Seasonal variations in groundwater upwelling zones in a Danish lowland stream analyzed using Distributed Temperature Sensing (DTS)

The distribution of groundwater inflows in a stream reach plays a major role in controlling the stream temperature, a vital component shaping the riverine ecosystem. In this study, the Distributed Temperature Sensing (DTS) system was installed in a small Danish lowland stream, Elverdamsåen, to assess the seasonal dynamics of groundwater inflow zones using high spatial (1 m) and temporal (3 minutes) resolution of water temperature measurements. Four simple criteria consisting of 30 min average temperature at 16:00, mean and standard deviation of diurnal temperatures, and the day–night temperature difference were applied to three DTS datasets representing stream temperature responses to the variable meteorological and hydrological conditions prevailing in summer, winter and spring. The standard deviation criterion was useful to identify groundwater discharge zones in summer and spring conditions, while the mean temperature criterion was better for the winter conditions. In total, 20 interactions were identified from the DTS datasets representing summer, 16 in winter and 19 in spring, albeit with only two interactions contributing in all three seasons. Higher baseflow to streamflow ratio, antecedent precipitation and presence of fractured clayey till in the stream reach were deemed as the vital factors causing apparent seasonal variation in the locations of upwelling zones, prompting use of DTS not only in preconceived scenarios of large diurnal temperature change but rather a long‐term deployment covering variable meteorological and hydrological scenarios. Copyright © 2012 John Wiley & Sons, Ltd.     

Physiological responses to copper in giant clams: a comparison of two methods in revealing effects on photosynthesis in zooxanthellae

In the present work physiological responses to a short term, sub-lethal exposure to copper (5 microg Cu2 l(-1) were studied on two species of giant clams, Tridacna gigas and Hippopus hippopus. All giant clams (fam. Tridacnidae) maintain a symbiotic relationship with photo-synthesising microalgae (zooxanthellae) and the phytotoxic effects of this copper concentration were approached with two different end points: changes in oxygen production and maximal quantum yield (Fv/Fm). Additionally we measured respiration, whereby Pg:R ratios could be calculated for the system (algae and clam) and used as an indicator of stress. Cu accumulation was only determined for T. gigas and showed significantly higher tissue concentrations in exposed specimens (11.3 microg Cu g(-1) dry wt) compared to the controls (4.2 microg Cu g(-1)). Both species displayed significantly reduced Pg:R ratios due to exposure, mainly explained by lowered gross production. No indication of stress was shown in the fluorescence measurements and possible explanations are discussed in the paper. We propose that inhibitions in the slow kinetics of photosynthesis were not captured by this fluorescence parameter. Accordingly we suggest that measurements of maximum fluorescence yield should be accompanied by complementary parameters when studying pollutants with unclear phytotoxic mechanisms.     

Time-series of δ26Mg values in a headwater catchment reveal decreasing magnesium isotope variability from precipitation to runoff

Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg²⁺ in catchment runoff. We report the first annual time-series of δ²⁶Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ²⁶Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ²⁶Mg values of throughfall (−0.73‰), but significantly different from the δ²⁶Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ²⁶Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ²⁶Mg values of Mg²⁺ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ²⁶Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ²⁶Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.     

Evidence of early deglaciation (18 000 cal a bp) and a postglacial relative sea‐level curve from southern Karmøy,south‐west Norway

Based on six consistent radiocarbon dates from the isolation basins Grødheimsvatnet and Kringlemyr, we estimate a minimum deglaciation age for southern Karmøy, an island in outer Boknafjorden (south‐west Norway), of around 18 000 calibrated years before present (18k cal a bp ). We use microscopic phytoplankton, macrofossils, lithostratigraphic evidence and X‐ray fluorescence data to identify the isolation contacts in the basins, and date them to 17.52–17.18k cal a bp in Grødheimsvatnet [15.57 m above present mean sea level (MSL)] and 16.19–15.80k cal a bp in Kringlemyr (11.99 m above MSL). Combining these data with previous studies, we construct a relative sea‐level (RSL) curve from 18k cal a bp until the present, which is ~3 ka longer than any previous RSL reconstruction from southern Norway. Following deglaciation, southern Karmøy has experienced a net emergence of around 16–19 m, although with significant RSL fluctuations. This includes two RSL minima well below present MSL around ~13.8 and ~10k cal a bp , and two maxima that culminated around 5–7 m above MSL during the Younger Dryas and early to mid‐Holocene, respectively. Considering eustatic sea level and modelled gravitational deformation of the geoid, we estimate a net postglacial isostatic uplift of ~120 m. © 2019 John Wiley & Sons, Ltd     

Total hydrocarbons,polycyclic aromatic hydrocarbons and synthetic organic compounds in the Hard shell clam, Mercenaria mercenaria, purchased at commercial seafood stores

An analytical method for the determination of polycyclic aromatic h hydrocarbons (PAHs) and substituted benzotriazoles in clams was developed using a combination of silica gel and Sephadex chromatography to isolate these compounds from large concentrations of polyolefinic hydrocarbons. The concentrations of total hydrocarbons, PAHs and substituted benzotriazoles were measured in hard shell clams (Mercenaria mercenaria) purchased from Rhode Island seafood stores. The levels of total hydrocarbons, PAHs and substituted benzotriazoles in these clams were generally higher than the concentrations found in clams collected from a lower Narragansett Bay control location. The significance of these findings on the health of consumers is unknown at this time because human health standards or alert levels for these compounds in seafoods have not been established. However, this study illustrates that contaminants entering Narragansett Bay from a variety of sources may eventually make their way to commercial outlets.     

