Exponential metric fields

The Laser Interferometer Space Antenna (LISA) mission will use advanced technologies to achieve its science goals: the direct detection of gravitational waves, the observation of signals from compact (small and dense) stars as they spiral into black holes, the study of the role of massive black holes in galaxy evolution, the search for gravitational wave emission from the early Universe. The gravitational red-shift, the advance of the perihelion of Mercury, deflection of light and the time delay of radar signals are the classical tests in the first order of General Relativity (GR). However, LISA can possibly test Einstein’s theories in the second order and perhaps, it will show some particular feature of non-linearity of gravitational interaction. In the present work we are seeking a method to construct theoretical templates that limit in the first order the tensorial structure of some metric fields, thus the non-linear terms are given by exponential functions of gravitational strength. The Newtonian limit obtained here, in the first order, is equivalent to GR.     

Site evaluation and RFI spectrum measurements in Portugal at the frequency range 0.408–10 GHz for a GEM polarized galactic radio emission experiment

We probed for radio frequency interference (RFI) at three potential galactic emission mapping experiment (GEM) sites in Portugal using custom made omnidirectional disconic antennas and directional pyramidal horn antennas. For the installation of a 10-m dish dedicated to the mapping of polarized galactic emission foreground planned for 2005–2007 in the 5–10 GHz band, the three sites chosen as suitable to host the antenna were surveyed for local radio pollution in the frequency range 0.01–10 GHz. Tests were done to look for radio broadcasting and mobile phone emission lines in the radio spectrum. The results show one of the sites to be almost entirely RFI clean and showing good conditions to host the experiment.     

Mesoarchean (3.0 and 2.86 Ga) host rocks of the iron oxide–Cu–Au Bacaba deposit,Carajás Mineral Province: U–Pb geochronology and metallogenetic implications

The Bacaba iron oxide–copper–gold deposit, situated within a WNW–ESE-striking shear zone in the Carajás Domain, Carajás Mineral Province, is hosted by the Serra Dourada Granite, the Bacaba Tonalite, and crosscutting gabbro intrusions, which were intensely affected by sodic (albite–scapolite), potassic, chloritic, and hydrolytic hydrothermal alteration. This deposit is located 7 km northeast of the world-class Sossego iron oxide–copper–gold deposit and might represent a distal and deeper portion of the same or related hydrothermal system. The U–Pb laser ablation inductively coupled plasma–mass spectrometry data for zircon from a sodically altered sample of the Serra Dourada Granite yielded a 2,860±22 Ma (MSWD=11.5) age. Three samples from the Bacaba Tonalite, including one with potassic alteration and two with Cu–Au mineralization, rendered the 3,001.2±3.6 Ma (MSWD=1.8), 2,990.9±5.8 Ma (MSWD=1.9), and 3,004.6±9 Ma (MSWD=2.2) ages, respectively. The ca. 2.86 and ca. 3.0 Ga ages are interpreted as the timing of the igneous crystallization of the Serra Dourada Granite and the Bacaba Tonalite, respectively, and represent the oldest magmatic events recognized in the Carajás Domain. The Serra Dourada Granite and the Bacaba Tonalite are interpreted to greatly predate the genesis of the Bacaba deposit. A genetic link is improbable in the light of the similarities with the Sossego deposit, which is also hosted by younger ca. 2.76 Ga metavolcano-sedimentary units of the Itacaiúnas Supergroup. In this context, the iron oxide–copper–gold deposits in the southern sector of the Carajás Domain could be mainly controlled by important crustal discontinuities, such as a regional shear zone, rather than be associated with a particular rock type. These results expand the potential for occurrences of iron oxide–copper–gold deposits within the Mesoarchean basement rocks underlying the Carajás Basin, particularly those crosscut by Neoarchean shear zones.     

