Seasonal and spatial variations of water quality,substrate and aquatic macrophytes based on side scan sonar,in an eastern Mediterranean lagoon (Kaiafas,Ionian Sea)

Temporal and spatial variations of environmental and water quality parameters and their relations with macrobenthic flora were investigated in an eastern Mediterranean lagoon. Kaiafas is a mesohaline lagoon, which is influenced by point and diffused sources from the adjacent agricultural land and the nearby city. Water samples were analyzed for physicochemical parameters, microbial load and primary production, on a seasonal and spatial scale, while heavy metal concentrations were measured into two different sediment cores. An overall analysis of seasonal dynamics of water parameters and Chl-a based on trophic index TSI pointed out the lagoon as eutrophic. According to water quality parameters the lagoon was separated into two parts. The southern sector of the lagoon which was more affected by human activities showed higher nutrients, Chl-a, heavy metals and total Coliforms concentrations. Sediment texture and distribution of macrophytes were detected through the acoustic side scan sonar method, which proved to be a promising tool for defining and monitoring vegetation coverage of shallow lagoons. A number of distinct echo types and three different sediment types were revealed on the basis of the backscatter level and the variability of low and high backscatter areas. Furthermore, the extension and the coverage of Potamogeton pectinatus and Chara hispida f. corfuensis were successively depicted by combining the data of SSS and ground truthing samples. Meadows of P. pectinatus were established to the lagoon limits where high turbidity and silty substrate occurred, while C. hispida f. corfuensis was limited in deep and high transparent waters with sandy substrate.     

Seeing through porous media: An experimental study for unveiling interstitial flows

We describe a novel inexpensive method, utilizing particle image velocimetry (PIV) and refractive index‐matching (RIM) for visualizing and quantifying the flow field within bio‐amended porous media. To date, this technique has been limited to idealized particles, whose refractive index does not match that of fresh water and thus requires specialized and often toxic or hazardous fluids. Here, we use irregularly shaped grains made of hydrogel as the solid matrix and water as the fluid. The advantage of using water is that it provides, for the first time, the opportunity to study both hydraulic and biological processes, which typically occur in soils and streambeds. By using RIM coupled with PIV (RIM‐PIV), we measured the interstitial flow field within a cell packed with granular material consisting of hydrogel grains in a size range of 1–8 mm, both in the presence and in the absence of Sinorhizobium meliloti bacteria (strain Rm8530). We also performed experiments with fluorescent tracer (fluorescein) and fluorescent microbes (Shewanella GPF MR‐1) to test the capability of visualizing solute transport and microbial movements. Results showed that the RIM‐PIV can measure the flow field for both biofilm‐free and biofilm‐covered hydrogel grains. The fluorescent tracer injection showed the ability to visualize both physical (concave surfaces and eddies) and biological (biofilms) transient storage zones, whereas the fluorescent microbe treatment showed the ability to track microbial movements within fluids. We conclude that the proposed methodology is a promising tool to visualize and quantify biofilm attachment, growth, and detachment in a system closer to natural conditions than a 2D flow cell experiment.     

Air/water/sediment temperature contrasts in small streams to identify groundwater seepage locations