Trace metals in sediment cores from Deception and Penguin Islands (South Shetland Islands, Antarctica)

This paper presents information on the levels of trace elements in sediments collected at Deception and Penguin Islands and tracks the sources of natural and anthropogenic inputs of metals into this sub-Antarctic region. The results suggest that natural processes, such as volcanic activity, hydrothermal processes and sediment transport, are more important than anthropogenic inputs in accounting for the metal concentrations measured in sediments at Deception Island. The higher levels of trace metals recorded in sediments at Penguin Island seem to reflect the composition of the source rocks of the island, which are dominated by the olivine-basalt group. Our findings show that human activities in the study areas may contribute to negligible levels of trace metals associated with anthropogenic inputs (e.g., Cr and Zn) in sediments, and these results can be used in the future as background levels related to low anthropogenic impacts.     

Variation in transparent exopolymer particles in relation to biological and chemical factors in two contrasting lake districts

In inland waters, transparent exopolymer particles (TEP) can affect carbon export and sequestration in sediments with consequences for lake C budgets. We measured TEP concentration in 32 lakes from two contrasting lake districts covering wide ranges in biological and chemical characteristics. North temperate lakes, located in a wet region, have low to moderate ionic strength and low to high dissolved organic carbon with corresponding variation in color (light absorbance). Mediterranean lakes located in a semiarid region were characterized by high ionic strength and high concentrations of dissolved organic carbon but low color. TEP concentrations were large relative to the living portion of the particulate organic carbon pool in both Mediterranean (36%) and north temperate (33%) lakes. TEP concentrations ranged from 36 to 1,462 μg [as Gum Xanthan equivalents (GX eq)] L⁻¹ in north temperate lakes. In the Mediterranean lakes, concentrations were higher that previously reported for other systems and ranged from 66 to 9,038 μg GX eq L⁻¹. TEP concentration was positive and significantly related to chlorophyll a (chl a) in north temperate lakes and in the entire data set. Although a significant and positive relationship between TEP and chl a was also detected in the Mediterranean lakes, bacterial abundance was most strongly related to TEP. In contrast with the positive influence of phytoplankton and bacteria on TEP, there were weaker relationships between TEP and the chemical variables tested. We observed a significant and positive relationship between pH and TEP (for all lakes) but this relationship was indirectly driven by a co-variation of pH with phytoplankton biomass based on multiple regression analysis. For the Mediterranean lakes, the negative (but not significant) trends between TEP and both conductivity and divalent cations suggest thresholds above which TEP will likely be destabilized. Under these conditions, TEP may flocculate or disperse in the water column.     

Attitudes toward climate change mitigation policies: a review of measures and a construct of policy attitudes

Research on policy support or public acceptability of climate change policies is proliferating. There is, however, a great diversity in how these evaluative responses have been defined, operationalized, and measured across studies. In order to shed some light on this subject, we reviewed 118 studies published over the last 15 years aiming at measurement of policy acceptability, acceptance, support, and other responses to climate change mitigation policies. We found that conceptual vagueness and weak theoretical embedding are pervasive in the field, which leads to uncertainty over what is being measured, ambiguity of policy recommendations, and difficulties in comparing empirical results. In response, we propose a construct of policy attitudes as an overarching concept comprising the diversity of measures and constructs already in use. The purpose of the construct is to serve as a common basis for operationalization and survey design. In order to inform policy makers, researchers should be clear in how they formulate surveys with a focus on questions of importance to research and policy-making.

Key policy insights

• Acceptability, acceptance, and support are defined as distinct and possibly empirically distinguishable classes of responses evaluating a policy proposal. These responses are expressions of underlying policy attitudes.

• People may respond to policies in other ways as well, including lack of interest.

• There is no popularity threshold for a policy to be safe to implement, but instead it is a matter of identifying the conditions of policy support or other responses.

• Results obtained using different measures of mitigation policy attitudes vary widely with respect to the characteristics of the policy in question and the measured response. Thus, great care must be taken when designing surveys and interpreting their results.

     

A statistical-mechanics model of ordering in aluminosilicate solid solutions

A statistical-thermodynamic approximation for order-disorder phase transitions in aluminosilicate solid solutions is presented. The approximation involves estimating the number of configurations with long range order parameter Q and short range order parameter σ, using an approximation to the probability that a configuration with the correct amount of long range order will also have the correct amount of short range order. This estimate is then used to give a free energy F(Q, σ, x, T), where x is the concentration of Al in the structure, and hence quantities such as T _c (x) are estimated. The predictions of the model for T _c (x) and the critical concentration x _c at which T _c falls to zero are shown to be in good agreement with the results of Monte Carlo simulations. Received: 14 May 1997 / Revised, accepted: 2 June 1997