Cretaceous stratigraphy and palaeoenvironments of the Southern Petén Basin, Guatemala

The Cretaceous deposits of the Southern Petén Basin, an oil-producing province, are located to the south of the Yucatan Platform and to the east of the Chiapas Carbonate Platform of Mexico. The succession in the southern part of this basin has been studied both in wells and at outcrop by microfacies analysis. It is composed of 5000 m of shallow marine carbonates and evaporites with a few thin layers of pelagic limestones rich in organic carbon and planktic foraminifera deposited during peak transgressions or maximum flooding. The sedimentation of this thick succession was not continuous, and the section is punctuated by subaerial erosional bounding surfaces and a single hardground which marks the final drowning of the carbonate platform during the late Maastrichtian. New age determinations have been obtained on the basis of planktic and benthic foraminifera from the Aptian to Santonian Cobán Formation, D, C, B and A Members. Cobán C (Albian) and B (Cenomanian) Members are the present oil reservoirs. The rudist and alveolinid limestones of late Campanian and Maastrichtian age referred to the Campur Formation in the Southern Petén Basin are here reassigned to the Angostura Formation, as recognized in the Chiapas area. The Actela Formation is defined here to encompass the limestone breccia deposits that occur at the Cretaceous–Tertiary boundary and extend into the Parvularugoglobigerina eugubina Zone of early Danian age. The D, C, B and A Members of the Cobán Formation and the Angostura Formation represent second order transgressive and regressive trends in a passive margin area where the deposits indicate a succession of various environments, including fluviatile, salinas, shallow marine carbonate platform, outer shelf and intrashelf basin. High subsidence rates, sea-level changes and tectonic uplift controlled the sedimentation.

Abstract

Les formations crétacées du sud-est du Bassin du Petén, région pétrolière du nord du Guatemala, sont situées au Sud du Yucatan et à l'Est du Chiapas au Mexique. Ces sédiments ont été étudiés à la fois dans deux puits et à l'affleurement par l'analyse des microfaciès. Cet ensemble sédimentaire est composé de 5000 m de carbonates de plate-forme de faible profondeur et d'évaporites, dans lesquels s'intercalent de minces couches de calcaires pélagiques riches en matière organique et en foraminifères planctoniques. Ces calcaires pélagiques se sont déposés lors des maximums de transgressions. La sédimentation de cette épaisse série n'est pas continue et est ponctuée par quelques surfaces d'érosion sub-aérienne et une surface durcie qui souligne l'ennoyage définitif de la plate-forme carbonatée au Maastrichtien terminal. De nouvelles datations ont été obtenues sur la formation Cobán et ses membres D, C, B et A qui s'étagent de l'Aptien au Santonien. Les membres C (albien) et B (cénomanien) constituent les réservoirs productifs. Les calcaires à rudistes et à alveolinidés du Campanien supérieur–Maastrichtien ont été appelés à tort au Petén formation Campur. Ils doivent, selon nous, être attribués à la formation Angostura comme au Chiapas voisin, où affleurent des faciès comparables et de même âge. Une nouvelle formation est créée (formation Actela) pour les brèches calcaires de la limite Crétacé–Tertiaire et de la Zone à Eugubina du Danien inférieur. Les membres D, C, B, A de la formation Cobán et la formation Angostura représentent des cycles transgressifs–régressifs de deuxième ordre. Sur cette marge passive du Petén, les dépôts correspondent à des environnements variés comme des terres émergées soumises à une altération karstique et à des dépôts fluviatiles, des salinas, des plates-formes carbonatées marines, des shelf externes et des bassins intra plate-forme. La sédimentation a été, ici, contrôlée par une forte vitesse de subsidence, les variations du niveau marin et des soulèvements tectoniques.     

New pterosaurian remains from the Late Cretaceous (Santonian) of Hungary (Iharkút, Csehbánya Formation)

The Late Cretaceous (Santonian) continental vertebrate locality of Iharkút, western Hungary has provided numerous azhdarchid pterosaur remains including the recently described, Bakonydraco galaczi. Since the first report of these fossils, additional remains have been discovered that improve considerably our knowledge of some aspects of the anatomy of azhdarchid pterosaurs. New cranial material described here indicates an edentulous, non-crested premaxillary rostrum in Bakonydraco similar to that of Quetzalcoatlus and reveals that this rostrum was considerably thinner and more lightly built than the relatively massive, pointed mandibular symphysis. In addition, the contact surface of the upper and lower jaws of Bakonydraco at least in the symphyseal region was more similar to Tapejara wellnhoferi than to other azdarchids: the contact is irregular and the premaxilla does not fit closely the rostral part of the mandible. Among the postcranial material the atlas-axis complex possessing lateral pneumatic foramina is of great importance because it further supports the notion of interspecific variability of vertebral pneumaticity among pterosaurs.     

