Bristen granite: a highly differentiated,fluorite-bearing A-type granite from the Aar massif,Central Alps,Switzerland

Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C.     

The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

Hydrogeochemistry of the Koyna River basin,India

Hydrogeochemistry of the Koyna River basin, famous for the Koyna earthquake (magnitude 7) of 1967, has been studied. Basalt is the primary aquifer; laterites, alluvium, and talus deposits form aquifers of secondary importance. Groundwater generally occurs under water table conditions in shallow aquifers. Deeper aquifers are associated only with basalts. One hundred and 87 water samples were collected from various sources, such as dugwells, borewells, springs, and surface water, including 40 samples for analysis of iron. Only major constituents were analyzed. Analyses show that the concentrations of Ca²⁺ exceed that of Mg²⁺ in almost all water samples; the concentrations of Na⁺ are generally next to Ca²⁺ and are always higher than that of K⁺; and CO₃ ^2– and SO₄ ^2– are very low and are often negligible. Groundwater in borewells tapping deeper aquifers has higher mineralization compared to that in dugwells representing shallow aquifers. Majority of the water samples are dominated by alkaline earths (Ca²⁺, Mg²⁺) and weak acids (HCO₃ ⁻, CO₃ ^2–). Groundwater from shallow aquifers is generally calcium-bicarbonate type (53%) and calcium-magnesium-bicarbonate type (27%). In case of deeper aquifer, it is mostly calcium-magnesium-bicarbonate type (29%), sodium-bicarbonate type (24%), calcium-bicarbonate type (19%), calcium-magnesium-sodium-bicarbonate type (19%) and sodium-calcium-bicarbonate type (9%). Groundwater water is generally fit for drinking and irrigation purposes, except in the lower reaches of the Koyna River basin, which is affected by near water logging conditions.     

Tracing origins of sewage and organic matter using dissolved sterols in Masan and Haengam Bay,Korea

Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.     

Analysis of types and changes of village-level economy in rural Gongyi city,Henan Province since 1990

Based on the research on the rural living standard in China in terms of annual net income per capita, we define six types of village-level economy, i.e. ＂to be extremely poor＂, ＂to make a basic living＂, ＂to dress warmly and eat one＇s fill＂, ＂to try to enrich （to disengage poverty）＂, ＂to be well-off＂ and ＂to be affluent＂. The data of average annual net income of all the 292 villages between 1990 and 2004 in rural Gongyi City, Henan Province were collected, verified and classified. By using standard deviation, coefficient of variation and regression analysis, it is found that the Gongyi＇s rural economy has boosted up remarkably from the relative-poverty and absolute-poverty stages in 1990 to the well-off in 2004. However, the absolute differences between villages present a trend of enlargement, while the relative differences fluctuating. On the other hand, spatial analysis of village-level economy shows that most villages with relatively high economic development level were located along national expressway and most villages with absolute-poverty lay in remote mountainous areas in 1990. Since the 1990s, the rapid urbanization and industrialization have had strongly positive effects on rural economic growth. Initial economic foundation, natural resources and traditional techniques also contribute to village economy. From the perspective of geography, villages with location advantages, such as near urban center or industrial parks, have more chances for their economic development and the ＂core-periphery＂ economic structure has been presented in the process of rural development.     

Misconceptions about the Hubble recession law

Almost all astronomers now believe that the Hubble recession law was directly inferred from astronomical observations. It turns out that this common belief is completely false. Those models advocating the idea of an expanding universe are ill-founded on observational grounds. This means that the Hubble recession law is really a working hypothesis. One alternative to the Hubble recession law is the tired-light hypothesis originally proposed by Zwicky (Proc. Nat. Acad. Sci. 15:773, 1929). This hypothesis leads to a universe that is an eternal cosmos continually evolving without beginning or end. Such a universe exists in a dynamical state of virial equilibrium. Observational studies of the redshift-magnitude relation for Type Ia supernovae in distant galaxies might provide the best observational test for a tired-light cosmology. The present study shows that the model Hubble diagram for a tired-light cosmology gives good agreement with the supernovae data for redshifts in the range 0<z<2. This observational test of a static cosmology shows that the real universe is not necessarily undergoing expansion nor acceleration. An erratum to this article can be found at     

A comparative study of sequential minimal optimization-based support vector machines,vote feature intervals,and logistic regression in landslide susceptibility assessment using GIS

