Seasonal surface ocean circulation and dynamics in the Philippine Archipelago region during 2004–2008

The dynamics of the seasonal surface circulation in the Philippine Archipelago (117°E–128°E, 0°N–14°N) are investigated using a high-resolution configuration of the Regional Ocean Modeling System (ROMS) for the period of January 2004–March 2008. Three experiments were performed to estimate the relative importance of local, remote and tidal forcing. On the annual mean, the circulation in the Sulu Sea shows inflow from the South China Sea at the Mindoro and Balabac Straits, outflow into the Sulawesi Sea at the Sibutu Passage, and cyclonic circulation in the southern basin. A strong jet with a maximum speed exceeding 100 cm s⁻¹ forms in the northeast Sulu Sea where currents from the Mindoro and Tablas Straits converge. Within the Archipelago, strong westward currents in the Bohol Sea carry the surface water of the western Pacific (WP) from the Surigao Strait into the Sulu Sea via the Dipolog Strait. In the Sibuyan Sea, currents flow westward, which carry the surface water from the WP near the San Bernardino Strait into the Sulu Sea via the Tablas Strait.These surface currents exhibit strong variations or reversals from winter to summer. The cyclonic (anticyclonic) circulation during winter (summer) in the Sulu Sea and seasonally reversing currents within the Archipelago region during the peak of the winter (summer) monsoon result mainly from local wind forcing, while remote forcing dominates the current variations at the Mindoro Strait, western Sulu Sea and Sibutu passage before the monsoons reach their peaks. The temporal variations (with the mean removed), also referred to as anomalies, of volume transports in the upper 40 m at eight major Straits are caused predominantly by remote forcing, although local forcing can be large during sometime of a year. For example, at the Mindoro Strait, the correlation between the time series of transport anomalies due to total forcing (local, remote and tides) and that due only to the remote forcing is 0.81 above 95% significance, comparing to the correlation of 0.64 between the total and local forcing. Similarly, at the Sibutu Passage, the correlation is 0.96 for total versus remote effects, comparing to 0.53 for total versus local forcing. The standard deviations of transports from the total, remote and local effects are 0.59 Sv, 0.50 Sv, and 0.36 Sv, respectively, at the Mindoro Strait; and 1.21 Sv, 1.13 Sv, and 0.59 Sv at the Sibutu Passage. Nonlinear rectification of tides reduces the mean westward transports at the Surigao, San Bernardino and Dipolog Straits, and it also has non-negligible influence on the seasonal circulation in the Sulu Sea.     

Evaluation of microwave-assisted acid extraction procedures for the determination of metal content and potential bioavailability in sediments

Acid extractions represent a simple and effective tool for the assessment of metal contamination, origin and bioavailability in the aquatic environment. Optimized microwave-assisted procedures utilizing two extractions (8 M HNO₃ and 1 M HCl) were developed. Particular attention was given to the evaluation of efficiency and selectivity of the developed procedures. This involved an examination of the sediment and the extraction residues by Mössbauer spectroscopy and X-ray diffractometry. These instrumental approaches were used to identify the geochemical phases associated with acid decomposition. Microwave digestion with 8 M HNO₃ produced an efficient solubilization of the most important metal-bearing phases and left unaffected only the minerals (quartz, feldspars, muscovite) with a negligible metal content, thus providing a good estimate of the total metal concentrations. The 1 M HCl extraction, despite the limitation due to the incomplete solubilization of pyrite and to the partial dissolution of sheet silicates, represents a simple and effective technique for providing an estimate of the bioavailable metal fraction in sediments. The combined use of the two microwave-assisted acid extractions can provide a rapid and simple approach for the risk assessment of metal-polluted sediments.     

Profitability and the poor: Corporate strategies, innovation and sustainability

Based on empirical evidence, the article looks at the implications of private sector participation (PSP) for the delivery of water supply and sanitation to the urban and peri-urban poor in developing countries, with particular reference to Africa and Latin America. More precisely, the article addresses the impact produced by multinational companies’ (MNCs) strategies, in light of the pursuit of profitability, on the extension of connections to the pipeline network. It does so by questioning the assumptions that greater private sector efficiency and innovation, together with contract design, will enable the sustainable extension of service coverage to low income dwellers. The strategies of the major water MNCs are considered both in relation to the global expansion of their operations and the adjustment of local strategies to commercial considerations. The latter might result in identifying profitable markets, modifying contractual provisions, attempting to reduce costs and increase income, reducing risks and exiting from non-performing contracts. The evidence reviewed allows for re-assessing the relative roles of the public and private sectors in extending and delivering water services to the poor. First, the most far reaching innovative approaches to extending connections are more likely to come from communities, public authorities and political activity than from MNCs. Secondly, whenever MNCs are liable to exit from non-profitable contracts, the public sector has no other option than to deal with external risks affecting continuity of provision. Finally, market limitations affecting MNCs’ ability to serve marginal populations and access cheap capital do not apply to well-organised, politically led public sector undertakings.     

