Variability in temperature and geometry of the Norwegian Current over the past 600 yr; stable isotope and grain size evidence from the Norwegian margin

Core P1‐003MC was retrieved from 851 m water depth on the southern Norwegian continental margin, close to the boundary between the Norwegian Current (NC) and the underlying cold Norwegian Sea Deep Water. The core chronology was established by using ²¹⁰Pb measurements and ¹⁴C dates, suggesting a sampling resolution of between 2 and 9 yr. Sea‐surface temperature (SST) variations in the NC are reconstructed from stable oxygen isotope measurements in two planktonic Foraminifera species, Neogloboquadrina pachyderma (d.) and Globigerina bulloides. The high temporal resolution of the SST proxy records allows direct comparison with instrumental ocean temperature measurements from Ocean Weather Ship (OWS) Mike in the Norwegian Sea and an air temperature record from the coastal island Ona, western Norway. The comparison of the instrumental and the proxy SST data suggests that N. pachyderma (d.) calcify during summer, whereas G. bulloides calcify during spring. The δ¹⁸O records of both species suggest that the past 70 yr have been the warmest throughout the past 600 yr. The spring and summer proxy temperature data suggest differences in the duration of the cold period of the Little Ice Age. The spring temperature was 1–3°C colder throughout most of the period between ca. AD 1400 and 1700, and the summer temperature was 1–2°C colder throughout most of the period between ca. AD 1400 and 1920. Fluctuations in the depth of the lower boundary of the NC have been investigated by examining grain size data and benthic foraminiferal assemblages. The data show that the transition depth of the lower boundary of the NC was deeper between ca. AD 1400 and 1650 than after ca. AD 1750 until present. Copyright © 2003 John Wiley & Sons, Ltd.     

Pressure variations in peat as a result of gas bubble dynamics

Transient high pore‐water pressures, up to 50 cm higher than ambient pressure, developed over the summer season at various depths in a shallow (1 m) fen peat. The excess pressures had a pattern of gradual increases and sharp drops, and their initiation and release typically corresponded to abrupt changes in atmospheric pressure. We conclude that these phenomena depend on gas bubbles (probably methane) generated by biological activity, both by clogging pores and by building up pressure as they grow. These transient and spatially discontinuous high‐pressure zones were found using pressure transducers in sealed (backfilled) pits, but not in piezometers open to the atmosphere. Piezometers may provide a conduit for the release of gas and pressure, thus rendering them unsuitable for measuring this phenomenon. Although the development of localized zones of high pressure causes erratic and unpredictable hydraulic gradients, we suggest that their effect on the flow of water or solutes is offset by the reduced permeability caused by the bubbles, which allows them to be sustained. These zones, however, probably deflect flows driven by the dominant hydraulic gradients. Furthermore, they may cause the peat volume to adjust (swell). The use and interpretation of traditional methods for estimating hydraulic head and conductivity in peat soils thus require great caution. Copyright © 2004 John Wiley & Sons, Ltd.     

GPS Solutions: Closed Forms, Critical and Special Configurations of P4P

P4P is the pseudo-ranging 4-point problem as it appears as the basic configuration of satellite positioning with pseudo-ranges as observables. In order to determine the ground receiver/satellite receiver (LEO networks) position from four positions of satellite transmitters given, a system of four nonlinear (algebraic) equations has to be solved. The solution point is the intersection of four spherical cones if the ground receiver/satellite receiver clock bias is implemented as an unknown. Here we determine the critical configuration manifold (Determinantal Loci, Inverse Function Theorem, Jacobi map) where no solution of P4P exists. Four examples demonstrate the critical linear manifold. The algorithm GS solves in a closed form P4P in a manner similar to Groebner bases: The algebraic nonlinear observational equations are reduced in the forward step to one quadratic equation in the clock bias unknown. In the backward step two solutions of the position unknowns are generated in closed form. Prior information in P4P has to be implemented in order to decide which solution is acceptable. Finally, the main target of our contribution is formulated: Can we identify a special configuration of satellite transmitters and ground receiver/satellite receiver where the two solutions are reduced to one. A special geometric analysis of the discriminant solves this problem. ? 2002 Wiley Periodicals, Inc.     

