Arsenic anomalies in shallow Venetian Plain (Northeast Italy) groundwater

A pilot area within the Venetian Plain was selected to assess the arsenic (As) contamination of groundwater. The area represents a typical residential, industrial and agricultural organization representative of most western countries, and is also devoid of lithologies with high or anomalous As content. Hydrogeological and chemical data have been collected, the latter spatialized by a geostatistical approach. The unconfined aquifer reservoir varies from a predominantly gravel composition in the north to a sandy and silt–clay composition further south, including peat layers. The hydrochemical features of the waters are rather homogeneous, featuring low mineral content and a Ca-bicarbonate signature. In contrast, the redox state is highly variable; oxidizing conditions are predominant in the northern and coarse parts of the aquifer, whereas reducing potentials prevail in the southern and silt–clay parts. Several well waters contain arsenic in excess of drinkable limits (=10 ppb), and most of these wells are located in the southern area. A large portion of the studied area has a high probability of containing non-potable water (up to 150 ppb As). Remarkably, As “hot spots” (As > 300 ppb, up to 431 ppb) were identified at the transition from gravel to silt–clay sediments. No industrial or agricultural source of As has been found.     

Sea-level rise impacts on longitudinal salinity for a low-gradient estuarine system

Climatic Change - Salinity response to sea-level rise is evaluated for a low-gradient, tidally active estuary, the lower St. Johns River, Florida. A high-resolution numerical model is forced by...     

The impact of the Laacher See Volcano (11 000 yr B.P.) on terrestrial vegetation and diatoms

Late-glacial lake sediments containing the Laacher See Tephra (LST, 11 000 yr B.P.) have been analyzed for their pollen and diatom content at three sites at varying distances from the volcano and on different bedrock geologies. The aim was to test the null hypothesis that this major volcanic eruption had no effect on terrestrial pollen or aquatic diatom assemblages. The pollen spectra at all sites show a short-lived increase in grass pollen following the LST. Partial redundancy analysis and associated Monte Carlo permutation tests suggest, however, that the LST had no statistically significant effect at two sites but it had a statistically significant impact on the pollen assemblages at the site nearest (60 km) to the volcano.The diatom assemblages at the three sites changed individualistically after the LST deposition, with increases inAchnanthes minutissima at one site, an expansion ofAulacoseira species at another, and an increase ofAsterionella formosa andFragilaria brevistriata at the third site. Partial redundancy analysis and associated permutation tests suggest a statistically significant change in diatoms in relation to the LST and associated changes in sediment lithology at the one site situated on acidic bedrock. No significant impacts were found at the sites on volcanic or calcareous rocks. Due to the interaction between tephra and sediment lithology, it is not possible to conclude if the statistically significant diatom changes were a direct result of the LST deposition or an indirect result of lithological changes following LST deposition.This is the first paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Paeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

Origin of dacites of Taupo Volcanic Zone, New Zealand

Dacites form a relatively small proportion of lavas in the Taupo Volcanic Zone, New Zealand (5km³), and occur mainly on the eastern side. In this paper their origin is considered in terms of three processes: (a) partial melting of crustal rocks; (b) fractional crystallisation of basalt and andesite; and (c) sub-surface mixing of basic and acid magma. Modelling techniques are used to calculate the most acceptable degree of fractional crystallisation and magma mixing to fit major-element data, and these values are used to compare calculated and observed trace-element values. The success or failure of the model is determined by the closeness of the two sets of values. For partial-melt models, trace-element values alone are calculated by the batch-melting equation.Results indicate that White Island dacite can best be modelled by fractional crystallisation; Manawahe by fractional crystallisation plus limited crustal contamination; Maungaongaonga by partial melting of Western Basement greywacke, and Tauhara by partial melting of this greywacke together with minor mixing with a more basic magma. Results from Parekauau and Horohoro indicate that these lavas are unlikely to have formed by any of the processes examined.     