Bootstrapping: A Fast Way to Simulate QTz Curves

The aim of this paper is to present a fast method based on bootstrapping, for simulating recoverable reserves for input to financial Monte Carlo simulations. In mining, the three parameters defining recoverable reserves are the cutoff grade, z, the ore tonnage above cutoff, T, and the metal quantity above cutoff, Q. After introducing the concept of 3-dimensional QTz curves, the statistical technique called bootstrapping is reviewed and applied to a set of South African gold grades. As selective mining is carried out on blocks not points, these curves have to be calculated for blocks. The QTz curves obtained by bootstrapping are compared to those obtained by conditionally simulating the same deposit. The procedure has been extended to incorporate geologists' ideas of the likely size of the ore volume. Lastly, the recoverable reserves obtained by bootstrapping are compared with those obtained by traditional risk analysis (base case ± 10% or 20%).     

Geology of the epithermal Ag–Au Huevos Verdes vein system and San José district, Deseado massif, Patagonia, Argentina

The San José district is located in the northwest part of the Deseado massif and hosts a number of epithermal Ag–Au quartz veins of intermediate sulfidation style, including the Huevos Verdes vein system. Veins are hosted by andesitic rocks of the Bajo Pobre Formation and locally by rhyodacitic pyroclastic rocks of the Chon Aike Formation. New ⁴⁰Ar/³⁹Ar constraints on the age of host rocks and mineralization define Late Jurassic ages of 151.3 ± 0.7 Ma to 144.7 ± 0.1 Ma for volcanic rocks of the Bajo Pobre Formation and of 147.6 ± 1.1 Ma for the Chon Aike Formation. Illite ages of the Huevos Verdes vein system of 140.8 ± 0.2 and 140.5 ± 0.3 Ma are 4 m.y. younger than the volcanic host rock unit. These age dates are among the youngest reported for Jurassic volcanism in the Deseado massif and correlate well with the regional context of magmatic and hydrothermal activity. The Huevos Verdes vein system has a strike length of 2,000 m, with several ore shoots along strike. The vein consists of a pre-ore stage and three main ore stages. Early barren quartz and chalcedony are followed by a mottled quartz stage of coarse saccharoidal quartz with irregular streaks and discontinuous bands of sulfide-rich material. The banded quartz–sulfide stage consists of sulfide-rich bands alternating with bands of quartz and bands of chlorite ± illite. Late-stage sulfide-rich veinlets are associated with kaolinite gangue. Ore minerals are argentite and electrum, together with pyrite, sphalerite, galena, chalcopyrite, minor bornite, covellite, and ruby silver. Wall rock alteration is characterized by narrow (< 3 m) halos of illite and illite/smectite next to veins, grading outward into propylitic alteration. Gangue minerals are dominantly massive quartz intergrown with minor to accessory adularia. Epidote, illite, illite/smectite, and, preferentially at deeper levels, Fe-chlorite gangue indicate near-neutral pH hydrothermal fluids at temperatures of >220°C. Kaolinite occurring with the late sulfide-rich veinlet stage indicates pH < 4 and a temperature of <200°C. The Huevos Verdes system has an overall strike of 325°, dipping on average 65° NE. The orientations of individual ore shoots are controlled by vein strike and intersecting north-northwest-striking faults. We propose a structural model for the time of mineralization of the San José district, consisting of a conjugate shear pair of sinistral north-northwest- and dextral west-northwest-striking faults that correspond to R and R′ in the Riedel shear model and that are related to master faults (M) of north-northeast-strike. Veins of 315° strike can be interpreted as nearly pure extensional fractures (T). Variations in vein strike predict an induced sinistral shear component for strike directions of >315°, whereas strike directions of <315° are predicted with an induced dextral strike–slip movement. The components of the structural model appear to be present on a regional scale and are not restricted to the San José district.     