Elektronenmikroskopische Untersuchungen an mikritischen Kalken

Zusammenfassung Es werden die Entstehungsmöglichkeiten von mikritischen Kalken diskutiert und an Hand von elektronenmikroskopischen Aufnahmen Hinweise auf genetische Interpretationen vorgeführt.

---

The origin of micritic limestones is discussed and genetic interpretation of micrites from different environments, studied by electron microscope, is given.

---

Résumé L'origine des calcaires micritic est discutée et une interprétation génétique des micrites de milieux différents est donnée à l'aide de la microscopie électronique.

---

. .

---

---

Vorgetragen auf der 56. Jahresversammlung der Geologischen Vereinigung in Wien im Februar 1966.     

Temporal behavior of manganese and iron in a sandy coastal sediment exposed to water column anoxia

The influence of bottom water anoxia on manganese (Mn), iron (Fe), and sulfur (S) biogeochemistry was examined in defaunated sandy sediment from Kærby Fed, Denmark, under controlled laboratory incubations. The initial narrow peaks and steep gradients in solid Mn(IV) and Fe(III) as well as porewater Mn²⁺ and Fe²⁺ observed in the upper 2–5 cm of the sediment indicate rapid metal reduction-oxidation cycles under oxic conditions in the overlying water. The fe zones were generally displaced about 0.5 cm downward compared with the Mn zones due to differences in reactivity. Mn(IV) was reduced and gradually disappeared first (within 10 d) when the sediment was exposed to anoxia followed by reduction and disappearance of Fe(III) (day 7 to 18). The associated loss of Mn²⁺ to the overlying water was most rapid during the first 15 d, whereas the Fe²⁺ efflux initiated around day 10, and after a few days with modest rates the efflux peaked around day 20. A considerable portion of the total Mn (26%) and Fe (23%) inventory initially present in the sediment was lost by efflux after about 1 mo of anoxia. The ability of the sediment to retain upward diffusion of H₂S gradually disappeared in a temporal pattern closely related to the changes in pool size of the reactive Mn and Fe present. The total metal pool in Kærby Fed sediment prevented H₂S release to the overlying water for at least a month of anoxia. It is speculated that external supplies from the overlying water allows a rapid refuelling of surface Mn and Fe oxides in the field when oxic conditions returns between periods of anoxia.     

Behaviour of Fe-oxides relevant to contaminant uptake in the environment

The behaviour of Fe-oxides was investigated during precipitation and co-precipitation, phase transformation and dissolution, while their ability to adsorb and incorporate trace components was examined. Some samples were synthesised and studied under controlled laboratory conditions and other samples were taken from experiments designed to test the effectiveness of waste treatment strategies using iron. Surface-sensitive and high-resolution techniques were used to complement information gathered from classical, macroscopic methods.

Adsorption isotherms for Ni²⁺ uptake on synthetic ferrihydrite (Fe₅HO₈·4H₂O, often written simply Fe(OH)₃), goethite (-FeOOH), hematite (-Fe₂O₃) and magnetite (Fe₃O₄) were all similar, increasing as expected at higher pH. Desorption behaviour was also similar, but one third or more of the Ni²⁺ failed to return to solution. In the past, “irreversible sorption” has been blamed on uptake into micro-fractures or pores, but during examination (using Atomic force microscopy, AFM) of hundreds of Fe-oxide particles, no evidence for such features could be found, leading to the conclusion that Ni²⁺ must become incorporated onto or into the solids. When solutions of Fe(II) are oxidised in controlled laboratory conditions or during treatment of ash from municipal waste incinerators, two-line ferrihydrite forms rapidly and on never-dried samples, AFM shows abundant individual particles with diameter ranging from 0.5 to several tens of nanometers. Aging in solution at 70°C promotes growth of the particles into hematite and goethite and their identification (by X-ray powder diffraction, XRPD, with Rietveld refinement) becomes possible at the same aging stage as mineral morphology becomes recognisable by AFM. In other experiments that were designed to mimic natural attack by organic acids, colloidal lepidocrocite (γ-FeOOH) was observed in situ by AFM, while reductive dissolution removed material on specific crystal faces. Lath ends are eroded fastest while basal planes are more stable.