Source investigation of a small event using empirical Green's functions and simulated annealing

We propose a two-step inversion of three-component seismograms that (1) recovers the far-field source time function at each station and (2) estimates the distribution of co-seismic slip on the fault plane for small earthquakes (magnitude 3 to 4). The empirical Green's function (EGF) method consists of finding a small earthquake located near the one we wish to study and then performing a deconvolution to remove the path, site, and instrumental effects from the main-event signal.
The deconvolution between the two earthquakes is an unstable procedure: we have therefore developed a simulated annealing technique to recover a stable and positive source time function (STF) in the time domain at each station with an estimation of uncertainties. Given a good azimuthal coverage, we can obtain information on the directivity effect as well as on the rupture process. We propose an inversion method by simulated annealing using the STF to recover the distribution of slip on the fault plane with a constant rupture-velocity model. This method permits estimation of physical quantities on the fault plane, as well as possible identification of the real fault plane.
We apply this two-step procedure for an event of magnitude 3 recorded in the Gulf of Corinth in August 1991. A nearby event of magnitude 2 provides us with empirical Green's functions for each station. We estimate an active fault area of 0.02 to 0.15 km² and deduce a stress-drop value of 1 to 30 bar and an average slip of 0.1 to 1.6 cm. The selected fault of the main event is in good agreement with the existence of a detachment surface inferred from the tectonics of this half-graben.     

Petrology of the Izmir-Karaburun volcanic area (West Turkey)

The Izmir-Karaburun region is located on the West coast of Turkey. In this area volcanic rocks of the late Miocene-Pliocene age outcrop. On the basis of the collected petrographic and geochemical data it has been possible to subdivide these rocks in to three series:a) calc-alkaline series of Karaburun-Koca dag-Izmir (quantitatively the most important). This series is formed by latite-andesites-dacites-rhyodacites.b) Silicic series of Izmir-Lebedos, mainly constituted by alkali rhyolitic rocks.c) Urla series, formed by alkali trachytes and alkali rhyolites, associated with scarce basic lavas of hawaiitic type. A different genesis is assumed for these series. In a first phase the latite-andesitic magma was formed by a partial melting in the lower crust or in the upper mantle. Afterwards a subcrustal magma with alkali basaltic affinity rose slowly through the crust forming an intermediate reservoir and differentiating predominantly towards alkali trachytic terms. Finally silicic magma of Izmir-Lebedos was formed by an anatectic process. It is possible that the fusion has been favoured by the presence of basic magma in the upper crust.     

LEVINSON INVERSION OF EARTHQUAKE GEOMETRY SH-TRANSMISSION SEISMOGRAMS IN THE PRESENCE OF NOISE*

The Kunetz-Claerbout equation for the acoustic transmission problem in a layered medium in its original form establishes the relation between the transmission and the reflec tion response for P-waves in an horizontally layered medium and with vertical incidence. It states that the reflection seismogram due to an impulsive source at the surface, is one side of the autocorrelation of the seismogram due to an impulsive source at depth and a surface receiver. By adapting Claerbout's formulation to the transmission of SH-waves, the Kunetz-Claerbout equation also holds for reflection and transmission coefficients dependent on the incident angle. Thus, earthquake geometry SH-transmission seismograms can be used to caculate corresponding pseudoreflection seismograms which, in turn, can be inverted for the impedance structure using the Levinson algorithm. If the average incidence angle is known, a geometrical correction on the resulting impedance model can improve the resolution of layer thicknesses. In contrast to the inversion of reflection seismograms, the Levinson algorithm is shown to yield stable results for the inversion of transmission seismograms even in the presence of additive noise. This noise stabilization is inherent to the Kunetz-Claerbout equation. Results of inverted SH-wave microearthquake seismograms from the Swabian Jura, SW Germany, seismic zone obtained at recording site Hausen im Tal have been compared with sonic-log data from nearby exploration drilling at Trochtelfingen. The agreement of the main structural elements is fair to a depth of several hundred metres.