Landslide susceptibility assessment using GIS has been done for part of Uttarakhand region of Himalaya (India) with the objective of comparing the predictive capability of three different machine learning methods, namely sequential minimal optimization-based support vector machines (SMOSVM), vote feature intervals (VFI), and logistic regression (LR) for spatial prediction of landslide occurrence. Out of these three methods, the SMOSVM and VFI are state-of-the-art methods for binary classification problems but have not been applied for landslide prediction, whereas the LR is known as a popular method for landslide susceptibility assessment. In the study, a total of 430 historical landslide polygons and 11 landslide affecting factors such as slope angle, slope aspect, elevation, curvature, lithology, soil, land cover, distance to roads, distance to rivers, distance to lineaments, and rainfall were selected for landslide analysis. For validation and comparison, statistical index-based methods and the receiver operating characteristic curve have been used. Analysis results show that all these models have good performance for landslide spatial prediction but the SMOSVM model has the highest predictive capability, followed by the VFI model, and the LR model, respectively. Thus, SMOSVM is a better model for landslide prediction and can be used for landslide susceptibility mapping of landslide-prone areas.     

Surface and groundwater quality characterization of Deoria District,Ganga Plain,India

A water quality investigation was carried out in the Deoria district, Ganga plain, to assess the suitability of surface and groundwaters for domestic, agricultural, and industrial purposes. As much as 50 representative samples from river and groundwater were collected from various stations to monitor the water chemistry of various ions, comprising Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻, Cl⁻, F⁻, and trace metals, such as Fe, Cu, Mn, Zn, Cd, and Pb. The results showed that electrical conductance (EC), total dissolved solids (TDS), HCO₃ ⁻, Mg²⁺, Na⁺, and total hardness (TH) are above the maximum desirable limit, and apart from Fe and Mn all other trace metals are within the maximum permissible limit for drinking water. The calculated values for sodium absorption ratio (SAR), salinity, residual sodium carbonate (RSC), and permeability index (PI) indicate well to permissible use of water for irrigation. High values of Na%, RSC, and Mg-hazard (MH) at some stations restrict its use for agricultural purpose. Anthropogenic activities affect the spatial variation of water quality. Economic and social developments of the study area is closely associated with the characteristics of the hydrological network.     

Errors and correction of precipitation measurements in China

In order to discover the range of various errors in Chinese precipitation measurements and seek a correction method, 30 precipitation evaluation stations were set up countrywide before 1993. All the stations are reference stations in China. To seek a correction method for wind-induced error, a precipitation correction instrument called the ＂horizontal precipitation gauge＂ was devised beforehand. Field intercomparison observations regarding 29,000 precipitation events have been conducted using one pit gauge, two elevated operational gauges and one horizontal gauge at the above 30 stations. The range of precipitation measurement errors in China is obtained by analysis of intercomparison measurement results. The distribution of random errors and systematic errors in precipitation measurements are studied in this paper. A correction method, especially for wind-induced errors, is developed. The results prove that a correlation of power function exists between the precipitation amount caught by the horizontal gauge and the absolute difference of observations implemented by the operational gauge and pit gauge. The correlation coefficient is 0.99. For operational observations, precipitation correction can be carried out only by parallel observation with a horizontal precipitation gauge. The precipitation accuracy after correction approaches that of the pit gauge. The correction method developed is simple and feasible.     

Assessment of rock slope stability by probabilistic-based Slope Stability Probability Classification method along highway cut slopes in Adilcevaz-Bitlis (Turkey)

Rock slope stability is of great concern along highway routes as stability problems on cut slopes may cause fatal events as well as loss of property. In rock slope engineering, stability evaluations are commonly performed by means of analytical or numerical analyses, principally considering the factor of safety concept. As a matter of fact, the probabilistic assessment of slope stability is progressively getting popularity due to difficulties in assigning the most appropriate values to design parameters in analytical or numerical methods. Additionally, the effect of heterogeneities in rock masses and discontinuities on the analysis results is minimized through the probabilistic concept. In this study, slope stability of high and steep sedimentary rock cut slopes along a state highway in Adilcevaz-Bitlis (Turkey) was evaluated on the basis of probabilistic approach using the Slope Stability Probability Classification (SSPC) system. The probabilistic assessment indicates major slope stability problems because of discontinuity controlled and discontinuity orientation independent mass movements. Almost all studied cut slopes suffer from orientation-independent stability problems with very low stability probabilities. Additionally, the probability of planar and toppling failures is significantly high with respect to the SSPC system. The stability problems along the investigated rock slopes were also verified by field reconnaissance. Remedial measures such as slope re-design and reinforcement at the studied locations should be taken to prevent hazardous events along the highway. On the other hand, the probabilistic approach may be a useful tool during rock slope engineering to overcome numerous uncertainties when probabilistic and analytic results are compared.