The role of the Polochic Fault as part of the North American and Caribbean Plate boundary: Insights from the infill of the Lake Izabal Basin

The Lake Izabal Basin in Guatemala is a major pull-apart basin along the sinistral Polochic Fault, which is part of the North American and Caribbean plate boundary. The basin infill contains information about the tectonic and sedimentological processes that have imparted a significant control on its sedimentary section. The inception of the basin has been linked to the relative importance of the Polochic Fault in the tectonic history of the plate boundary; yet, its sedimentological record and its inception age have been poorly documented. This study integrates diverse datasets, including industry reports, well logs and reports, well cuttings, vintage seismic data, outcrop observations and geochronological data to constrain the initial infill and age of inception of the basin. The integrated data show that during the Oligocene–Miocene, a marine carbonate platform was established in the region which was later uplifted and eroded in the early Miocene. The fluvial–lacustrine deposits above this carbonate platform are part of the initial infill of the basin and are constrained with zircon weighted-mean ²⁰⁶Pb/²³⁸U ages of 12.060 ± 0.008 from a volcanic tuff ~30 m above the unconformity. Sandstone, mudstone and coal dominate the interval from 12 to 4 Ma, with an increase in conglomerate correlating to the uplift of the Mico Mountains and San Gil Hill at 4 Ma. Fault switch activity between the Polochic and Motagua faults has been hypothesized to explain total offset along the Polochic Fault and the geologic and geodetic slip rates along the two faults. The 12 Ma age determined for the initial infill of the basin confirms this hypothesis. Consequently, our study confirms that at ~12 Ma the Polochic Fault served as the main fault of the plate boundary with inferred slip rates ranging from 13 to 21 mm/yr with a strong possibility that the Polochic Fault was, at some point between 15 Ma and 7 Ma, the only active fault of the plate boundary. The results of this study show that tectonic records preserved in sediments of strike-slip basins improve the understanding of the relative significance of individual faults and the implications with respect to strain partitioning throughout its tectonic history.     

The radiation environment in L-2 orbit: implications on the non-X-ray background of the eROSITA pn-CCD cameras

The pn-CCD cameras at the focal plane of the eROSITA space observatory will be the first X-ray (0.2?C12?keV) detector to operate in a L-2 orbit. Therefore, no direct information of instrumental non X-ray background (NXB) is available to make predictions for eROSITA. Since, in general, the instrumental NXB experienced in orbit has a major impact on the overall sensitivity of the cameras, we investigated and modeled the L-2 radiation environment and its interaction with the eROSITA mass distribution and cameras, in order to quantify the expected pn-CCD NXB level. We obtain an average value of NXB ??25% lower than that observed by the pn-CCDs on-board the XMM-Newton satellite, which is placed in a Highly Elliptical Orbit (HEO). We discuss this result in light of the differences between the L-2 and HEO space environments.     

Rates, progenitors and cosmic mix of Type Ia supernovae

Following an episode of star formation, Type Ia supernova events occur over an extended period of time, following a distribution of delay times (DDT). We critically discuss some empirically based DDT functions that have been proposed in recent years, some favouring very early (prompt) events, other very late (tardy) ones, and therefore being mutually exclusive. We point out that in both the cases the derived DDT functions are affected by dubious assumptions, and therefore there is currently no ground for claiming either a DDT strongly peaked at early times, or at late ones. Theoretical DDT functions are known to accommodate both prompt as well as late SN Ia events, and can account for all available observational constraints. Recent observational evidence exist that both single and double degenerate precursors may be able of producing SN Ia events. We then explore on the basis of plausible theoretical models the possible variation with cosmic time of the mix between the events produced by the two different channels, which, in principle, could lead to systematic effects on the SN Ia properties with redshift.     

Galaxy Evolution from Deep Multicolor Surveys

A composite sample of NIR-selected galaxies having extended multicolor coverage has been used to probe the cosmological evolution of the blue luminosity function and of the stellar mass function. The bright fraction of the sample has spectroscopic redshifts, and the remaining fraction well-calibrated photometric redshifts. The resulting blue luminosity function shows an increasing brightening with redshift respect to the local luminosity function. Hierarchical CDM models predictions are in agreement only at low and intermediate redshifts but fail to reproduce the observed brightening at high redshifts (z ∼ 2–3). This brightening marks the epoch where starburst activity triggered by galaxy interactions could be an important physical mechanism for the galaxy evolution. At the same time the NIR galaxy sample has been used to trace the evolution of the cosmological stellar mass density up to ∼3. A clear decrease of the average mass density is apparent with a fraction ∼15% of the local value at z ∼ 3. UV bright star-forming galaxies are substancial contributors to the evolution of the stellar mass density. Although these results are globally consistent with Λ–CDM scenarios, they tend to underestimate the mass density produced by more massive galaxies present at z > 2.