectroscopy and biomarker analysis reveal multiple carbon inputs to a Precambrian glacial sediment

Extractable biomarkers can help elucidate the environment and biota of ancient glaciations, although the method must be applied with care, as glacial sediments have a potential for incorporation of older detrital carbon. In Phanerozoic glacial sediments, the distinct elemental, molecular and isotopic compositions of the terrestrial and marine biomass allow discrimination between primary marine and redeposited terrestrial organic matter. However, as the Proterozoic biosphere was largely microbial and marine, biomarker and isotopic analyses are insufficient for distinguishing primary organic matter from secondary reworked organic matter. Here, we report the combined application of Raman spectroscopy and biomarker analysis to Precambrian glacial sediments, which, together, allows discrimination between mixed pools of organic carbon and provides a promising new approach for rapidly screening Precambrian sediments for immature organic matter amenable to biomarker analysis.     

Quasi-periodic burst structure at 2.8 GHz and its relationship to burst morphological parameters

Fifteen examples of quasi-periodic 2.8 GHz burst emission observed at the La Posta Astrogeophysical Observatory during the period December 1966 through May 1973 were identified. The periods of these events and those of 22 additional events previously reported in the literature were plotted against burst morphological parameters. The relationship between period and event energy was found to be considerably weaker than initially reported by Cribbens and Matthews.     

Windblown sand on Venus: Preliminary results of laboratory simulations

Small particles and winds of sufficient strength to move them have been detected from Venera and Pioneer-Venus data and suggest the existence of aeolian processes on Venus. The Venus wind tunnel (VWT) was fabricated in order to investigate the behavior of windblown particles in a simulated Venusian environment. Preliminary results show that sand-size material is readily entrained at the wind speeds detected on Venus and that saltating grains achieve velocities closely matching those of the wind. Measurements of saltation threshold and particle flux for various particle sizes have been compared with theoretical models which were developed by extrapolation of findings from Martian and terrestial simulations. Results are in general agreement with theory, although certain discrepancies are apparent which may be attributed to experimental and/or theoretical-modeling procedures. Present findings enable a better understanding of Venusian surface processes and suggest that aeolian processes are important in the geological evolution of Venus.     

Splendid isolation: local uniqueness of the centered co-circular relative equilibria in the <Emphasis Type="Italic">N</Emphasis>-body problem

We study the neighborhood of the equal mass regular polygon relative equilibria in the N-body probem, and show that this relative equilibirum is isolated among the co-circular configurations (in which each point lies on a common circle) for which the center of mass is located at the center of the common circle. It is also isolated in the sense that a sufficiently small mass cannot be added to the common circle to form a \(N+1\)-body relative equilibrium. These results provide strong evidence for a conjecture that the equal mass regular polygon is the only co-circular relative equilibrium with its center of mass located at the center of the common circle.     

Pressure dependence of hydrogen bonding in metal deuteroxides: a neutron powder diffraction study of Mn(OD)2 and β-Co(OD)2.

The structures of deuterated pyrochroite, Mn(OD)₂ and β−Cο(OD)₂ have been refined using the Rietveld method and neutron powder diffraction data collected in an opposed-anvil high pressure (Paris-Edinburgh) cell from room pressure to 9 GPa. The equation of state for Mn(OD)₂ was determined (K=41(3) GPa for fixed K′=4.7) and found to be consistent with previous studies of the isostructural brucite, Mg(OD)₂. The compressibility of β−Cο(OD)₂ on the other hand is apparently anomalous. The c-axis initially decreases at 3 times the rate of decrease of the a-axis; the ratio decreases to about 1.5 at an estimated 6 GPa before increasing again beyond this pressure. There is no obvious corresponding anomaly in the details of the atomic structure. In both materials there is an increase in the D-site disorder with pressure. A split-site model for the D-positions best fits the data at pressures above 8 GPa. There is no statistically significant increase in the O-D interatomic distance at increased pressure while the hydrogen bonding interaction D...O appears to increase as this distance decreases and the O-D...O angle increases. The intramolecular O-D bond valences, determined indirectly from the intermolecular D...O distances, decrease steadily for both materials as pressure is increased. Received: 31 October 1996 / Revised, accepted: 27 February 1997