Toxicity and compositional analysis of aromatic hydrocarbon fractions of two pairs of undegraded and biodegraded crude oils from the Santa Maria (California) and Vienna basins

The monoaromatic and total aromatic hydrocarbon fractions of two pairs of undegraded and moderately biodegraded crude oils from the Santa Maria basin (California) and the Vienna basin (Austria), all dominated by unresolved complex mixtures, were studied regarding their composition and toxicity towards the feeding rate of the marine mussel Mytilus edulis. Total aromatic and monoaromatic hydrocarbon fractions from sulphur-rich Monterey Formation crude oils were slightly more toxic than the fractions isolated from sulphur-lean Vienna basin oils. The ecotoxicity tests did not show any significant differences in toxicity of aromatic compounds from undegraded or in-reservoir biodegraded crude oils from the same oilfield although some differences in composition were observed. Organic sulphur compounds are suspected to cause the slightly higher toxicity of the aromatic hydrocarbon fractions from the Monterey oils.     

Comparative aeronomy in the solar system

The coupled upper atmospheres, ionospheres and magnetospheres of the planets were the subject of a joint RAS–G/MIST discussion meeting hosted by the RAS on 10 January 2003, organized by Ingo Mueller-Wodarg and Emma Bunce . The scientific programme consisted of 10 presentations by speakers from the UK, France, USA and Australia.     

Frequency Content Evolution of Snow Avalanche Seismic Signals

Seismic signals generated by avalanches have been recorded by theavalanche team of the Universitat de Barcelona at theVallée de la Sionne experimental site (Switzerland) since 1998. During these years avalanches of varying size and flowwere recorded by two sensors located at different positions.In the present paper we show the general features of the running spectra of the seismicsignals for the different type of recorded avalanches. Using this method we are able not only to detect avalanches with low amplitude signals but also to distinguishbetween avalanches and other seismic sources (i.e., local earthquakes) which have thesame frequency content but a different frequency evolution.     

The Tornquist Sea and Baltica–Avalonia docking

Early Ordovician (Late Arenig) limestones from the SW margin of Baltica (Scania–Bornholm) have multicomponent magnetic signatures, but high unblocking components predating folding, and the corresponding palaeomagnetic pole (latitude=19°N, LONGITUDE=051°E) compares well with Arenig reference poles from Baltica. Collectively, the Arenig poles demonstrate a midsoutherly latitudinal position for Baltica, then separated from Avalonia by the Tornquist Sea.Tornquist Sea closure and the Baltica–Avalonia convergence history are evidenced from faunal mixing and increased resemblance in palaeomagnetically determined palaeolatitudes for Avalonia and Baltica during the Mid-Late Ordovician. By the Caradoc, Avalonia had drifted to palaeolatitudes compatible with those of SW Baltica, and subduction beneath Eastern Avalonia was taking place. We propose that explosive vents associated with this subduction and related to Andean-type magmatism in Avalonia were the source for the gigantic Mid-Caradoc (c. 455 Ma) ash fall in Baltica (i.e. the Kinnekulle bentonite). Avalonia was located south of the subtropical high during most of the Ordovician, and this would have provided an optimum palaeoposition to supply Baltica with large ash falls governed by westerly winds.In Scania, we observe a persistent palaeomagnetic overprint of Late Ordovician (Ashgill) age (pole: LATITUDE=4°S, LONGITUDE=012°E). The remagnetisation was probably spurred by tectonic-derived fluids since burial alone is inadequate to explain this remagnetisation event. This is the first record of a Late Ordovician event in Scania, but it is comparable with the Shelveian event in Avalonia, low-grade metamorphism in the North Sea basement of NE Germany (440–450 Ma), and sheds new light on the Baltica–Avalonia docking.     

The transition from an active to a passive margin (SW end of the South Shetland Trench, Antarctic Peninsula)

The lateral ending of the South Shetland Trench is analysed on the basis of swath bathymetry and multichannel seismic profiles in order to establish the tectonic and stratigraphic features of the transition from an northeastward active to a southwestward passive margin style. This trench is associated with a lithospheric-scale thrust accommodating the internal deformation in the Antarctic Plate and its lateral end represents the tip-line of this thrust. The evolutionary model deduced from the structures and the stratigraphic record includes a first stage with a compressional deformation, predating the end of the subduction in the southwestern part of the study area that produced reverse faults in the oceanic crust during the Tortonian. The second stage occurred during the Messinian and includes distributed compressional deformation around the tip-line of the basal detachment, originating a high at the base of the slope and the collapse of the now inactive accretionary prism of the passive margin. The initial subduction of the high at the base of the slope induced the deformation of the accretionary prism and the formation of another high in the shelf—the Shelf Transition High. The third stage, from the Early Pliocene to the present-day, includes the active compressional deformation of the shelf and the base-of-slope around the tip-line of the basal detachment, while extensional deformations are active in the outer swell of the trench.     