The need to identify groundwater seepage locations is of great importance for managing both stream water quality and groundwater sourced ecosystems due to their dependency on groundwater‐borne nutrients and temperatures. Although several reconnaissance methods using temperature as tracer exist, these are subjected to limitations related to mainly the spatial and temporal resolution and/or mixing of groundwater and surface water leading to dilution of the temperature differences. Further, some methods, for example, thermal imagery and fiber optic distributed temperature sensing, although relative efficient in detecting temperature differences over larger distances, these are labor‐intensive and costly. Therefore, there is a need for additional cost‐effective methods identifying substantial groundwater seepage locations. We present a method expanding the linear regression of air and stream temperatures by measuring the temperatures in dual‐depth; in the stream column and at the streambed‐water interface (SWI). By doing so, we apply metrics from linear regression analysis of temperatures between air/stream and air/SWI (linear regression slope, intercept, and coefficient of determination), and the daily water temperature cycle (daily mean temperatures, temperature variance, and the mean diel temperature fluctuation). We show that using metrics from only single‐depth stream temperature measurements are insufficient to identify substantial groundwater seepage locations in a head‐water stream. Conversely, comparing the metrics from dual‐depth temperatures show significant differences; at groundwater seepage locations, temperatures at the SWI merely explain 43–75% of the variation opposed to ? 91% at the corresponding stream column temperatures. In general, at these locations at the SWI, the slopes ( < 0.25) and intercepts ( > 6.5 °C) are substantially lower and higher, respectively, while the mean diel temperature fluctuations ( < 0.98 °C) are decreased compared to remaining locations. The dual‐depth approach was applied in a post‐glacial fluvial setting, where metrics analyses overall corroborated with field measurements of groundwater fluxes and stream flow accretions. Thus, we propose a method reliably identifying groundwater seepage locations along streambeds in such settings.     

Radium isotopes in river sediments of Czech Republic

In the Czech Republic, river bottom sediments have been systematically monitored since 1999. In the paper, their radioactive contamination due to uranium mining and milling is assessed. The sediments samples were analyzed by gamma spectrometry. Especially the radium-226 and radium-228 activities were further evaluated.The highest values of the radium-226 activities were found at river profiles where the uranium industry impact was obvious. It turned out that the radium-226 and radium-228 activities ratio is more convenient to assess the level of radium-226 contamination than only the radium-226 activity itself. Based on this hypothesis, the sediment classification scheme for uranium industry contamination was suggested. The natural background activities of radium-226 and radium-228 in the Czech Republic were also evaluated. The case of radium-226 contamination due to the uranium industry was studied in details at the Ploučnice River.     

On Some Aspects of the Inversion Problem of Magnetostatics

Debye potentials and vector spherical harmonics were applied to a magnetostatic problem. By these mathematical methods it is shown that the inverse problem of the magnetostatics cannot be solved though the divergence of vector M is given.     

Adjusted Daily Rainfall and Snowfall Data for Canada

This article documents how Environment and Climate Change Canada’s Adjusted Daily Rainfall and Snowfall (AdjDlyRS) dataset was developed. The adjustments include (i) conversion of ruler measurements of snowfall to its water equivalent using a previously developed snow water equivalent (SWE) ratio map for Canada; (ii) corrections for gauge-related issues including undercatch and evaporation caused by wind effects and gauge-specific wetting loss, as well as for trace precipitation amounts, using previously developed procedures for Canada. Various data flags (e.g., accumulation flags) were also treated. This dataset contains all Canadian stations reporting daily rainfall and snowfall for which we have metadata to implement the adjustments. The length of the data record varies from one station to another, starting as early as 1840. The results show that the original unadjusted total precipitation data in Environment and Climate Change Canada’s digital archive underestimate the total precipitation in northeastern Canada by more than 25% and by about 10–15% in most of southern Canada. Such large underestimates make the original data unsuitable for water availability and/or balance studies or for numerical model validation, among many other applications. The use of the assumed 10:1 SWE ratio for the archived total precipitation data is the primary cause of the underestimate, which is most severe in northeastern Canada. The trace correction adds 5–20% to precipitation values in northern Canada but less than 5% in southern Canada. The gauge-related corrections do not show an organized spatial pattern but add 5–10% to the precipitation at 312 stations. Long runs (≥3 months) of miscoded missing values were also identified and corrected.

The latest version of the AdjDlyRS dataset is available from the Canadian Open Data Portal; currently it is version 2016, which contains 3346 stations and covers the period from station inception to February 2016. This dataset is suitable for producing gridded precipitation datasets, as well as other applications.     