Multi-model calibration and combination of tropical seasonal sea surface temperature forecasts

Different combination methods based on multiple linear regression are explored to identify the conditions that lead to an improvement of seasonal forecast quality when individual operational dynamical systems and a statistical–empirical system are combined. A calibration of the post-processed output is included. The combination methods have been used to merge the ECMWF System 4, the NCEP CFSv2, the Météo-France System 3, and a simple statistical model based on SST lagged regression. The forecast quality was assessed from a deterministic and probabilistic point of view. SSTs averaged over three different tropical regions have been considered: the Niño3.4, the Subtropical Northern Atlantic and Western Tropical Indian SST indices. The forecast quality of these combinations is compared to the forecast quality of a simple multi-model (SMM) where all single models are equally weighted. The results show a large range of behaviours depending on the start date, target month and the index considered. Outperforming the SMM predictions is a difficult task for linear combination methods with the samples currently available in an operational context. The difficulty in the robust estimation of the weights due to the small samples available is one of the reasons that limit the potential benefit of the combination methods that assign unequal weights. However, these combination methods showed the capability to improve the forecast reliability and accuracy in a large proportion of cases. For example, the Forecast Assimilation method proved to be competitive against the SMM while the other combination methods outperformed the SMM when only a small number of forecast systems have skill. Therefore, the weighting does not outperform the SMM when the SMM is very skilful, but it reduces the risk of low skill situations that are found when several single forecast systems have a low skill.     

Ammonium,nitrate and phytoplankton interactions in a freshwater tidal estuarine zone: potential effects of cultural eutrophication

Nitrate and ammonium are the most important nitrogen sources for phytoplankton growth. Differential utilization of inorganic nitrogenous compounds by phytoplankton has been observed and may have significant impacts on primary productivity at local scales. We used enrichment experiments with natural phytoplankton populations from the freshwater tidal zone of the Guadiana estuary, a coastal ecosystem increasingly subjected to anthropogenic influences, to study the effects of nitrate and ammonium on N-consumption and phytoplankton growth. In addition, we used combined additions of nitrate and ammonium to understand the inhibitory effect of ammonium over nitrate uptake. Ammonium concentrations in the freshwater tidal reaches of the Guadiana estuary throughout the sampling period were too low to exert an inhibitory effect on nitrate uptake or a toxic effect on phytoplankton growth. Nitrate was clearly the main nitrogen source for phytoplankton at the study site. Overall, nitrate seemed to become limiting at concentrations lower than 20 μM and N-limitation was particularly significant during summer. A trend of decreasing nitrate uptake with increasing ammonium concentrations and uptake suggested an overall preference for ammonium. However, preference for ammonium was group-specific, and it was observed mainly in green algae and cyanobacteria. In fact, cyanobacteria relied only on ammonium as their N-source. On the contrary, diatoms preferred nitrate, and did not respond to ammonium additions. The increasing eutrophication in the Guadiana estuary and particularly increased inputs of nitrogen as ammonium due to urban waste effluents may result in a shift in phytoplankton community composition, towards a dominance of cyanobacteria and green algae.     

Lead isotope distribution and enrichment factors in soil profiles around an abandoned Pb-smelter plant

Todos os Santos (all Saints) Bay area on Brazil’s east coast is known for one of the most significant cases of lead contamination in the country owing to the past activities of a Pb-smelter plant. This work was carried out to assess the concentration and sources of Pb based on Pb isotopes and enrichment factor of soil profiles surrounding Todos os Santos Bay in order to understand the expansion of contamination and to help the establishment of Pb regulatory standards for the region. Forty-four samples were collected from soil genetic horizons of six pedons that represent the range of dominant soil properties and geologic materials in the region. Concentrations of Pb and the isotopes ²⁰⁴Pb, ²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb were determined on an inductively coupled plasma (quadrupole) mass spectrometry. The soil enrichment factor was calculated using Al and Fe as conservative index elements. Average Pb concentration (15.87 mg kg^?1) in uppermost horizons (from all six pedons) is slightly higher than soil background concentrations commonly reported in Brazil. Samples feature a wide range of Pb isotope ratios, ranging from 36.71 to 47.38 for ²⁰⁸Pb/²⁰⁴Pb, 15.00 to 15.65 for ²⁰⁷Pb/²⁰⁴Pb, 16.86 to 20.59 for ²⁰⁶Pb/²⁰⁴Pb, and 1.10 to 1.31 for ²⁰⁶Pb/²⁰⁷Pb. For the enrichment factor calculations, only Fe demonstrated a good agreement with Pb isotopic ratios. Both Pb isotopic composition and enrichment factor were useful tools to distinguishing natural and anthropogenic influence on the Pb soil concentrations.     

