Formation of corundum megacrysts during H<Subscript>2</Subscript>O-saturated incongruent melting of feldspar: P–T pseudosection-based modelling from the Skattøra migmatite complex,North Norwegian Caledonides

Corundum megacryst-bearing rocks associated with the high-pressure migmatites of the Skattøra migmatite complex (SMC) belonging to the Nakkedal Nappe Complex, North Norwegian Caledonides, display a classical example of incongruent melting of plagioclase under water-saturated conditions. Petrography and micro-textures suggest that several centimetre long corundum megacrysts formed from the silicate melt along with amphibole (pargasite) and plagioclase (X_An ~ 0.47). The corundum-bearing leucosomes are rich in biotite compared to the other mafic units of SMC. Locally, margarite occurs in coronas around corundum megacrysts. Geochemically, the corundum-bearing rocks are enriched in Al, K, Rb and Ba and depleted in Fe, Mg and Ca compared to the leucogabbroic host rock. A P–T pseudosection of the leucogabbro indicates that feldspar breakdown and corundum formation occurred at temperatures >850 °C and pressure >1.2 GPa. The calculated equilibrium P–T of the corundum-bearing rock corresponds to 750–825 °C and 0.9–1.1 GPa. The P–T pseudosection of margarite indicates that margarite formed after cooling and decompression to P–T conditions corresponding to 600 °C at 0.5 GPa. Based on geochemical and mineral chemical analysis coupled with thermodynamic modelling, we suggest that formation of corundum occurred as a result of high-pressure incongruent melting of plagioclase in the presence of a K-, Rb- and Ba-rich external fluid. It is also suggested that the external fluid transported out portions of Ca, Fe and Mg, resulting in an increase of the peraluminousity of the melt and promoting further growth of corundum.     

Relationships and evolving networks of rural manufacturing clusters: A case study in Yucheng County, Henan Province of China

The evolution of networks in rural industrial clusters,in particular in the context of China has been paid more attention to in the world.Applying the theory and techniques of social network analysis (SNA),this study is with particular regard to the business network relationships and their evolutionary dynamics of steel measuring tape manufacturing clustered in Nanzhuang Village,Yucheng County of Henan Province,China,which is important for better understanding the industrial and regional development in less developed rural areas.From data collected by comprehensive questionnaire survey in 2002 and mass interviews with 60 enterprises and assembling families and several government authorities in 2002,2003,2004,2005 and 2008,four types of networks are identified: spin-off,consulting,communication and cooperative.The characteristic of these networks is outlined in detail.Compared with the high-tech clusters of typical developed areas,the networks that have evolved in traditional manufacturing clusters are more affected by emotive linkages.The cluster networks are shown to exhibit a polycentric hierarchical structure.The family relationships are the dominate spin-off channels of enterprises,while the supply and demand relationships and the mobility of the skilled workers are also important paths of network learning,and the cooperation relationships are comparatively stable.Besides the root enterprises,the middle-sized enterprises are comparatively more active than small-sized enterprises,and the intermediary agencies and the service institutions act as bridges of the inter-enterprises cooperation.By analysis of the structure of networks and the interactions between the networks,the four stages of network evolution are also identified.The four stages are dominated by the family networks,the internal division production networks,the local innovation networks and the global supply networks respectively,and they play different roles in cluster development.     

Relations between static and dynamic moduli of sedimentary rocks

Static moduli of rocks are usually different from the corresponding dynamic moduli. The ratio between them is generally complex and depends on several conditions, including stress state and stress history. Different drainage conditions, dispersion (often associated with pore fluid effects), heterogeneities and strain amplitude, are all potential reasons for this discrepancy. Moreover, comparison of static and dynamic moduli is often hampered and maybe mistaken due to insufficient characterization of anisotropy. This paper gives a review of the various mechanisms causing differences between static and dynamic moduli. By careful arrangements of test conditions, it is possible to isolate the mechanisms so that they can be studied separately. Non-elastic deformation induced by the large static strain amplitudes is particularly challenging, however a linear relationship between non-elastic compliance and stress makes it possible to eliminate also this effect by extrapolation to zero strain amplitude. To a large extent, each mechanism can be expressed mathematically with reasonable precision, thus quantitative relations between the moduli can be established. This provides useful tools for analyses and prediction of rock behaviour. For instance, such relations may be used to predict static stiffness and even strength based on dynamic measurements. This is particularly useful in field situations where only dynamic data are available. Further, by utilizing the possibility for extrapolation of static measurements to zero strain amplitude, dispersion in the range from seismic to ultrasonic frequencies may be studied by a combination of static and dynamic measurements.     

Evaluation and Influence Factor of Green Efficiency of China's Agricultural Innovation from the Perspective of Technical Transformation

Agricultural innovation is important for the green transformation of agriculture. Based on the perspective of technology transformation, this paper builds a theoretical analysis framework and evaluation index system for green efficiency of agricultural innovation,and discusses the evolution laws and influencing factors of the green efficiency of China's agricultural innovation from 2005 to 2017 utilizing the DEA model, Malmquist index, and Tobit regression analysis. The results show that: 1) The overall green efficiency of China's agricultural innovation is not high, the green efficiency of agricultural innovation in eastern China is mainly driven by pure technical efficiency, while that in central and western China is mainly driven by the scale efficiency. The green efficiency of agricultural innovation shows significant spatial differences, and the low efficiency and relatively low-efficiency regions moved to central and southeastern China. 2) Technical progress is the main force affecting the change of green total factor productivity of China's agricultural innovation, seeing a trend of decrease followed by an increase. Pure technical efficiency and scale efficiency exhibit an increasing-decreasing trend, and gradually transform into key factors that restrict the improvement of the green total factor productivity of agricultural innovation. 3) Agricultural technologies' diffusion, absorption, and implementation are three influencing factors of the green efficiency of agricultural innovation. The local level of informatization, the number of agricultural technicians in enterprises and institutions, average education level of residents, and the level of agricultural mechanization have positive impacts on the promotion of the green efficiency of agricultural innovation, promoting the diffusion, absorption and implementation of agricultural innovation technology can significantly improve the green efficiency of agricultural innovation.     