Surface-wave analysis for static corrections in mineral exploration: A case study from central Sweden

In mineral exploration, increased interest towards deeper mineralizations makes seismic methods attractive. One of the critical steps in seismic processing workflows is the static correction, which is applied to correct the effect of the shallow, highly heterogeneous subsurface layers, and improve the imaging of deeper targets. We showed an effective approach to estimate the statics, based on the analysis of surface waves (groundroll) contained in the seismic reflection data, and we applied it to a legacy seismic line acquired at the iron-oxide mining site of Ludvika in Sweden. We applied surface-wave methods that were originally developed for hydrocarbon exploration, modified as a step-by-step workflow to suit the different geologic context of hard-rock sites. The workflow starts with the detection of sharp lateral variations in the subsurface, the existence of which is common at hard-rock sites. Their location is subsequently used, to ensure that the dispersion curves extracted from the data are not affected by strong lateral variations of the subsurface properties. The dispersion curves are picked automatically, windowing the data and applying a wavefield transform. A pseudo-2D time-average S-wave velocity and time-average P-wave velocity profile are obtained directly from the dispersion curves, after inverting only a reference curve. The time-average P-wave velocity profile is then used for the direct estimation of the one-way traveltime, which provides the static corrections. The resulting P-wave statics from the field data were compared with statics computed through conventional P-wave tomography. Their difference was mostly negligible with more than 91% of the estimations being in agreement with the conventional statics, proving the effectiveness of the proposed workflow. The application of the statics obtained from surface waves provided a stacked section comparable with that obtained by applying tomostatics.     

Deep reflection seismic imaging of iron-oxide deposits in the Ludvika mining area of central Sweden

Reflection seismic data were acquired within two field campaigns in the Blötberget, Ludvika mining area of central Sweden, for deep imaging of iron-oxide mineralization that were known to extend down to 800–850 m depth. The two surveys conducted in years 2015 and 2016, one employing a seismic landstreamer and geophones connected to wireless recorders, and another one using cabled geophones and wireless recorders, aimed to delineate the geometry and depth extent of the iron-oxide mineralization for when mining commences in the area. Even with minimal and conventional processing approaches, the merged datasets provide encouraging information about the depth continuation of the mineralized horizons and the geological setting of the study area. Multiple sets of strong reflections represent a possible continuation of the known deposits that extend approximately 300 m further down-dip than the known 850 m depth obtained from historical drilling. They show excellent correlation in shape and strength with those of the Blötberget deposits. Furthermore, several reflections in the footwall of the known mineralization can potentially be additional resources underlying the known ones. The results from these seismic surveys are encouraging for mineral exploration purposes given the good quality of the final section and fast seismic surveys employing a simple cost-effective and easily available impact-type seismic source.     

Total organic carbon fluxes of the Red River system (Vietnam)

Riverine transport of organic carbon from terrestrial ecosystems to the oceans plays an important role in the global carbon cycle. The Red River is located in Southeast Asia where river discharge, sediment loads and fluxes of elements (carbon, nitrogen and phosphorus) associated with suspended solids have been dramatically altered over past decades as a result of reservoir impoundment and land use, population, and climate change. Dissolved organic carbon (DOC) and particulate organic carbon (POC) concentrations were measured monthly at four stations of the Red River system from January 2008 to December 2010. The results reveal that POC changed synchronically with total suspended solids (TSS) concentration and with the river discharge, whereas no clear trend was observed for DOC concentration. The mean value of total organic carbon (TOC = DOC + POC) flux in the delta of the Red River was 31.5 × 10¹³ ± 4.0 × 10¹³ MgC.yr^?1 (range 27.9–35.8 × 10¹³ MgC.yr^?1 which leads to a specific TOC flux of 2012 ± 255 kgC.km^?2.yr^?1 during this 2008–2010 period. About 80% of the TOC flux was transferred to the estuary during the rainy season as a consequence of the higher river water discharge. The high mean value of the POC:Chl‐a ratio (1585 ± 870 mgC.mgChl‐a^?1) and the moderate C:N ratio (7.3 ± 0.1) in the water column system suggest that organic carbon in the Red River system is mainly derived from erosion and soil leaching in the basin. The effect of two new dam impoundments in the Red River was also observable with lower TOC fluxes in 2010 compared with 2008. Copyright © 2017 John Wiley & Sons, Ltd.     

Mineral fibres and environmental monitoring:A comparison of different analytical strategies in New Caledonia

Covered by ultrabasic units for more than a third of its surface,the New Caledonia(South West Pacific)is one of the largest world producers of Ni-ore from lateritic deposits.Almost all outcrops of geological units and open mines contain serpentine and amphibole,also as asbestos varieties.In this geological context,in which weathering processes had a great contribution in the production and dispersion of mineral fibres into the environment,the development of a routinely analytical strategy,able to discriminate an asbestiform fibre from a non-harmful particle,is a pivotal requisite.However,the acquisition of all these parameters is necessary for determining the risk associated to fibres exposition.A multidisciplinary routinely approach,based on the use of complementary simply-to-use but reliable analytical methods is the only possible strategy.In addition,the instrumental apparatus must be easily transportable on the field,directly on the mining site.The employment of specialized tools such as Polarized Light Microscopy associated to Dispersion Staining method(PLM/DS)and portable Raman spectroscopy for identification of environmental asbestos,are proved extremely effective in the improvement of the performance and rapidity of data acquisition and interpretation.Both PLM/DS and handheld Raman devices confirmed to be discriminant in the detection and characterization of asbestos fibres for both serpentine and amphibole.Furthermore,these techniques proved extremely effective even in the presence of strongly fibrous and altered samples.