Thermal alteration experiments on organic matter in recent marine sediment—II. Isoprenoids

Several isoprenoid compounds were isolated from a heat-treated marine sediment in the southern California continental shelf (from Tanner Basin) which were not present in the original sediment. Among the compounds identified were: phytol, dihydrophytol, C₁₈-isoprenoid ketone, phytanic and pristanic acids, C₁₉- and C₂₀-monoolefins, and the alkanes 2,6,10-trimethylpentadecane, pristane and phytane. The significance and possible routes leading to these compounds is discussed.     

Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.     

The meteorological framework and the cultural memory of three severe winter-storms in early eighteenth-century Europe

Three violent eighteenth-century storms that ravaged the North Sea area (1703), western central Europe (1739) and Portugal (1739) are investigated from the point of view of their meteorological setting, their socio-economic impact, and whether and by what means they secured an enduring place in the cultural memory. The evidence draws on individual narrative sources such as chronicles and poems, and institutional sources such as ship’s logbooks and state-organised ‘windthrow’ inventories of tree loss. Each of the three storms had socio-economic impacts that could be described as ‘war-like’ in the damage caused to buildings and the destruction of forests. The “Great Storm” of December 1703 jeopardized English naval supremacy in the War of the Spanish Succession by sinking a number of Royal Navy ships and taking the life of more than 8000 seamen. In January 1739 two similarly destructive storms swept over mainland Europe. The cultural memory of the three events here considered was however strikingly different. The sequence of storms in January 1739 though being the most protracted of the last centuries, and well-chroniceled, did not persist in the collective memories of those in France, Switzerland and elsewhere who experienced them. Likewise, the “Great Storm” was quickly forgotten on the continent, whereas its memory remained deeply rooted in England through the writings of Defoe (1704). In Portugal the 1739 storm won a lasting place in the country’s cultural memory owing to two poems that it inspired. Furthermore, it was recorded in the Kingdom’s official newspaper, in the astronomical prognoses and in written records of the Old Regime’s cultural elite.     

On the long-term context of the 1997–2009 ‘Big Dry’ in South-Eastern Australia: insights from a 206-year multi-proxy rainfall reconstruction

This study presents the first multi-proxy reconstruction of rainfall variability from the mid-latitude region of south-eastern Australia (SEA). A skilful rainfall reconstruction for the 1783–1988 period was possible using twelve annually-resolved palaeoclimate records from the Australasian region. An innovative Monte Carlo calibration and verification technique is introduced to provide the robust uncertainty estimates needed for reliable climate reconstructions. Our ensemble median reconstruction captures 33% of inter-annual and 72% of decadal variations in instrumental SEA rainfall observations. We investigate the stability of regional SEA rainfall with large-scale circulation associated with El Niño–Southern Oscillation (ENSO) and the Inter-decadal Pacific Oscillation (IPO) over the past 206 years. We find evidence for a robust relationship with high SEA rainfall, ENSO and the IPO over the 1840–1988 period. These relationships break down in the late 18th–early 19th century, coinciding with a known period of equatorial Pacific Sea Surface Temperature (SST) cooling during one of the most severe periods of the Little Ice Age. In comparison to a markedly wetter late 18th/early 19th century containing 75% of sustained wet years, 70% of all reconstructed sustained dry years in SEA occur during the 20th century. In the context of the rainfall estimates introduced here, there is a 97.1% probability that the decadal rainfall anomaly recorded during the 1998–2008 ‘Big Dry’ is the worst experienced since the first European settlement of Australia.     

Nitrous oxide emissions from gasohol, ethanol and CNG light duty vehicles

A sample of 21 light duty vehicles powered by Otto cycle engines were tested on a chassis dynamometer to measure the exhaust emissions of nitrous oxide (N₂O). The tests were performed at the Vehicle Emission Laboratory of CETESB (Environmental Company of the State of Sao Paulo) using the US-FTP-75 (Federal Test Procedure) driving cycle. The sample tested included passenger cars running on three types of fuels used in Brazil: gasohol, ethanol and CNG. The measurement of N₂O was made using two methods: Non Dispersive InfraRed (NDIR) analyzer and Fourier Transform InfraRed spectroscopy (FTIR). Measurements of regulated pollutants were also made in order to establish correlations between N₂O and NO_x. The average N₂O emission factors obtained by the NDIR method was 78?±?41?mg.km^?1 for vehicles running with gasohol, 73?±?45?mg.km^?1 for ethanol vehicles and 171?±?69?mg.km^?1 for CNG vehicles. Seventeen results using the FTIR method were also obtained. For gasohol vehicles the results showed a good agreement between the two methods, with an average emission factor of 68?±?41?mg.km^?1. The FTIR measurement results of N₂O for ethanol and CNG vehicles were much lower than those obtained by the NDIR method. The emission factors were 17?±?10?mg.km^?1 and 33?±?17?mg.km^?1, respectively, possibly because of the interference of water vapor (present at a higher concentration in the exhaust gases of these vehicles) on measurements by the NDIR method.     