Reply to Discussion “Geopolymers Based on Recycled Glass Powder for Soil Stabilization” Jair de Jesús Arrieta Baldovino,Ronaldo Luis dos Santos Izzo,Juliana Lundgren Rose,and Mônica Angélica Avanci

Geotechnical and Geological Engineering -     

Degradation of Monoazo Pigments Red 53:1 and Red 48:2 by Fenton,Photo‐Fenton and UV/Peroxide Reactions

The degradation reactions of two monoazo pigments, namely, Red 53:1 and Red 48:2, by Fenton, photo‐Fenton and UV/H₂O₂ systems have been studied. The efficiencies of the Fenton reactions increased with temperature, but the formation of solid agglomerates was observed when the reactions were carried out above 50°C indicating a coagulant action of Fe⁺² or Fe⁺³. Photo‐Fenton reactions irradiated by sunlight presented the best rate constants for cleavage of the azo bond and the naphthalene rings. The UV/H₂O₂ system exhibited the highest efficiency with respect to the consumption of H₂O₂. The presence of a carbonyl group in the ortho position of the naphthol ring hampered the oxidation of pigment Red 48:2 by hydroxyl radicals. This finding may be explained in terms of the acceptor character of the COOH group, and suggests the formation of a complex containing two six‐membered rings between Fe⁺³ and the pigment molecule.     

Efforts to reduce sea turtle bycatch in the shrimp fishery in Northeastern Brazil through a co-management process

The neritic waters of the state of Sergipe in Northeastern Brazil is adjacent to the main nesting area of the olive ridley sea turtles (Lepidochelys olivacea) in the Western Atlantic Ocean and an important area for shrimp trawl fishery. To address the problem of incidental mortality of sea turtles captured during trawling and reduce the risk of overexploitation of shrimp stocks, Projeto TAMAR/ICMBio, a Brazilian sea turtle conservation program, has adopted two main strategies: (1) the implementation of a marine monitoring program and (2) active participation in local forums. This paper describes the conflicts among stakeholders, the arrangements and established mechanisms of negotiation aimed to protect sea turtles and shrimp grounds, and strategies to reduce conflicts between user groups. The analysis of this co-management process highlights the importance of stakeholder participation in resource management decision-making through a cooperative process, the role assumed by non-governmental organizations as mediators, and the factors that influence this system. The key factors and actions learnt from the current study include clear identification of the conflicts, identification of stakeholders – both local and external, and local leaders, encouragement of actors and leaders to participate, support and strengthening of local groups, legitimization of the discussion forums through involvement with government, formalization of decisions taken through legislation, and monitoring of the management efficacy.     

Rigid‐plastic seismic design of reinforced concrete structures

In this paper a new seismic design procedure for Reinforced Concrete (R/C) structures is proposed—the Rigid‐Plastic Seismic Design (RPSD) method. This is a design procedure based on Non‐Linear Time‐ History Analysis (NLTHA) for systems expected to perform in the non‐linear range during a lifetime earthquake event. The theoretical background is the Theory of Plasticity (Rigid‐Plastic Structures). Firstly, a collapse mechanism is chosen and the corresponding stress field is made safe outside the regions where plastic behaviour takes place. It is shown that this allows the determination of the required structural strength with respect to a pre‐defined performance parameter using a rigid‐plastic response spectrum, which is characteristic of the ground motion alone. The maximum strength demand at any point is solely dependent on the intensity of the ground motion, which facilitates the task of distributing required strength throughout the structure. Any artificial considerations intended to adjust results according to empirical observations are avoided, which, from a conceptual point of view, is considered to be an advantage over other simplified design procedures for seismic design. The procedure is formulated using a step‐by‐step format followed by a design example of a 4‐storey‐R/C‐plane‐frame. Results are compared with refined NLTHA and found to be extremely encouraging. Copyright © 2006 John Wiley & Sons, Ltd.