Diffusion-limited REE uptake by eclogite garnets and its consequences for Lu–Hf and Sm–Nd geochronology

Garnets from the Zermatt-Saas Fee eclogites contain narrow central peaks for Lu + Yb + Tm ± Er and at least one additional small peak towards the rim. The REE Sm + Eu + Gd + Tb ± Dy are depleted in the cores but show one prominent peak close to the rim. These patterns cannot be modeled using Rayleigh fractionation accompanied by mineral breakdown reactions. Instead, the patterns are well explained using a transient matrix diffusion model where REE uptake is limited by diffusion in the matrix surrounding the porphyroblast. Observed profiles are well matched if a roughly linear radius growth rate is used. The secondary peaks in the garnet profiles are interpreted to reflect thermally activated diffusion due to temperature increase during prograde metamorphism. The model predicts anomalously low ¹⁷⁶Lu/¹⁷⁷Hf and ¹⁴⁷Sm/¹⁴⁴Nd ratios in garnets where growth rates are fast compared to diffusion of the REE, and these results have important implications for Lu–Hf and Sm–Nd geochronology using garnet.     

Low temperature volatile production at the Lost City Hydrothermal Field, evidence from a hydrogen stable isotope geothermometer

Although commonly utilized in continental geothermal work, the water-hydrogen and methane-hydrogen isotope geothermometers have been neglected in hydrothermal studies. Here we report δD-CH₄ and δD-H₂ values from high-temperature, black smoker-type hydrothermal vents and low-temperature carbonate-hosted samples from the recently discovered Lost City Hydrothermal Field. Methane deuterium content is uniform across the dataset at − 120 ± 12‰. Hydrogen δD values vary from − 420‰ to − 330‰ at high-temperature vents to − 700‰ to − 600‰ at Lost City. The application of several geothermometer equations to a suite of hydrothermal vent volatile samples reveals that predicted temperatures are similar to measured vent temperatures at high-temperature vents, and 20-60 °C higher than those measured at the Lost City vents. We conclude that the overestimation of temperature at Lost City reflects 1) that methane and hydrogen are produced by serpentinization at > 110 °C, and 2) that isotopic equilibrium at temperatures < 70 °C is mediated by microbial sulfate reduction. The successful application of hydrogen isotope geothermometers to low-temperature Lost City hydrothermal samples encourages its employment with low-temperature diffuse hydrothermal fluids.     

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.     

An experimental study of lake water-sediment interaction rates

Dissolution rates of sediments obtained from the Oued Cherf reservoir were measured in closed-system batch reactors at 25 °C in fluids sampled concurrently from the same locations as the sediments. The BET surface areas of the sediments ranged from 16 to 45 m²/g and consisted primarily of quartz, calcite, and clay minerals. After a brief initial period, release rates of Si, Mg, Ca, Cl, SO₄, and NO₃ from these sediments are approximately linear with time over the course of the experiments, which lasted from 3 to 5 months. BET surface area normalized Si release rates ranged from 10^–17.4 to 10^–18.4 mol/cm²/s. These release rates match closely Si release rates from quartz and clay minerals determined from laboratory dissolution rates reported in the literature. This coherence suggests that laboratory measured silicate dissolution rates can be used with confidence to predict the dissolution behavior of sediments in natural surface waters.     

Genesis and solvus relations of submicroscopically intergrown paragonite and phengite in a blueschist from northern California

Electron microbeam techniques have been used to examine submicroscopically intergrown paragonite, phengite and chlorite from the South Fork Mountain Schist of the Franciscan Terrane of northern California, which was subjected to blueschist facies metamorphism. The sample also contains quartz, albite, lawsonite, and rutile. The subassemblage albite-lawsonite-rutile requires metamorphic conditions on the low-temperature side of the equilibrium albite+lawsonite+rutile=paragonite+sphene+quartz+H₂O (T<200° C and P<7.4 kbars based on thermodynamic data of Holland and Powell 1990). The white micas appear to be optically homogeneous, but back-scattered electron images can distinguish two different micas by their slight difference in contrast. Electron microprobe analyses (EMPA) of micas show Na/(Na+K) ranging from 0.2 to 0.8. The two micas are resolved by transmission electron microscopy (TEM) as packets of phengite and paragonite that range from 20 to several hundred nm in thickness. The compositions, determined by analytical electron microscopy (AEM), constrain the limbs of the phengite-paragonite solvus to values of Na/(Na+K)=<0.02 and 0.97, representing less mutual solid solution than ever reported by EMPA. The textural relations imply that the sheet silicates were derived from reactions between fluids and detrital clays and that they are in an intermediate stage of textural development. We caution that microprobe analyses of apparently homogeneous sheet silicates may yield erroneous data and lead to faulty conclusions using phengite barometry and paragonite-muscovite thermometry, especially in fine-grained rocks that formed at relatively low temperatures. Contribution no. 473 from the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan, USA