Sensitivity of the Eastern Mediterranean geomorphic system towards environmental change during the Late Holocene: a chronological perspective

Alluvial and colluvial sediment deposition provide a vital record of environmental change during the Holocene. Firm chronological control on these archives is necessary to enable us to relate sediment dynamics to human activity and climate variability. In the Eastern Mediterranean, such relationships are hard to establish due to the lack of spatially well‐distributed sediment archives with good chronological control. This scarcity is problematic with respect to regional‐scale reconstructions of the temporal variation of sediment dynamics. Here, we present a radiocarbon database (n = 178) of geomorphological activity collected from multiple distinct sediment archives within the territory of Sagalassos in south‐western Turkey. The data were grouped according to their sedimentary facies for analysis using cumulative probability distributions (CPDs) and sedimentation rate (SR) modelling. Two small‐scale colluvial valleys, where chronological information was abundant, were investigated in more detail. Results show that sedimentation chronology differs between individual, nearby cores, as it depends strongly on the local geomorphic situation. A generalizing approach combining multiple core results yields more widely valid conclusions. High sedimentation rates coincided with the initial major anthropogenic disturbance of the landscape and decreased afterwards, probably due to hillslope soil depletion. CPD and SR analysis indicates that in general colluvial sedimentation rates did not change much from 2000 BC onwards. River floodplain sedimentation, in contrast, increased markedly during the first millennium BC and during recent times, and a significant time lag in enhanced sediment deposition between the upper and lower reaches of the river valleys was observed. Copyright © 2012 John Wiley & Sons, Ltd.     

On local structural changes in lizardite-1T: {Si4+/Al3+}, {Si4+/Fe3+}, [Mg2+/Al3+], [Mg2+/Fe3+] substitutions

Geometrical changes induced by cation substitutions {Si⁴⁺/Al³⁺}[Mg²⁺/Al³⁺], {2Si⁴⁺/2Al³⁺} [2Mg²⁺/2Al³⁺], {Si⁴⁺/Fe³⁺} [Mg²⁺/Al³⁺] or [Mg²⁺/Fe³⁺], where {} and [] indicate tetrahedral and octahedral sheet in lizardite 1T, are studied by ab-initio quantum chemistry calculations. The majority of the models are based on the chemical compositions reported for various lizardite polytypes with the amount of Al in the tetrahedral sheets reported to vary from 3.5% to 8% in the 1T and 2H ₁, up to ~30% in the 2H ₂ polytype. Si⁴⁺ by Fe³⁺ substitution in the tetrahedral sheet with an Al³⁺ (Fe³⁺) in the role of a charge compensating cation in the octahedral sheet is also examined. The cation substitutions result in the geometrical changes in the tetrahedral sheets, while the octahedral sheets remain almost untouched. Substituted tetrahedra are tilted and their basal oxygens pushed down from the plane of basal oxygens. Ditrigonal deformation of tetrahedral sheets depends on the substituting cation and the degree of substitution.     

DFT study of Rb-TFA structure after high-pressure action

The pressure-induced A-B phase transition of synthetic Rb-tetra-ferri-annite (Rb-TFA) mica was studied theoretically by means of Density Functional Theory (DFT) method. The calculations show that Rb-TFA keeps a Franzini A-type structure up to at least 5.39 GPa of pressure, whereas at higher pressure, it transforms to a Franzini B-type structure. The negative value of the tetrahedral rotation angle α = −4.68° has appeared at 5.56 GPa of calculated pressure. This result is in a relatively good agreement with experimentally estimated phase transition area in the range of 3.36−3.84 GPa. The energy difference between the A and B structures is very small (ΔE = 8 kJ/mol). The detailed analysis of the optimized structural data shows minimal changes in the structure of Rb-TFA after the pressure-induced phase transition.     

An empirical solvus for CO2-H2O-2.6 wt% salt

The solvus in the system CO₂-H₂O-2.6 wt% NaCl-equivalent was determined by measuring temperature of homogenization in fluid inclusions which contained variable $\text{CO}{}_2\text{H}{}_2\text{O}$ but the same amount of salt dissolved in the aqueous phase at room temperature. The critical point of the solvus is at 340 ± 5°C, at pressures between 1 and 2 kbar; this is about 65°C higher than for the pure CO₂-H₂O system. The solvus is assymetrical, with a steeper H₂O-rich limb and with the critical point at mole fraction of water between 0.65 and 0.8.