水力喷射微小井眼技术用于海域水合物钻探的可行性分析

天然气水合物具有储量丰富、清洁高效的特点,世界各国非常重视天然气水合物资源的调查和开采工作,我国在2017年顺利实施了海域天然气水合物直井试采工作,并取得了丰硕的成果。水力喷射微小井眼技术是一项正在兴起的新型钻探技术,已经在石油钻探中得到了一定的应用,将其应用到海域天然气水合物钻探中具有钻井成本低、可顺利完成水平段钻进、降低井眼轨迹控制难度、储层污染小,降低了大规模海底坍塌的风险的优势,但是还存在着水平段长度短、井壁稳定性差、卡钻事故处理难度大、钻井工具开发难、连续油管寿命短等关键技术问题需要解决。     

Analysis of limestone micromechanical properties by optical microscopy

Four dense Scandinavian limestones were analyzed to determine their mechanical properties. The generation of dust (? 10 μm) and fines (? 90 μm) during a closed circuit vertical roller mill comminution process was correlated with the calcite crystal size distributions of each limestone. Thin sections were analyzed and by means of stereology the calcite crystal size distributions for each limestone was measured. The dust generation of limestones is governed by a surface abrasive mechanism (R² = 0.99) and the production of fines is governed by the mechanical strength of limestones (R² = 0.99). The overall limestone degradation mechanism is predominantly controlled by the calcite cleavage planes which reduce the power consumption during the comminution process. This study is the first step in determining the influence of limestone texture on the wear rates in heterogenous raw mixes used in closed circuit comminution equipment.     

The Impact of Heterogeneity on the Anisotropic Strength of an Outcrop Shale

Properly accounting for the mechanical anisotropy of shales can be critical for successful drilling of high inclination wells, because shales are known to be weak along bedding planes. To optimize the drilling parameters in such cases, a sufficiently representative, anisotropic rock mechanical model is therefore required. This paper presents such a model developed to better match results from a dedicated, extensive set of uniaxial and triaxial compression tests performed on plugs of Mancos outcrop shale with different orientations relative to the bedding plane. Post failure inspection of the plugs shows that the failure planes are to some extent affected by the orientation of the applied stress relative to the bedding planes, indicating that the bedding planes may represent weak planes which tend to fail before intrinsic failure occurs, whenever the orientation of these planes is suitable. The simple “plane of weakness” model is commonly used to predict strength as function of orientation for such a rock. A comparison of this model to the experimental data shows, however, that the weak planes seem to have an impact on strength even outside the range of orientations where the model predicts such impact. An extension of this model allowing the weak planes to be heterogeneous in terms of patchy weakness was therefore developed. In this model, local shear sliding may occur prior to macroscopic failure, leading to enhanced local stresses and corresponding reduction in strength. The model is found to give better match with strength data at intermediate orientations. The model is also able to partly predict the qualitatively different variation of Young’s modulus with orientation for this data set.     

Evaluating the Poroelastic Effect on Anisotropic, Organic-Rich, Mudstone Systems

Understanding the poroelastic effect on anisotropic organic-rich mudstones is of high interest and value for evaluating coupled effects of rock deformation and pore pressure, during drilling, completion and production operations in the oilfield. These applications include modeling and prevention of time-dependent wellbore failure, improved predictions of fracture initiation during hydraulic fracturing operations (Suarez-Rivera et al. Presented at the Canadian Unconventional Resources Conference held in Calgary, Alberta, Canada, 15–17 November 2011. CSUG/SPE 146998 2011), improved understanding of the evolution of pore pressure during basin development, including subsidence and uplift, and the equilibrated effective in situ stress (Charlez, Rock mechanics, vol 2 1997; Katahara and Corrigan, Pressure regimes in sedimentary basins and their prediction: AAPG Memoir, vol 76, pp 73–78 2002; Fjær et al. Petroleum related rock mechanics. 2nd edn 2008). In isotropic rocks, the coupled poro-elastic deformations of the solid framework and the pore fluids are controlled by the Biot and Skempton coefficients. These are the two fundamental properties that relate the rock framework and fluid compressibility and define the magnitude of the poroelastic effect. In transversely isotropic rocks, one desires to understand the variability of these coefficients along the directions parallel and longitudinal to the principal directions of material symmetry (usually the direction of bedding). These types of measurements are complex and uncommon in low-porosity rocks, and particularly problematic and scarce in tight shales. In this paper, we discuss a methodology for evaluating the Biot’s coefficient, its variability along the directions parallel and perpendicular to bedding as a function of stress, and the homogenized Skempton coefficient, also as a function of stress. We also predict the pore pressure change that results during undrained compression. Most importantly, we provide values of transverse and longitudinal Biot’s coefficients and the homogenized Skempton coefficient for two important North American, gas-producing, organic-rich mudstones. These results could be used for petroleum-related applications.