Science-based approach for credible accounting of mitigation in managed forests

Background

The credibility and effectiveness of country climate targets under the Paris Agreement requires that, in all greenhouse gas (GHG) sectors, the accounted mitigation outcomes reflect genuine deviations from the type and magnitude of activities generating emissions in the base year or baseline. This is challenging for the forestry sector, as the future net emissions can change irrespective of actual management activities, because of age-related stand dynamics resulting from past management and natural disturbances. The solution implemented under the Kyoto Protocol (2013–2020) was accounting mitigation as deviation from a projected (forward-looking) “forest reference level”, which considered the age-related dynamics but also allowed including the assumed future implementation of approved policies. This caused controversies, as unverifiable counterfactual scenarios with inflated future harvest could lead to credits where no change in management has actually occurred, or conversely, failing to reflect in the accounts a policy-driven increase in net emissions. Instead, here we describe an approach to set reference levels based on the projected continuation of documented historical forest management practice, i.e. reflecting age-related dynamics but not the future impact of policies. We illustrate a possible method to implement this approach at the level of the European Union (EU) using the Carbon Budget Model.

Results

Using EU country data, we show that forest sinks between 2013 and 2016 were greater than that assumed in the 2013–2020 EU reference level under the Kyoto Protocol, which would lead to credits of 110–120 Mt CO₂/year (capped at 70–80 Mt CO₂/year, equivalent to 1.3% of 1990 EU total emissions). By modelling the continuation of management practice documented historically (2000–2009), we show that these credits are mostly due to the inclusion in the reference levels of policy-assumed harvest increases that never materialized. With our proposed approach, harvest is expected to increase (12% in 2030 at EU-level, relative to 2000–2009), but more slowly than in current forest reference levels, and only because of age-related dynamics, i.e. increased growing stocks in maturing forests.

Conclusions

Our science-based approach, compatible with the EU post-2020 climate legislation, helps to ensure that only genuine deviations from the continuation of historically documented forest management practices are accounted toward climate targets, therefore enhancing the consistency and comparability across GHG sectors. It provides flexibility for countries to increase harvest in future reference levels when justified by age-related dynamics. It offers a policy-neutral solution to the polarized debate on forest accounting (especially on bioenergy) and supports the credibility of forest sector mitigation under the Paris Agreement.

     

Role of reservoir regulation and groundwater feedback in a simulated ground-soil-vegetation continuum: A long-term regional scale analysis

The regional terrestrial water cycle is strongly altered by human activities. Among them, reservoir regulation is a way to spatially and temporally allocate water resources in a basin for multi-purposes. However, it is still not sufficiently understood how reservoir regulation modifies the regional terrestrial- and subsequently, the atmospheric water cycle. To address this question, the representation of reservoir regulation into the terrestrial component of fully coupled regional Earth system models is required. In this study, an existing process-based reservoir network module is implemented into NOAH-HMS, that is, the terrestrial component of an atmospheric–hydrologic modelling system, namely, the WRF-HMS. It allows to quantitatively differentiate role of reservoir regulation and of groundwater feedback in a simulated ground-soil-vegetation continuum. Our study focuses on the Poyang Lake basin, where the largest freshwater lake of China and reservoirs of different sizes are located. As compared to streamflow observations, the newly extended NOAH-HMS slightly improves the streamflow and streamflow duration curves simulation for the Poyang Lake basin for the period 1979–1986. The inclusion of reservoir regulation leads to major changes in the simulated groundwater recharges and evaporation from reservoirs at local scale, but has minor effects on the simulated soil moisture and surface runoff at basin scale. The performed groundwater feedback sensitivity analysis shows that the strength of the groundwater feedback is not altered by the consideration of reservoir regulation. Furthermore, both reservoir regulation and groundwater feedback modify the partitioning of the simulated evapotranspiration, thus affecting the atmospheric water cycle in the Poyang Lake region. This finding motivates future research with our extended fully coupled atmospheric–hydrologic modelling system by the community.