In order to help elucidate mechanisms of contaminant immobilisation by Fe-oxides, we examined samples from a reactive barrier made with 90% quartz sand, 5% bentonite and 5% zero-valent iron filings that had reacted with a solution typical of leachate from coal-burning fly ash using time-of-flight secondary ion mass spectroscopy (TOF-SIMS). Fe(0) oxidised to Fe(III), while soluble and toxic Cr(VI) was reduced to insoluble Cr(III). Chemical maps show Fe-oxide coatings on bentonite; Cr is associated with Fe-oxides to some extent but its association with Ca in a previously undescribed phase is much stronger. Other samples taken from municipal waste incinerator ash that had been treated by aeration in Fe(II) solutions were examined with transmission electron microscopy (TEM), selected area electron diffraction (SAED) and energy dispersive X-ray spectroscopy (EDS). Pb and some Zn are seen to be dispersed throughout two-line ferrihydrite aggregates, whereas Sn and some Zn are incorporated simply as a result of entrainment of individual ZnSn-oxide crystallites.

Geochemical speciation models that fail to account for contaminant uptake in solid solutions within major phases or as thin coatings or entrained crystals of uncommon phases such as those described here risk to underestimate contaminant retardation or immobilisation.     

The influence of foliation on the fragility of granitic rocks, image analysis and quantitative microscopy

Fabric-dependent anisotropy is important in understanding the mechanical behaviour of foliated rocks because the foliation creates mechanically weak discontinuities. Using optical microscopy, a foliation index (FIX) was calculated for a group of granitic rocks in southern Sweden that displays a range of textures from foliated to nonfoliated. Image analysis from scanning electron microscope with backscattered detector (SEM/BSE) images was used in order to measure the rock texture of these samples. The analyses were compared with the Los Angeles (LA) test, which measures resistance of rock aggregate to fragmentation. The results demonstrate that the measured grain size, shape and spatial arrangement are important parameters controlling the fragility of the rock. Both the texture and foliation must be taken into account to obtain a significant relationship with the mechanical analyses. We suggest that this alternative method could be a helpful tool for predicting a rock's suitability as an aggregate as it gives a better understanding of the material properties compared to mechanical testing.     

The application of cascading consequences for emergency management operations

How societies organize themselves to respond to cascading impacts exacerbated by climate change will help define the future of disaster planning, mitigation, response, and recovery. Current emergency management risk analyses focus on identifying a broad array of threats and hazards that may affect an area. However, there is limited attention and understanding of the totality of hazard impacts, the relationship of consequences across disasters, and the dangers of not addressing critical capabilities necessary to rapidly managing consequences—including the potential to create new incidents within incidents. Through a focused review of the related literature and guiding policy documents, this study aims to provide a cascading consequence-based framework that can support emergency managers in the analysis of their jurisdictional risks, development of emergency operations plans, and decision-making. Results include the identification of an alternative framework to identify cascading networks, the creation of a supplementary model for downstream risk assessment, and refined Threat and Hazard Identification and Risk Analysis (THIRA) outputs for improved grant allocation. The proposed framework has the potential to help organizations factor both conspicuous and downstream consequences into their Emergency Operations Plans in the planning and mitigations phases. This proposed refinement, which looks deeper into the progression of a disaster, has both national and international implications.