Determining the amount of overstepping required to nucleate garnet during Barrovian regional metamorphism,Connecticut Valley Synclinorium

The novel method of inclusion barometry coupled with the calculation of the required affinity for garnet nucleation is applied to three samples from the previously well‐characterized Connecticut Valley Synclinorium in central Vermont. Raman shifts for quartz inclusions record a range of maximum peak shifts of the quartz 464 cm^?1 peak from 2.4 to 3.0 cm^?1. Temperature of garnet nucleation was constrained by calculating mineral assemblage diagrams in the MnNCKFMASHT system and plotting the intersection of quartz inclusion in garnet barometry (QuiG, quartz‐in‐garnet) with Zr‐in‐rutile thermometry. Utilizing the intersection of Zr‐in‐rutile thermometry with QuiG barometry, garnet nucleation is inferred to have occurred within a P–T range of ~8.6–9.5 kbar and ~560–575°C. These P–T conditions for garnet nucleation are significantly higher than calculated equilibrium garnet‐in isograds for the three samples. Affinities for garnet nucleation were calculated as the difference between the free energy of a fictive garnet composition based on the matrix assemblage and the free energy of the nucleated garnet. The calculated nucleation affinity varied from 300 to 600 kJ/mol O for St–Ky grade samples. These results suggest that the assumption that metamorphism proceeds as a sequence of near‐equilibrium conditions cannot, in general, be made for regional metamorphic terranes. This body of work agrees with numerous recent studies showing that garnet‐producing reactions must be overstepped in order to for garnet to nucleate.     

From Lightning Rod to Community Asset? The Creation of a Protected Area in Northern California and its Evolving Relationship to a Nearby Community

Researchers have described shifting relationships between communities and Protected Areas (PAs), from excluding communities to consultative relationships to participatory models. This research focuses on a PA created on formerly industrial timberland that was the focus of conflict between environmental activists and the timber industry. In a nearby formerly timber-dependent community, we assessed community use and support of the PA, and its perceived purposes and benefits, through a survey of residents and interviews with key stakeholders. Despite intense conflict surrounding its creation, we found support for the PA, and our case suggests a new possible relationship between PAs and communities, which is mitigating and helping to resolve natural resource conflict. We also found that community well-being benefits of the PA were unclear; we suggest that PA management should include cultural, economic, and historical context in objectives and interpretive materials; and should work to create economic opportunities connected to the PA.     

Experts' Perspectives on the Integration of Indigenous Knowledge and Science in Wet Tropics Natural Resource Management

Aboriginal inhabitants of the Wet Tropics of Queensland advocate for greater inclusion of their Indigenous knowledge (IK) in natural resource management (NRM) to fulfil their customary obligations to country and to exert their Native Title rights. Despite a legal and institutional framework for inclusion of IK in NRM, IK has so far been applied only sporadically. We conducted an ethnographic case study to investigate perceptions on IK, science and how they affect integration of the two knowledge systems in the Wet Tropics. Our results show that IK and science are perceived as different concepts; that integration is limited by weak Indigenous internal and external governance; and that stronger Aboriginal governance and more focused engagement strategies are required to further the application of IK in local NRM. We conclude by arguing that NRM in the Wet Tropics needs to be reconceptualised to accommodate IK holistically, by considering its epistemology and the values and ethic that underpin it.     

Estimating Aquifer Sensitivity to Nitrate Contamination Using Geochemical Information

Methods for predicting aquifer sensitivity to contamination typically ignore geochemical factors that affect the occurrence of contaminants such as nitrate. Use of geochemical information offers a simple and accurate method for estimating aquifer sensitivity to nitrate contamination. We developed a classification method in which nitrate-sensitive aquifers have dissolved oxygen concentrations > 1.0 mg/L, Eh values >250 mV, and either reduced iron concentrations < 0.1 mg/L or total iron concentrations < 0.7 mg/L. We tested the method in four Minnesota aquifer systems having different geochemical and hydrologic conditions. A surficial sand aquifer in central Minnesota exhibited geochemical zonation, with a rapid shift from aerobic to anaerobic conditions 5 m below the water table. A fractured bedrock aquifer in east-central Minnesota remained aerobic to depths of 50 m, except in areas where anaerobic ground water discharged upward from an underlying aquifer. A bedrock aquifer in southeast Minnesota exhibited aerobic conditions when overlain by surficial deposits lacking shale, whereas anaerobic conditions occurred under deposits that contained shale. Surficial sand aquifers in northwest Minnesota contained high concentrations of sulfate and were anaerobic throughout their extent. Nitrate-nitrogen was detected at concentrations exceeding 1 mg/L in 135 of 149 samples classified as sensitive. Nitrate was not detected in any of the 109 samples classified as not sensitive. We observed differences between our estimates of sensitivity and existing sensitivity maps, which are based on methods that do not consider aquifer geochemistry. Because dissolved oxygen, reduced iron, and Eh are readily measured in the field, use of geochemistry provides a quick and accurate way of assessing aquifer sensitivity to nitrate contamination.     

