Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

Endolithic biodegradation of cool-water skeletal carbonates on Scott shelf, northwestern Vancouver Island, Canada

Biodegradation of shell material is widespread in the cool-water skeletal carbonate deposits on Scott shelf, northwestern Vancouver Island, and is especially evident in the large aragonitic bivalves, Glycymeris and Humilaria, major primary sediment contributors. Ten types of endolithic microborings have been identified in the shells, including representatives of green algae (e.g., Ostreobium quekettii), blue-green algae (e.g., Plectonema terebrans, ?Scytonema sp.), fungi, bacteria and clionid sponges, as well as macroborings of phoronids, polychaetes and naticid gatropods. Microcrystalline carbonate is not precipitated in vacated bores. Boring physically weakens the shells, rendering them more prone to mechanical abrasion during sediment transport and bioturbation, and to biological abrasion by grazing benthos. Tumbling experiments demonstrate that the rate of carbonate mud production is much greater for bored as compared to fresh bivalve shells, and that mud production rates decrease with tumbling time because most endolithic microborings are confined to the periphery of grains. Boring also increases significantly the porosity and surface area of skeletal grains, and destroys their organic matrix, making them susceptible to maceration and dissolution on cool-water shelves. Fostered by the generally low rates of carbonate production and accumulation, many aragonitic bivalve shells on Scott shelf have become thoroughly degraded through a combination of endolithic microboring, maceration and dissolution within about 1000 years in ambient sea water. In geologic terms, such selective taphonomic loss of skeletal material may be considerable in ancient temperate-shelf limestones and should be evaluated when interpreting their paleoecology and paleoenvironments.     

Impact of storm runoff from tropical watersheds on coastal water quality and productivity

Storm runoff in the steep watersheds in Hawaii leads to sediment and freshwater pulses to coastal waters that quickly affect nearshore water quality. This is particularly true in semi-enclosed embayments, such as Kaneohe Bay, Oahu, where water has a relatively long residence time compared to more open coastal areas of the islands. In this paper the authors discuss water quality and productivity in Kaneohe Bay after back-to-back rain events in late November and early December 2003, following a particularly dry summer. The short-term biogeochemical response of coastal waters and the ecosystem to runoff and physical forcing was evaluated through a combination of continuous in situ measurements and adaptive synoptic sampling carried out on a variety of temporal and spatial scales.     

Constraining Holocene 10Be production rates in Greenland

The absence of a production rate calibration experiment on Greenland has limited the ability to link ¹⁰Be exposure dating chronologies of ice‐margin change to independent records of rapid climate change. We use radiocarbon age control on Holocene glacial features near Jakobshavn Isbræ, western Greenland, to investigate ¹⁰Be production rates. The radiocarbon chronology is inconsistent with the ¹⁰Be age calculations based on the current globally averaged ¹⁰Be production rate calibration data set, but is consistent with the ¹⁰Be production rate calibration data set from north‐eastern North America, which includes a calibration site nearby on north‐eastern Baffin Island. Based on the best‐dated feature available from the Jakobshavn Isbræ forefield, we derive a ¹⁰Be production rate value of 3.98 ± 0.24 atoms g a^?1, using the ‘St’ scaling scheme, which overlaps with recently published reference ¹⁰Be production rates. We suggest that these ¹⁰Be production rate data, or the very similar data from north‐eastern North America, are used on Greenland. Copyright © 2011 John Wiley & Sons, Ltd.     

Shear strength and compressibility of oyster shell–sand mixtures

This paper investigates the fundamental characteristics of shear strength and deformation of crushed oyster shell–sand mixtures to stimulate recycling of waste oyster shells. Standard penetration tests (SPT) and large-scale direct-shear tests were carried out with different kinds of dry unit weight and mixing rate of oyster shell–sand mixture. Correlations between N-value, dry unit weight, and friction angle of mixtures were observed from the results of experimental tests, making it possible to estimate the in situ strength from SPT, and the coefficient of volume compressibility from the confined direct-shear compression test. These results also make it possible to compute the settlement of oyster shell–sand mixture when used in soft ground improvement.     

Significance of river–aquifer interactions for reach-scale thermal patterns and trout growth potential in the Motueka River, New Zealand

To assess whether reaches of the Motueka River (New Zealand) that gain water from groundwater were likely to represent significant cold-water refugia for brown trout during periods of high water temperatures, water temperature was monitored for more than 18 months in two gaining reaches of the Motueka River and three reaches that were predicted to be losing water to groundwater. These data were used to predict brown trout (Salmo trutta) growth in gaining and losing reaches. Groundwater inputs had a small effect on water temperature at the reach-scale and modelling suggests that the differences observed were unlikely to result in appreciable differences in trout growth. Several coldwater patches were identified within the study reach that were up to 3.5°C cooler than the mainstem, but these were generally shallow and were unlikely to provide refuge for adult trout. The exception was Hinetai Spring, which had a mean water temperature of close to 16°C during the period January–March, when temperatures in the mainstem regularly exceeded 19°C. Trout were observed within the cold-water plume at the mouth of Hinetai Stream, which would allow them to thermoregulate when mainstem temperatures are unfavourable while still being able to capitalise on food resources available in the mainstem.     

Collectorless flotation of chalcopyrite and sphalerite ores by using sodium sulfide

The flotation of chalcopyrite and sphalerite from copper and copper-zinc ores has been achieved without using thiol-type collectors. Typically, a sulfide ore sample is first treated with sodium sulfide either during grinding or during the preflotation conditioning period, and then the chalcopyrite is floated with frother alone. With a copper-zinc ore, sphalerite is subsequently floated from the chalcopyrite tailings by activating it with copper sulphate. Results of the collectorless flotation tests are comparable to those obtained by using thiol collectors. The mechanisms of selective collectorless flotation are discussed on the basis of differences in the solubilities of sulfide minerals.