Reaction overstepping and re-evaluation of peak P‒T conditions of the blueschist unit Sifnos,Greece: implications for the Cyclades subduction zone

ABSTRACT

Equilibrium thermodynamic modelling, quartz in garnet (QuiG) Raman geobarometry, and modelling of garnet nucleation at overstepped conditions were applied to three garnet-bearing blueschists from a 1.5 km-long transect across the eclogite-blueschist unit in Sifnos, Greece, in order to evaluate the accuracy of P?T conditions calculated via equilibrium thermodynamics. QuiG barometry uses the Raman shift of quartz inclusions in garnet to estimate the pressure of garnet nucleation and is independent of chemical equilibrium. Garnet nucleation temperatures were estimated by determining the stability field of the palaeo-assemblage inferred from garnet inclusion suites on mineral assemblage diagrams calculated in the MnNCKFMASH system and on temperatures obtained from Zr in rutile thermometry. These conditions were then compared to P?T conditions calculated at the equilibrium garnet isograd, and the method of intersecting isopleths. The P?T conditions calculated with intersecting garnet isopleths over- and underestimated the temperature of nucleation in samples SPH99-1a and SPH99-7, respectively, whereas they significantly underestimated nucleation pressure in SPH99-5. Nucleation of garnet in SPH99-1a at 12 kbar and ~484°C requires overstepping of ~6 kbar and a reaction affinity of 2.2 kJ mol^?1 O. SPH99-5 requires overstepping of ~8 kbar with garnet reaction affinities of at least 2.0 kJ mol^?1 O at 15 kbar and ~520°C. SPH99-7 requires overstepping of approximately 15 kbar and affinities of about 2.0–2.4 kJ mol^?1 O at ~23 kbar and ~530°C. The geotherms calculated from SPH99-7 (~6.7°C km^?1) and SPH99-5 (9.8°C km^?1) are in accordance with previous studies. The geotherm calculated from SPH99-1a, however, is warmer (11.3°C km^?1), and could reflect changes in the rate of subduction or differences in structural position within the down-going slab. The 10 kbar pressure difference between SPH99-7 and SPH99-1a can be explained by thrusting and accretion of thin slices of underplated wedge material facilitated by slab rollback and gravitational collapse.     

The absence of memory in the climatic forcing of glaciers

Glaciers respond to both long-term, persistent climate changes as well as the year-to-year variability that is inherent to a constant climate. Distinguishing between these two causes of length change is important for identifying the true climatic cause of past glacier fluctuations. A key step in addressing this is to determine the relative importance of year-to-year variability in climate relative to more persistent climate fluctuations. We address this question for European climate using several long-term observational records: a century-long, Europe-wide atmospheric gridded dataset; longer-term instrumental measurements of summertime temperature where available (up to 250 years); and seasonal and annual records of glacier mass balance (between 30 and 50 years). After linear detrending of the datasets, we find that throughout Europe persistence in both melt-season temperature and annual accumulation is generally indistinguishable from zero. The main exception is in Southern Europe where a degree of interannual persistence can be identified in summertime temperatures. On the basis of this analysis, we conclude that year-to-year variability dominates the natural climate forcing of glacier fluctuations on timescales up to a few centuries.     

An investigation of GNSS atomic clock behavior at short time intervals

A technique for obtaining clock measurements from individual GNSS satellites at short time intervals is presented. The methodology developed in this study allows for accurate satellite clock stability analysis without an ultra-stable clock at the ground receiver. Variations in the carrier phase caused by the satellite clock are isolated using a combination of common GNSS carrier-phase processing techniques. Furthermore, the white phase variations caused by the thermal noise of the collection and processing equipment are statistically modeled and removed, allowing for analysis of clock performance at subsecond intervals. Allan deviation analyses of signals collected from GPS and GLONASS satellites reveal distinct intervals of clock noise for timescales less than 100 s. The clock data collected from GPS Block IIA, IIR, IIR-M, and GLONASS satellites reveal similar stability performance at time periods greater than 20 s. The GLONASS clock stability in the 0.6–10 s range, however, is significantly worse than GPS. Applications that rely on ultra-stable clock behavior from the GLONASS satellites at these timescales may therefore require high-rate corrections to estimate and remove oscillator-based errors in the carrier phase.     

Secondary mineral formation associated with respiration of nontronite,NAu-1 by iron reducing bacteria

Experimental batch and miscible-flow cultures were studied in order to determine the mechanistic pathways of microbial Fe(III) respiration in ferruginous smectite clay, NAu-1. The primary purpose was to resolve if alteration of smectite and release of Fe precedes microbial respiration. Alteration of NAu-1, represented by the morphological and mineralogical changes, occurred regardless of the extent of microbial Fe(III) reduction in all of our experimental systems, including those that contained heat-killed bacteria and those in which O₂, rather than Fe(III), was the primary terminal electron acceptor. The solid alteration products observed under transmission electron microscopy included poorly crystalline smectite with diffuse electron diffraction signals, discrete grains of Fe-free amorphous aluminosilicate with increased Al/Si ratio, Fe-rich grains, and amorphous Si globules in the immediate vicinity of bacterial cells and extracellular polymeric substances. In reducing systems, Fe was also found as siderite. The small amount of Fe partitioned to the aqueous phase was primarily in the form of dissolved Fe(III) species even in the systems in which Fe(III) was the primary terminal electron acceptor for microbial respiration. From these observations, we conclude that microbial respiration of Fe(III) in our laboratory systems proceeded through the following: (1) alteration of NAu-1 and concurrent release of Fe(III) from the octahedral sheets of NAu-1; and (2) subsequent microbial respiration of Fe(III).